Synthesis and Characterization of Multilayer 3D Chiral Polymers with Enhanced Optical Properties
This study reports the synthesis of novel multilayer 3D chiral polymers using 2,2′-(2,7-Naphthalenediyl)bis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane] and 1,8-dibronaphthalene along with its derivatives as key precursors. Comprehensive characterization was performed using nuclear magnetic resonance (N...
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| Format: | Article |
| Language: | English |
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MDPI AG
2025-03-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/30/7/1567 |
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| author | Sai Zhang Xiaobei Jin Daixiang Chen Qingzheng Xu Tao Wang Xiuyuan Qin Jialing Mao Yue Zhang Shenghu Yan Guigen Li |
| author_facet | Sai Zhang Xiaobei Jin Daixiang Chen Qingzheng Xu Tao Wang Xiuyuan Qin Jialing Mao Yue Zhang Shenghu Yan Guigen Li |
| author_sort | Sai Zhang |
| collection | DOAJ |
| description | This study reports the synthesis of novel multilayer 3D chiral polymers using 2,2′-(2,7-Naphthalenediyl)bis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane] and 1,8-dibronaphthalene along with its derivatives as key precursors. Comprehensive characterization was performed using nuclear magnetic resonance (NMR), gel permeation chromatography (GPC), photoluminescence, ultraviolet (UV) spectroscopy, scanning electron microscopy (SEM), polarimetry, dynamic light scattering (DLS), and thermogravimetric analysis (TGA). Notably, the polymers exhibited remarkable aggregation-induced emission (AIE) and aggregation-induced polarization (AIP) phenomena, revealing enhanced luminescence and optical activity in aggregated states. These findings underscore the potential of these chiral polymers for applications in optoelectronics and advanced sensing technologies, highlighting the intricate relationship between molecular structure and optical behavior. |
| format | Article |
| id | doaj-art-53560b65cfdf43febe4486c7011f17ce |
| institution | OA Journals |
| issn | 1420-3049 |
| language | English |
| publishDate | 2025-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj-art-53560b65cfdf43febe4486c7011f17ce2025-08-20T02:15:58ZengMDPI AGMolecules1420-30492025-03-01307156710.3390/molecules30071567Synthesis and Characterization of Multilayer 3D Chiral Polymers with Enhanced Optical PropertiesSai Zhang0Xiaobei Jin1Daixiang Chen2Qingzheng Xu3Tao Wang4Xiuyuan Qin5Jialing Mao6Yue Zhang7Shenghu Yan8Guigen Li9School of Pharmacy, Changzhou University, Changzhou 213164, ChinaChangzhou Tronly Advanced Electronic Materials Co., Ltd., Changzhou 213011, ChinaSchool of Pharmacy, Changzhou University, Changzhou 213164, ChinaSchool of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, ChinaSchool of Pharmacy, Changzhou University, Changzhou 213164, ChinaSchool of Life and Science, Nanjing Normal University, Nanjing 210046, ChinaSchool of Environmental Science and Engineering, Changzhou University, Changzhou 213164, ChinaSchool of Environmental Science and Engineering, Changzhou University, Changzhou 213164, ChinaSchool of Pharmacy, Changzhou University, Changzhou 213164, ChinaDepartment of Chemistry and Biochemistry, Texas Tech University, Lubbock, TX 79409-1061, USAThis study reports the synthesis of novel multilayer 3D chiral polymers using 2,2′-(2,7-Naphthalenediyl)bis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane] and 1,8-dibronaphthalene along with its derivatives as key precursors. Comprehensive characterization was performed using nuclear magnetic resonance (NMR), gel permeation chromatography (GPC), photoluminescence, ultraviolet (UV) spectroscopy, scanning electron microscopy (SEM), polarimetry, dynamic light scattering (DLS), and thermogravimetric analysis (TGA). Notably, the polymers exhibited remarkable aggregation-induced emission (AIE) and aggregation-induced polarization (AIP) phenomena, revealing enhanced luminescence and optical activity in aggregated states. These findings underscore the potential of these chiral polymers for applications in optoelectronics and advanced sensing technologies, highlighting the intricate relationship between molecular structure and optical behavior.https://www.mdpi.com/1420-3049/30/7/1567multilayer 3D chiral polymeraggregation-induced emission |
| spellingShingle | Sai Zhang Xiaobei Jin Daixiang Chen Qingzheng Xu Tao Wang Xiuyuan Qin Jialing Mao Yue Zhang Shenghu Yan Guigen Li Synthesis and Characterization of Multilayer 3D Chiral Polymers with Enhanced Optical Properties Molecules multilayer 3D chiral polymer aggregation-induced emission |
| title | Synthesis and Characterization of Multilayer 3D Chiral Polymers with Enhanced Optical Properties |
| title_full | Synthesis and Characterization of Multilayer 3D Chiral Polymers with Enhanced Optical Properties |
| title_fullStr | Synthesis and Characterization of Multilayer 3D Chiral Polymers with Enhanced Optical Properties |
| title_full_unstemmed | Synthesis and Characterization of Multilayer 3D Chiral Polymers with Enhanced Optical Properties |
| title_short | Synthesis and Characterization of Multilayer 3D Chiral Polymers with Enhanced Optical Properties |
| title_sort | synthesis and characterization of multilayer 3d chiral polymers with enhanced optical properties |
| topic | multilayer 3D chiral polymer aggregation-induced emission |
| url | https://www.mdpi.com/1420-3049/30/7/1567 |
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