STUDY OF THE INSERTION AND EXTRACTION MECHANISM OF Li3Mn0.5Ti0.25O3

The metal oxide [Li3Mn0.5Ti0.25O3] was synthesized by solid state reaction crystallization method in certain temperature. It was an inverse spinel type compound metal oxide. The extraction/insertion reaction of this material was studied by X-ray, saturation exchange capacity value and distribution c...

Full description

Saved in:
Bibliographic Details
Main Authors: JINHE JIANG, FANGWANG LIU
Format: Article
Language:English
Published: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2017-12-01
Series:Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
Subjects:
Online Access:http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201704&vol=4&aid=4640
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850226110531371008
author JINHE JIANG
FANGWANG LIU
author_facet JINHE JIANG
FANGWANG LIU
author_sort JINHE JIANG
collection DOAJ
description The metal oxide [Li3Mn0.5Ti0.25O3] was synthesized by solid state reaction crystallization method in certain temperature. It was an inverse spinel type compound metal oxide. The extraction/insertion reaction of this material was studied by X-ray, saturation exchange capacity value and distribution coefficient (Kd) measurement value. In terms of its composition and chemical metrology, this inverse spinel material is very comprehensive; it is worth noting that it can be inserted or extracted by other substitutional ions and changes in lithium and oxygen stoichiometry while maintaining their crystal structure. The metal oxide [Li3Mn0.5Ti0.25O3] is inorganic Li+ exchanger which has an ion-memory capacity. It has high exchange selectivity ability for Li+. This metal oxide can be used to separate or extract Li+ in aqueous solution. The experimental result has confirmed inverse spinel type compound metal oxide which was treated by acid could attain 9.7 mmol‧g-1 Li+ exchanged capacity.
format Article
id doaj-art-52a1e147b2404ec589da4e01267d3c12
institution OA Journals
issn 1582-540X
1582-540X
language English
publishDate 2017-12-01
publisher Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
record_format Article
series Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
spelling doaj-art-52a1e147b2404ec589da4e01267d3c122025-08-20T02:05:10ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X1582-540X2017-12-01184449454STUDY OF THE INSERTION AND EXTRACTION MECHANISM OF Li3Mn0.5Ti0.25O3JINHE JIANG 0FANGWANG LIU1Weifang University, Department of Chemistry and Chemical Engineering, 261061, Weifang, China Qingdao University of Science and Technology, Department of Chemical Engineering, 266000, Qingdao, China The metal oxide [Li3Mn0.5Ti0.25O3] was synthesized by solid state reaction crystallization method in certain temperature. It was an inverse spinel type compound metal oxide. The extraction/insertion reaction of this material was studied by X-ray, saturation exchange capacity value and distribution coefficient (Kd) measurement value. In terms of its composition and chemical metrology, this inverse spinel material is very comprehensive; it is worth noting that it can be inserted or extracted by other substitutional ions and changes in lithium and oxygen stoichiometry while maintaining their crystal structure. The metal oxide [Li3Mn0.5Ti0.25O3] is inorganic Li+ exchanger which has an ion-memory capacity. It has high exchange selectivity ability for Li+. This metal oxide can be used to separate or extract Li+ in aqueous solution. The experimental result has confirmed inverse spinel type compound metal oxide which was treated by acid could attain 9.7 mmol‧g-1 Li+ exchanged capacity.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201704&vol=4&aid=4640insertion and extraction rateion-exchange mechanisminverse spinel typemetal oxide Li3Mn0.5Ti0.25O3selective capability
spellingShingle JINHE JIANG
FANGWANG LIU
STUDY OF THE INSERTION AND EXTRACTION MECHANISM OF Li3Mn0.5Ti0.25O3
Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
insertion and extraction rate
ion-exchange mechanism
inverse spinel type
metal oxide Li3Mn0.5Ti0.25O3
selective capability
title STUDY OF THE INSERTION AND EXTRACTION MECHANISM OF Li3Mn0.5Ti0.25O3
title_full STUDY OF THE INSERTION AND EXTRACTION MECHANISM OF Li3Mn0.5Ti0.25O3
title_fullStr STUDY OF THE INSERTION AND EXTRACTION MECHANISM OF Li3Mn0.5Ti0.25O3
title_full_unstemmed STUDY OF THE INSERTION AND EXTRACTION MECHANISM OF Li3Mn0.5Ti0.25O3
title_short STUDY OF THE INSERTION AND EXTRACTION MECHANISM OF Li3Mn0.5Ti0.25O3
title_sort study of the insertion and extraction mechanism of li3mn0 5ti0 25o3
topic insertion and extraction rate
ion-exchange mechanism
inverse spinel type
metal oxide Li3Mn0.5Ti0.25O3
selective capability
url http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201704&vol=4&aid=4640
work_keys_str_mv AT jinhejiang studyoftheinsertionandextractionmechanismofli3mn05ti025o3
AT fangwangliu studyoftheinsertionandextractionmechanismofli3mn05ti025o3