The Absolute Configuration of 2,7-Disubstituted Triptycenes as Determined by the Chemical Correlation

The absolute configuration of optically active 2,5,7-trisubstituted triptycenes deduced from the rigorous analysis of their CD spectra based on molecular exciton theory was found to be consistent with that determined by “the revised X-ray method”. In order to get further information, the absolute c...

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Main Authors: M. Kuritani, Y. Sakata, F. Ogura, M. Nakagawa
Format: Article
Language:deu
Published: Swiss Chemical Society 1972-09-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9030
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author M. Kuritani
Y. Sakata
F. Ogura
M. Nakagawa
author_facet M. Kuritani
Y. Sakata
F. Ogura
M. Nakagawa
author_sort M. Kuritani
collection DOAJ
description The absolute configuration of optically active 2,5,7-trisubstituted triptycenes deduced from the rigorous analysis of their CD spectra based on molecular exciton theory was found to be consistent with that determined by “the revised X-ray method”. In order to get further information, the absolute configuration of 2,7-discustituted triptycene was correlated with that of 2,5,7-trisubstituted triptycenes.
format Article
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2673-2424
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publishDate 1972-09-01
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spelling doaj-art-53ef2d5a93cf496b84fe7bb3c9404bbc2025-08-20T01:47:43ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24241972-09-0126910.2533/chimia.1972.470The Absolute Configuration of 2,7-Disubstituted Triptycenes as Determined by the Chemical CorrelationM. Kuritani0Y. Sakata1F. Ogura2M. Nakagawa3Department of Chemistry, Faculty of Science, Osaka University Toyonaka, Osaka, 560, JapanDepartment of Chemistry, Faculty of Science, Osaka University Toyonaka, Osaka, 560, JapanDepartment of Chemistry, Faculty of Science, Osaka University Toyonaka, Osaka, 560, JapanDepartment of Chemistry, Faculty of Science, Osaka University Toyonaka, Osaka, 560, Japan The absolute configuration of optically active 2,5,7-trisubstituted triptycenes deduced from the rigorous analysis of their CD spectra based on molecular exciton theory was found to be consistent with that determined by “the revised X-ray method”. In order to get further information, the absolute configuration of 2,7-discustituted triptycene was correlated with that of 2,5,7-trisubstituted triptycenes. https://www.chimia.ch/chimia/article/view/9030
spellingShingle M. Kuritani
Y. Sakata
F. Ogura
M. Nakagawa
The Absolute Configuration of 2,7-Disubstituted Triptycenes as Determined by the Chemical Correlation
CHIMIA
title The Absolute Configuration of 2,7-Disubstituted Triptycenes as Determined by the Chemical Correlation
title_full The Absolute Configuration of 2,7-Disubstituted Triptycenes as Determined by the Chemical Correlation
title_fullStr The Absolute Configuration of 2,7-Disubstituted Triptycenes as Determined by the Chemical Correlation
title_full_unstemmed The Absolute Configuration of 2,7-Disubstituted Triptycenes as Determined by the Chemical Correlation
title_short The Absolute Configuration of 2,7-Disubstituted Triptycenes as Determined by the Chemical Correlation
title_sort absolute configuration of 2 7 disubstituted triptycenes as determined by the chemical correlation
url https://www.chimia.ch/chimia/article/view/9030
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