Dual-mode glucose sensing: Colorimetric chemical sensors using silver or gold nanoparticles embedded within polymethacrylate matrix

We suggest sensor systems based on the gold and silver nanoparticles embedded within the polymethacrylate matrix (PMM) for colorimetric determination of glucose. A feature of such sensors is the exclusion of the use of toxic solvents in their manufacture and application. In addition, silver and gold...

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Main Authors: Nadezhda V. Saranchina, Olga A. Bazhenova, Dmitrii A. Shcherbakov, Nataliya A. Gavrilenko, Kirill V. Serebriakov, Darya E. Kuznetsova, Mikhail A. Gavrilenko
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Green Analytical Chemistry
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Online Access:http://www.sciencedirect.com/science/article/pii/S2772577425000746
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author Nadezhda V. Saranchina
Olga A. Bazhenova
Dmitrii A. Shcherbakov
Nataliya A. Gavrilenko
Kirill V. Serebriakov
Darya E. Kuznetsova
Mikhail A. Gavrilenko
author_facet Nadezhda V. Saranchina
Olga A. Bazhenova
Dmitrii A. Shcherbakov
Nataliya A. Gavrilenko
Kirill V. Serebriakov
Darya E. Kuznetsova
Mikhail A. Gavrilenko
author_sort Nadezhda V. Saranchina
collection DOAJ
description We suggest sensor systems based on the gold and silver nanoparticles embedded within the polymethacrylate matrix (PMM) for colorimetric determination of glucose. A feature of such sensors is the exclusion of the use of toxic solvents in their manufacture and application. In addition, silver and gold nanoparticles are stabilized in a solid transparent polymer, which prevents migration into the environment. We studied the conditions of interaction between the gold and silver nanoparticles and matrix components by evaluating the influence of such factors as solution pH, the amount of nanoparticles within the polymer matrix, the contact time, and the analyte concentration upon the analytical signal. Dual-signal spectrophotometric and colorimetric approaches of using PMM-Ag0 / PMM-Au° can be used for the determination of glucose in saliva in the range of 0.1–5.6 mM with the limit of detection of 0.04 mM and 0.1–1.0 mM with the limit of detection of 0.03 mM, accordingly.
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issn 2772-5774
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publishDate 2025-06-01
publisher Elsevier
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series Green Analytical Chemistry
spelling doaj-art-528eaa7ec116447d9d90cb1b9a05005e2025-08-20T03:10:27ZengElsevierGreen Analytical Chemistry2772-57742025-06-011310027810.1016/j.greeac.2025.100278Dual-mode glucose sensing: Colorimetric chemical sensors using silver or gold nanoparticles embedded within polymethacrylate matrixNadezhda V. Saranchina0Olga A. Bazhenova1Dmitrii A. Shcherbakov2Nataliya A. Gavrilenko3Kirill V. Serebriakov4Darya E. Kuznetsova5Mikhail A. Gavrilenko6Tomsk Polytechnic University, 634050 Tomsk, Russian FederationTomsk Polytechnic University, 634050 Tomsk, Russian FederationTomsk State University, 634050 Tomsk, Russian FederationTomsk State University, 634050 Tomsk, Russian FederationTomsk Polytechnic University, 634050 Tomsk, Russian FederationTomsk State University, 634050 Tomsk, Russian FederationTomsk Polytechnic University, 634050 Tomsk, Russian Federation; Corresponding author.We suggest sensor systems based on the gold and silver nanoparticles embedded within the polymethacrylate matrix (PMM) for colorimetric determination of glucose. A feature of such sensors is the exclusion of the use of toxic solvents in their manufacture and application. In addition, silver and gold nanoparticles are stabilized in a solid transparent polymer, which prevents migration into the environment. We studied the conditions of interaction between the gold and silver nanoparticles and matrix components by evaluating the influence of such factors as solution pH, the amount of nanoparticles within the polymer matrix, the contact time, and the analyte concentration upon the analytical signal. Dual-signal spectrophotometric and colorimetric approaches of using PMM-Ag0 / PMM-Au° can be used for the determination of glucose in saliva in the range of 0.1–5.6 mM with the limit of detection of 0.04 mM and 0.1–1.0 mM with the limit of detection of 0.03 mM, accordingly.http://www.sciencedirect.com/science/article/pii/S2772577425000746GlucoseGold nanoparticlesSilver nanoparticlesPolymethacrylate matrixSolid phase spectrophotometryDigital colorimetry
spellingShingle Nadezhda V. Saranchina
Olga A. Bazhenova
Dmitrii A. Shcherbakov
Nataliya A. Gavrilenko
Kirill V. Serebriakov
Darya E. Kuznetsova
Mikhail A. Gavrilenko
Dual-mode glucose sensing: Colorimetric chemical sensors using silver or gold nanoparticles embedded within polymethacrylate matrix
Green Analytical Chemistry
Glucose
Gold nanoparticles
Silver nanoparticles
Polymethacrylate matrix
Solid phase spectrophotometry
Digital colorimetry
title Dual-mode glucose sensing: Colorimetric chemical sensors using silver or gold nanoparticles embedded within polymethacrylate matrix
title_full Dual-mode glucose sensing: Colorimetric chemical sensors using silver or gold nanoparticles embedded within polymethacrylate matrix
title_fullStr Dual-mode glucose sensing: Colorimetric chemical sensors using silver or gold nanoparticles embedded within polymethacrylate matrix
title_full_unstemmed Dual-mode glucose sensing: Colorimetric chemical sensors using silver or gold nanoparticles embedded within polymethacrylate matrix
title_short Dual-mode glucose sensing: Colorimetric chemical sensors using silver or gold nanoparticles embedded within polymethacrylate matrix
title_sort dual mode glucose sensing colorimetric chemical sensors using silver or gold nanoparticles embedded within polymethacrylate matrix
topic Glucose
Gold nanoparticles
Silver nanoparticles
Polymethacrylate matrix
Solid phase spectrophotometry
Digital colorimetry
url http://www.sciencedirect.com/science/article/pii/S2772577425000746
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