(Nitrito-κ2O:O′)bis[tris(4-fluorophenyl)phosphine-κP]silver(I)
The molecular structure of the title AgI complex, [Ag(NO2)(C18H12F3P)2], features a distorted tetrahedral geometry about the central AgI atom, with a total range of bond angles spanning from 49.80 (5) to 114.92 (1)°. The distortion arises primarily due to the small bite angle [49.80 (5)°] of the nit...
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| Language: | English |
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International Union of Crystallography
2025-04-01
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| Online Access: | https://journals.iucr.org/paper?S2414314625002962 |
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| author | Frederick P. Malan Kariska Potgieter Reinout Meijboom |
| author_facet | Frederick P. Malan Kariska Potgieter Reinout Meijboom |
| author_sort | Frederick P. Malan |
| collection | DOAJ |
| description | The molecular structure of the title AgI complex, [Ag(NO2)(C18H12F3P)2], features a distorted tetrahedral geometry about the central AgI atom, with a total range of bond angles spanning from 49.80 (5) to 114.92 (1)°. The distortion arises primarily due to the small bite angle [49.80 (5)°] of the nitrito ligand. The compound crystallizes with one molecule in the asymmetric unit, in the space group P21/n, with Z = 4 and Z′ = 1. |
| format | Article |
| id | doaj-art-53e0abe410fc43bd895562d5552aaad6 |
| institution | Kabale University |
| issn | 2414-3146 |
| language | English |
| publishDate | 2025-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj-art-53e0abe410fc43bd895562d5552aaad62025-08-20T03:52:10ZengInternational Union of CrystallographyIUCrData2414-31462025-04-01104x25029610.1107/S2414314625002962wm4226(Nitrito-κ2O:O′)bis[tris(4-fluorophenyl)phosphine-κP]silver(I)Frederick P. Malan0Kariska Potgieter1Reinout Meijboom2Department of Chemistry, University of Pretoria, Lynnwood Road, Hatfield, Pretoria, 0002, South AfricaDepartment of Chemical Sciences, University of Johannesburg, PO Box 524, Auckland Park, 2006, Johannesburg, South AfricaDepartment of Chemical Sciences, University of Johannesburg, PO Box 524, Auckland Park, 2006, Johannesburg, South AfricaThe molecular structure of the title AgI complex, [Ag(NO2)(C18H12F3P)2], features a distorted tetrahedral geometry about the central AgI atom, with a total range of bond angles spanning from 49.80 (5) to 114.92 (1)°. The distortion arises primarily due to the small bite angle [49.80 (5)°] of the nitrito ligand. The compound crystallizes with one molecule in the asymmetric unit, in the space group P21/n, with Z = 4 and Z′ = 1.https://journals.iucr.org/paper?S2414314625002962silver(i) complextris-4-fluorophenyl phosphinenitritecrystal structure |
| spellingShingle | Frederick P. Malan Kariska Potgieter Reinout Meijboom (Nitrito-κ2O:O′)bis[tris(4-fluorophenyl)phosphine-κP]silver(I) IUCrData silver(i) complex tris-4-fluorophenyl phosphine nitrite crystal structure |
| title | (Nitrito-κ2O:O′)bis[tris(4-fluorophenyl)phosphine-κP]silver(I) |
| title_full | (Nitrito-κ2O:O′)bis[tris(4-fluorophenyl)phosphine-κP]silver(I) |
| title_fullStr | (Nitrito-κ2O:O′)bis[tris(4-fluorophenyl)phosphine-κP]silver(I) |
| title_full_unstemmed | (Nitrito-κ2O:O′)bis[tris(4-fluorophenyl)phosphine-κP]silver(I) |
| title_short | (Nitrito-κ2O:O′)bis[tris(4-fluorophenyl)phosphine-κP]silver(I) |
| title_sort | nitrito κ2o o bis tris 4 fluorophenyl phosphine κp silver i |
| topic | silver(i) complex tris-4-fluorophenyl phosphine nitrite crystal structure |
| url | https://journals.iucr.org/paper?S2414314625002962 |
| work_keys_str_mv | AT frederickpmalan nitritok2oobistris4fluorophenylphosphinekpsilveri AT kariskapotgieter nitritok2oobistris4fluorophenylphosphinekpsilveri AT reinoutmeijboom nitritok2oobistris4fluorophenylphosphinekpsilveri |