Opening new frontiers with catalytic nucleic acids in miRNA inhibition

The concept of utilizing synthetic nucleic acids and their conjugates with biologically active molecules as RNA-targeted therapeutic agents represents a powerful strategy in the treatment of human pathologies. Recent research demonstrates that neoplastic development is closely associated with dysreg...

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Main Authors: Olga Patutina, Svetlana Miroshnichenko, Daria Chiglintseva, Marina Zenkova
Format: Article
Language:English
Published: Frontiers Media S.A. 2025-06-01
Series:Frontiers in Pharmacology
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Online Access:https://www.frontiersin.org/articles/10.3389/fphar.2025.1604711/full
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author Olga Patutina
Svetlana Miroshnichenko
Daria Chiglintseva
Marina Zenkova
author_facet Olga Patutina
Svetlana Miroshnichenko
Daria Chiglintseva
Marina Zenkova
author_sort Olga Patutina
collection DOAJ
description The concept of utilizing synthetic nucleic acids and their conjugates with biologically active molecules as RNA-targeted therapeutic agents represents a powerful strategy in the treatment of human pathologies. Recent research demonstrates that neoplastic development is closely associated with dysregulation of miRNAs, which are essential regulators of gene expression, highlighting the potential of therapeutic strategies aimed at their inhibition. Current approaches to pathological microRNA (miRNA) regulation primarily rely on physical blocking or sequestration mechanisms. However, these non-enzymatic strategies are limited by their stoichiometric nature, necessitating high drug doses to achieve therapeutic efficacy. A promising alternative lies in the application of catalytic nucleic acids, including miRNA-targeted ribozymes, DNAzymes/XNAzymes (antimiRzymes), and artificial ribonucleases (miRNases), which enable selective suppression of overexpressed miRNAs in pathological conditions through multiple enzymatic cleavage events. This review examines the fundamental principles governing the design of currently developed antimiRzymes and miRNases, analyzes their ribonuclease activity using synthetic miRNA substrates, and discusses key achievements in miRNA-inhibiting capability in tumor cells, along with their antitumor effects. Being effective RNA cleavers, these catalytic nucleic acids demonstrate remarkable potential, often surpassing the efficacy of conventional antisense oligonucleotides, and represent a promising therapeutic modality for RNA-associated diseases.
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publishDate 2025-06-01
publisher Frontiers Media S.A.
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spelling doaj-art-52bd5392b8b24ad0a1ffda9e1ccf41182025-08-20T02:10:23ZengFrontiers Media S.A.Frontiers in Pharmacology1663-98122025-06-011610.3389/fphar.2025.16047111604711Opening new frontiers with catalytic nucleic acids in miRNA inhibitionOlga PatutinaSvetlana MiroshnichenkoDaria ChiglintsevaMarina ZenkovaThe concept of utilizing synthetic nucleic acids and their conjugates with biologically active molecules as RNA-targeted therapeutic agents represents a powerful strategy in the treatment of human pathologies. Recent research demonstrates that neoplastic development is closely associated with dysregulation of miRNAs, which are essential regulators of gene expression, highlighting the potential of therapeutic strategies aimed at their inhibition. Current approaches to pathological microRNA (miRNA) regulation primarily rely on physical blocking or sequestration mechanisms. However, these non-enzymatic strategies are limited by their stoichiometric nature, necessitating high drug doses to achieve therapeutic efficacy. A promising alternative lies in the application of catalytic nucleic acids, including miRNA-targeted ribozymes, DNAzymes/XNAzymes (antimiRzymes), and artificial ribonucleases (miRNases), which enable selective suppression of overexpressed miRNAs in pathological conditions through multiple enzymatic cleavage events. This review examines the fundamental principles governing the design of currently developed antimiRzymes and miRNases, analyzes their ribonuclease activity using synthetic miRNA substrates, and discusses key achievements in miRNA-inhibiting capability in tumor cells, along with their antitumor effects. Being effective RNA cleavers, these catalytic nucleic acids demonstrate remarkable potential, often surpassing the efficacy of conventional antisense oligonucleotides, and represent a promising therapeutic modality for RNA-associated diseases.https://www.frontiersin.org/articles/10.3389/fphar.2025.1604711/fullcatalytic nucleic acidsmiRNAantimiRsDNAzymeribozymeantimiRzymes
spellingShingle Olga Patutina
Svetlana Miroshnichenko
Daria Chiglintseva
Marina Zenkova
Opening new frontiers with catalytic nucleic acids in miRNA inhibition
Frontiers in Pharmacology
catalytic nucleic acids
miRNA
antimiRs
DNAzyme
ribozyme
antimiRzymes
title Opening new frontiers with catalytic nucleic acids in miRNA inhibition
title_full Opening new frontiers with catalytic nucleic acids in miRNA inhibition
title_fullStr Opening new frontiers with catalytic nucleic acids in miRNA inhibition
title_full_unstemmed Opening new frontiers with catalytic nucleic acids in miRNA inhibition
title_short Opening new frontiers with catalytic nucleic acids in miRNA inhibition
title_sort opening new frontiers with catalytic nucleic acids in mirna inhibition
topic catalytic nucleic acids
miRNA
antimiRs
DNAzyme
ribozyme
antimiRzymes
url https://www.frontiersin.org/articles/10.3389/fphar.2025.1604711/full
work_keys_str_mv AT olgapatutina openingnewfrontierswithcatalyticnucleicacidsinmirnainhibition
AT svetlanamiroshnichenko openingnewfrontierswithcatalyticnucleicacidsinmirnainhibition
AT dariachiglintseva openingnewfrontierswithcatalyticnucleicacidsinmirnainhibition
AT marinazenkova openingnewfrontierswithcatalyticnucleicacidsinmirnainhibition