Synthesis, characterization of polytridecamethylene 2,6-naphthalamide as semiaromatic polyamide containing naphthalene-ring
A novel engineering plastic polytridecamethylene 2,6-naphthalamide (PA13N) was prepared via a reaction of 2,6-naphthalene dicarboxylic acid and 1,13-tridecanediamine through a three-step procedure. The structure of synthesized PA13N was characterized by elemental analysis, Fourier transform infrared...
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| Language: | English |
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Budapest University of Technology and Economics
2010-07-01
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| Series: | eXPRESS Polymer Letters |
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| Online Access: | http://www.expresspolymlett.com/letolt.php?file=EPL-0001491&mi=cd |
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| description | A novel engineering plastic polytridecamethylene 2,6-naphthalamide (PA13N) was prepared via a reaction of 2,6-naphthalene dicarboxylic acid and 1,13-tridecanediamine through a three-step procedure. The structure of synthesized PA13N was characterized by elemental analysis, Fourier transform infrared (FT-IR) spectroscopy and proton nuclear magnetic resonance (1H-NMR). The thermal behaviors were determined by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA). The solubility, water-absorbing capacity, and mechanical properties of PA13N have also been investigated. Melting temperature (Tm), glass transition temperature (Tg) and decomposition temperature (Td) of PA13N are 288, 129 and 492°C, respectively. The results show that the heat resistance and mechanical properties of PA13N are near to those of polynonamethylene terephthalamide (PA9T), and PA13N is a promising heat-resistant and processable engineering plastic. |
| format | Article |
| id | doaj-art-514026a928cb4da1b1ab5961a3e640f2 |
| institution | Kabale University |
| issn | 1788-618X |
| language | English |
| publishDate | 2010-07-01 |
| publisher | Budapest University of Technology and Economics |
| record_format | Article |
| series | eXPRESS Polymer Letters |
| spelling | doaj-art-514026a928cb4da1b1ab5961a3e640f22025-08-20T03:56:13ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2010-07-014744244910.3144/expresspolymlett.2010.55Synthesis, characterization of polytridecamethylene 2,6-naphthalamide as semiaromatic polyamide containing naphthalene-ringA novel engineering plastic polytridecamethylene 2,6-naphthalamide (PA13N) was prepared via a reaction of 2,6-naphthalene dicarboxylic acid and 1,13-tridecanediamine through a three-step procedure. The structure of synthesized PA13N was characterized by elemental analysis, Fourier transform infrared (FT-IR) spectroscopy and proton nuclear magnetic resonance (1H-NMR). The thermal behaviors were determined by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA). The solubility, water-absorbing capacity, and mechanical properties of PA13N have also been investigated. Melting temperature (Tm), glass transition temperature (Tg) and decomposition temperature (Td) of PA13N are 288, 129 and 492°C, respectively. The results show that the heat resistance and mechanical properties of PA13N are near to those of polynonamethylene terephthalamide (PA9T), and PA13N is a promising heat-resistant and processable engineering plastic.http://www.expresspolymlett.com/letolt.php?file=EPL-0001491&mi=cdMechanical propertiesthermal propertiespolyamidessynthesispolycondensation |
| spellingShingle | Synthesis, characterization of polytridecamethylene 2,6-naphthalamide as semiaromatic polyamide containing naphthalene-ring eXPRESS Polymer Letters Mechanical properties thermal properties polyamides synthesis polycondensation |
| title | Synthesis, characterization of polytridecamethylene 2,6-naphthalamide as semiaromatic polyamide containing naphthalene-ring |
| title_full | Synthesis, characterization of polytridecamethylene 2,6-naphthalamide as semiaromatic polyamide containing naphthalene-ring |
| title_fullStr | Synthesis, characterization of polytridecamethylene 2,6-naphthalamide as semiaromatic polyamide containing naphthalene-ring |
| title_full_unstemmed | Synthesis, characterization of polytridecamethylene 2,6-naphthalamide as semiaromatic polyamide containing naphthalene-ring |
| title_short | Synthesis, characterization of polytridecamethylene 2,6-naphthalamide as semiaromatic polyamide containing naphthalene-ring |
| title_sort | synthesis characterization of polytridecamethylene 2 6 naphthalamide as semiaromatic polyamide containing naphthalene ring |
| topic | Mechanical properties thermal properties polyamides synthesis polycondensation |
| url | http://www.expresspolymlett.com/letolt.php?file=EPL-0001491&mi=cd |