Research on Acetylene Sensing Properties and Mechanism of SnO2 Based Chemical Gas Sensor Decorated with Sm2O3

Acetylene C2H2 gas is one of the most important fault characteristic hydrocarbon gases dissolved in oil immersed power transformer oil. This paper reports the successful preparation and characterization of samarium oxide Sm2O3 decorated tin oxide SnO2 based sensors with hierarchical rod structure fo...

Full description

Saved in:
Bibliographic Details
Main Authors: Qu Zhou, Meiqing Cao, Wude Li, Chao Tang, Shiping Zhu
Format: Article
Language:English
Published: Wiley 2015-01-01
Series:Journal of Nanotechnology
Online Access:http://dx.doi.org/10.1155/2015/714072
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832545304950341632
author Qu Zhou
Meiqing Cao
Wude Li
Chao Tang
Shiping Zhu
author_facet Qu Zhou
Meiqing Cao
Wude Li
Chao Tang
Shiping Zhu
author_sort Qu Zhou
collection DOAJ
description Acetylene C2H2 gas is one of the most important fault characteristic hydrocarbon gases dissolved in oil immersed power transformer oil. This paper reports the successful preparation and characterization of samarium oxide Sm2O3 decorated tin oxide SnO2 based sensors with hierarchical rod structure for C2H2 gas detection. Pure and Sm2O3 decorated SnO2 sensing structures were synthesized by a facile hydrothermal method and characterized by XRD, FESEM, TEM, EDS, and XPS measurements, respectively. Planar chemical gas sensors with the synthesis samples were fabricated, and their sensing performances to C2H2 gas were systematically performed and automatically recorded by a CGS-1 TP intelligent gas sensing analysis system. The optimum operating temperature of the Sm2O3 decorated SnO2 based sensor towards 50 μL/L of C2H2 is 260°C, and its corresponding response value is 38.12, which is 6 times larger than the pure one. Its response time is about 8–10 s and 10–13 s for recovery time. Meanwhile good stability and reproducibility of the decorated sensor to C2H2 gas are also obtained. Furthermore, the proposed sensor exhibits excellent C2H2 selectivity among some potential interface gases, like H2 and CO gas. All sensing results indicate the sensor fabricated with oxide Sm2O3 decorated SnO2 nanorods might be a promising candidate for C2H2 detection in practice.
format Article
id doaj-art-535dd78b71324ce1a9eabbcc4db88440
institution Kabale University
issn 1687-9503
1687-9511
language English
publishDate 2015-01-01
publisher Wiley
record_format Article
series Journal of Nanotechnology
spelling doaj-art-535dd78b71324ce1a9eabbcc4db884402025-02-03T07:26:10ZengWileyJournal of Nanotechnology1687-95031687-95112015-01-01201510.1155/2015/714072714072Research on Acetylene Sensing Properties and Mechanism of SnO2 Based Chemical Gas Sensor Decorated with Sm2O3Qu Zhou0Meiqing Cao1Wude Li2Chao Tang3Shiping Zhu4College of Engineering and Technology, Southwest University, Chongqing 400715, ChinaState Grid Chongqing Hechuan District Power Supply Company, Chongqing 401520, ChinaState Grid Chongqing Hechuan District Power Supply Company, Chongqing 401520, ChinaCollege of Engineering and Technology, Southwest University, Chongqing 400715, ChinaCollege of Engineering and Technology, Southwest University, Chongqing 400715, ChinaAcetylene C2H2 gas is one of the most important fault characteristic hydrocarbon gases dissolved in oil immersed power transformer oil. This paper reports the successful preparation and characterization of samarium oxide Sm2O3 decorated tin oxide SnO2 based sensors with hierarchical rod structure for C2H2 gas detection. Pure and Sm2O3 decorated SnO2 sensing structures were synthesized by a facile hydrothermal method and characterized by XRD, FESEM, TEM, EDS, and XPS measurements, respectively. Planar chemical gas sensors with the synthesis samples were fabricated, and their sensing performances to C2H2 gas were systematically performed and automatically recorded by a CGS-1 TP intelligent gas sensing analysis system. The optimum operating temperature of the Sm2O3 decorated SnO2 based sensor towards 50 μL/L of C2H2 is 260°C, and its corresponding response value is 38.12, which is 6 times larger than the pure one. Its response time is about 8–10 s and 10–13 s for recovery time. Meanwhile good stability and reproducibility of the decorated sensor to C2H2 gas are also obtained. Furthermore, the proposed sensor exhibits excellent C2H2 selectivity among some potential interface gases, like H2 and CO gas. All sensing results indicate the sensor fabricated with oxide Sm2O3 decorated SnO2 nanorods might be a promising candidate for C2H2 detection in practice.http://dx.doi.org/10.1155/2015/714072
spellingShingle Qu Zhou
Meiqing Cao
Wude Li
Chao Tang
Shiping Zhu
Research on Acetylene Sensing Properties and Mechanism of SnO2 Based Chemical Gas Sensor Decorated with Sm2O3
Journal of Nanotechnology
title Research on Acetylene Sensing Properties and Mechanism of SnO2 Based Chemical Gas Sensor Decorated with Sm2O3
title_full Research on Acetylene Sensing Properties and Mechanism of SnO2 Based Chemical Gas Sensor Decorated with Sm2O3
title_fullStr Research on Acetylene Sensing Properties and Mechanism of SnO2 Based Chemical Gas Sensor Decorated with Sm2O3
title_full_unstemmed Research on Acetylene Sensing Properties and Mechanism of SnO2 Based Chemical Gas Sensor Decorated with Sm2O3
title_short Research on Acetylene Sensing Properties and Mechanism of SnO2 Based Chemical Gas Sensor Decorated with Sm2O3
title_sort research on acetylene sensing properties and mechanism of sno2 based chemical gas sensor decorated with sm2o3
url http://dx.doi.org/10.1155/2015/714072
work_keys_str_mv AT quzhou researchonacetylenesensingpropertiesandmechanismofsno2basedchemicalgassensordecoratedwithsm2o3
AT meiqingcao researchonacetylenesensingpropertiesandmechanismofsno2basedchemicalgassensordecoratedwithsm2o3
AT wudeli researchonacetylenesensingpropertiesandmechanismofsno2basedchemicalgassensordecoratedwithsm2o3
AT chaotang researchonacetylenesensingpropertiesandmechanismofsno2basedchemicalgassensordecoratedwithsm2o3
AT shipingzhu researchonacetylenesensingpropertiesandmechanismofsno2basedchemicalgassensordecoratedwithsm2o3