Rapid and Efficient Synthesis of ω-Alkylenediphosphoric Acids from Phosphorus Oxychloride
The aim of this investigation was to develop an efficient, rapid, and selective method for the synthesis of ω-alkylenediphosphoric acids (HO)2(O)P-O-CH2n-O-P(O)(OH)2 from reaction of several diols with phosphorus oxychloride. The reaction was investigated using three methodologies: (i) presence of a...
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| Format: | Article |
| Language: | English |
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Wiley
2016-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2016/8046893 |
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| _version_ | 1850227012187193344 |
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| author | Dalila Meziane Abdelhamid Elias Erwann Guénin |
| author_facet | Dalila Meziane Abdelhamid Elias Erwann Guénin |
| author_sort | Dalila Meziane |
| collection | DOAJ |
| description | The aim of this investigation was to develop an efficient, rapid, and selective method for the synthesis of ω-alkylenediphosphoric acids (HO)2(O)P-O-CH2n-O-P(O)(OH)2 from reaction of several diols with phosphorus oxychloride. The reaction was investigated using three methodologies: (i) presence of a base, (ii) classical heating, and (iii) use of microwave irradiation. Influence of reaction temperature and molar ratio of reagents, as well as the nature of the solvent, was studied using these three different methods. |
| format | Article |
| id | doaj-art-517776e6b17c4ed99ca1159ed6d3ce5e |
| institution | OA Journals |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2016-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-517776e6b17c4ed99ca1159ed6d3ce5e2025-08-20T02:04:55ZengWileyJournal of Chemistry2090-90632090-90712016-01-01201610.1155/2016/80468938046893Rapid and Efficient Synthesis of ω-Alkylenediphosphoric Acids from Phosphorus OxychlorideDalila Meziane0Abdelhamid Elias1Erwann Guénin2Département de Chimie, Faculté des Sciences, Université Mouloud Mammeri, BP 17 RP, 15000 Tizi Ouzou, AlgeriaDépartement de Chimie, Faculté des Sciences, Université Mouloud Mammeri, BP 17 RP, 15000 Tizi Ouzou, AlgeriaUFR SMBH, Université Paris 13, Sorbonne Paris Cité, 74 rue Marcel Cachin, 93017 Bobigny, FranceThe aim of this investigation was to develop an efficient, rapid, and selective method for the synthesis of ω-alkylenediphosphoric acids (HO)2(O)P-O-CH2n-O-P(O)(OH)2 from reaction of several diols with phosphorus oxychloride. The reaction was investigated using three methodologies: (i) presence of a base, (ii) classical heating, and (iii) use of microwave irradiation. Influence of reaction temperature and molar ratio of reagents, as well as the nature of the solvent, was studied using these three different methods.http://dx.doi.org/10.1155/2016/8046893 |
| spellingShingle | Dalila Meziane Abdelhamid Elias Erwann Guénin Rapid and Efficient Synthesis of ω-Alkylenediphosphoric Acids from Phosphorus Oxychloride Journal of Chemistry |
| title | Rapid and Efficient Synthesis of ω-Alkylenediphosphoric Acids from Phosphorus Oxychloride |
| title_full | Rapid and Efficient Synthesis of ω-Alkylenediphosphoric Acids from Phosphorus Oxychloride |
| title_fullStr | Rapid and Efficient Synthesis of ω-Alkylenediphosphoric Acids from Phosphorus Oxychloride |
| title_full_unstemmed | Rapid and Efficient Synthesis of ω-Alkylenediphosphoric Acids from Phosphorus Oxychloride |
| title_short | Rapid and Efficient Synthesis of ω-Alkylenediphosphoric Acids from Phosphorus Oxychloride |
| title_sort | rapid and efficient synthesis of ω alkylenediphosphoric acids from phosphorus oxychloride |
| url | http://dx.doi.org/10.1155/2016/8046893 |
| work_keys_str_mv | AT dalilameziane rapidandefficientsynthesisofōalkylenediphosphoricacidsfromphosphorusoxychloride AT abdelhamidelias rapidandefficientsynthesisofōalkylenediphosphoricacidsfromphosphorusoxychloride AT erwannguenin rapidandefficientsynthesisofōalkylenediphosphoricacidsfromphosphorusoxychloride |