Chemical Vapor Deposition Strategy of Fe‐N‐C Nanotubes for the Oxygen Evolution Reaction
Abstract The conversion of metal‐nitrogen‐carbon (M‐N‐C) nanoparticles derived from conventional metal‐organic frameworks (MOFs) into self‐supporting and well‐defined metal‐nitrogen‐carbon (M‐N‐C) superstructures is essential for various functional applications but remains a significant challenge. I...
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2025-05-01
|
| Series: | Advanced Science |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/advs.202413035 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849694204733685760 |
|---|---|
| author | Xin Liu Tao Wei Jonas Englhard Maïssa Barr Andreas Hirsch Julien Bachmann |
| author_facet | Xin Liu Tao Wei Jonas Englhard Maïssa Barr Andreas Hirsch Julien Bachmann |
| author_sort | Xin Liu |
| collection | DOAJ |
| description | Abstract The conversion of metal‐nitrogen‐carbon (M‐N‐C) nanoparticles derived from conventional metal‐organic frameworks (MOFs) into self‐supporting and well‐defined metal‐nitrogen‐carbon (M‐N‐C) superstructures is essential for various functional applications but remains a significant challenge. In this study, a versatile chemical vapor deposition (CVD) strategy is developed for solvent‐free synthesis of self‐supporting carbonaceous nanotubes doped with metal and nitrogen (MNCT). The stable carbonaceous nanotubes doped with Fe and N (FeNCT) fabricated here exhibit excellent electrocatalytic performances for the oxygen evolution reaction (OER) and outperform the carbonaceous film doped with Fe and N grown on carbon foil directly (FeNC/CF), which demonstrates the advantages of the superstructure of FeNCT. This strategy also provides a way to tailor the metal‐nitrogen‐carbon nanotubes (MNCT) catalyst according to the feature of the reactor and exhibits many advantages, such as wide applicability and facile scalability. |
| format | Article |
| id | doaj-art-52fb5fdc8a3f4df5b5609ac28976e80c |
| institution | DOAJ |
| issn | 2198-3844 |
| language | English |
| publishDate | 2025-05-01 |
| publisher | Wiley |
| record_format | Article |
| series | Advanced Science |
| spelling | doaj-art-52fb5fdc8a3f4df5b5609ac28976e80c2025-08-20T03:20:10ZengWileyAdvanced Science2198-38442025-05-011220n/an/a10.1002/advs.202413035Chemical Vapor Deposition Strategy of Fe‐N‐C Nanotubes for the Oxygen Evolution ReactionXin Liu0Tao Wei1Jonas Englhard2Maïssa Barr3Andreas Hirsch4Julien Bachmann5Chemistry of Thin Film Materials Section Materials Chemistry Department of Chemistry and Pharmacy Friedrich‐Alexander‐Universität Erlangen‐Nürnberg (FAU) IZNF, Cauerstr. 3 91058 Erlangen GermanyDepartment of Chemistry and Pharmacy & Joint Institute of Advanced Materials and Processes (ZMP) Friedrich‐Alexander University of Erlangen‐Nürnberg (FAU) Nikolaus‐Fiebiger‐Strasse 10 91058 Erlangen GermanyChemistry of Thin Film Materials Section Materials Chemistry Department of Chemistry and Pharmacy Friedrich‐Alexander‐Universität Erlangen‐Nürnberg (FAU) IZNF, Cauerstr. 3 91058 Erlangen GermanyChemistry of Thin Film Materials Section Materials Chemistry Department of Chemistry and Pharmacy Friedrich‐Alexander‐Universität Erlangen‐Nürnberg (FAU) IZNF, Cauerstr. 3 91058 Erlangen GermanyDepartment of Chemistry and Pharmacy & Joint Institute of Advanced Materials and Processes (ZMP) Friedrich‐Alexander University of Erlangen‐Nürnberg (FAU) Nikolaus‐Fiebiger‐Strasse 10 91058 Erlangen GermanyChemistry of Thin Film Materials Section Materials Chemistry Department of Chemistry and Pharmacy Friedrich‐Alexander‐Universität Erlangen‐Nürnberg (FAU) IZNF, Cauerstr. 3 91058 Erlangen GermanyAbstract The conversion of metal‐nitrogen‐carbon (M‐N‐C) nanoparticles derived from conventional metal‐organic frameworks (MOFs) into self‐supporting and well‐defined metal‐nitrogen‐carbon (M‐N‐C) superstructures is essential for various functional applications but remains a significant challenge. In this study, a versatile chemical vapor deposition (CVD) strategy is developed for solvent‐free synthesis of self‐supporting carbonaceous nanotubes doped with metal and nitrogen (MNCT). The stable carbonaceous nanotubes doped with Fe and N (FeNCT) fabricated here exhibit excellent electrocatalytic performances for the oxygen evolution reaction (OER) and outperform the carbonaceous film doped with Fe and N grown on carbon foil directly (FeNC/CF), which demonstrates the advantages of the superstructure of FeNCT. This strategy also provides a way to tailor the metal‐nitrogen‐carbon nanotubes (MNCT) catalyst according to the feature of the reactor and exhibits many advantages, such as wide applicability and facile scalability.https://doi.org/10.1002/advs.202413035atomic layer depositioncarbon‐based materialschemical vapor depositionelectrocatalysisnanotubeoxygen evolution reaction |
| spellingShingle | Xin Liu Tao Wei Jonas Englhard Maïssa Barr Andreas Hirsch Julien Bachmann Chemical Vapor Deposition Strategy of Fe‐N‐C Nanotubes for the Oxygen Evolution Reaction Advanced Science atomic layer deposition carbon‐based materials chemical vapor deposition electrocatalysis nanotube oxygen evolution reaction |
| title | Chemical Vapor Deposition Strategy of Fe‐N‐C Nanotubes for the Oxygen Evolution Reaction |
| title_full | Chemical Vapor Deposition Strategy of Fe‐N‐C Nanotubes for the Oxygen Evolution Reaction |
| title_fullStr | Chemical Vapor Deposition Strategy of Fe‐N‐C Nanotubes for the Oxygen Evolution Reaction |
| title_full_unstemmed | Chemical Vapor Deposition Strategy of Fe‐N‐C Nanotubes for the Oxygen Evolution Reaction |
| title_short | Chemical Vapor Deposition Strategy of Fe‐N‐C Nanotubes for the Oxygen Evolution Reaction |
| title_sort | chemical vapor deposition strategy of fe n c nanotubes for the oxygen evolution reaction |
| topic | atomic layer deposition carbon‐based materials chemical vapor deposition electrocatalysis nanotube oxygen evolution reaction |
| url | https://doi.org/10.1002/advs.202413035 |
| work_keys_str_mv | AT xinliu chemicalvapordepositionstrategyoffencnanotubesfortheoxygenevolutionreaction AT taowei chemicalvapordepositionstrategyoffencnanotubesfortheoxygenevolutionreaction AT jonasenglhard chemicalvapordepositionstrategyoffencnanotubesfortheoxygenevolutionreaction AT maissabarr chemicalvapordepositionstrategyoffencnanotubesfortheoxygenevolutionreaction AT andreashirsch chemicalvapordepositionstrategyoffencnanotubesfortheoxygenevolutionreaction AT julienbachmann chemicalvapordepositionstrategyoffencnanotubesfortheoxygenevolutionreaction |