Inverse effect in simultaneous thermal and radiation aging of EVA insulation

Poly(ethylene-co-vinyl acetate) (EVA) insulation of the cable applied in nuclear power plants was accelerated aged by gamma-rays at two various temperatures, namely 55 and 85°C. Radiation degradation in the dose range of 0–1500 kGy was monitored using a Differential Scanning Calorimetry method by me...

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Main Authors: G. Przybytniak, J. Boguski, V. Placek, L. Verardi, D. Fabiani, E. Linde, U. W. Gedde
Format: Article
Language:English
Published: Budapest University of Technology and Economics 2015-04-01
Series:eXPRESS Polymer Letters
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Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0005694&mi=cd
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author G. Przybytniak
J. Boguski
V. Placek
L. Verardi
D. Fabiani
E. Linde
U. W. Gedde
author_facet G. Przybytniak
J. Boguski
V. Placek
L. Verardi
D. Fabiani
E. Linde
U. W. Gedde
author_sort G. Przybytniak
collection DOAJ
description Poly(ethylene-co-vinyl acetate) (EVA) insulation of the cable applied in nuclear power plants was accelerated aged by gamma-rays at two various temperatures, namely 55 and 85°C. Radiation degradation in the dose range of 0–1500 kGy was monitored using a Differential Scanning Calorimetry method by measuring oxidative induction temperature (OITp), gel fraction, mechanical and electrical tests. It was confirmed that a dose rate effect in the range of 420–1500 Gy/h was negligible whereas progress of degradation with increasing dose was strongly temperature dependent. For the insulation accelerated aged at 85°C the OITp and permittivity measurements confirmed lower degradation than for the specimens radiation treated at 55°C at the same dose rates. It was postulated that an inverse thermal effect resulted from radiation induced cross-linking facilitated by melting of EVA crystallites at 85°C.
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institution Kabale University
issn 1788-618X
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publishDate 2015-04-01
publisher Budapest University of Technology and Economics
record_format Article
series eXPRESS Polymer Letters
spelling doaj-art-5069ecdd266840f5b351d4ae720864c82025-08-20T03:34:35ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2015-04-019438439310.3144/expresspolymlett.2015.36Inverse effect in simultaneous thermal and radiation aging of EVA insulationG. PrzybytniakJ. BoguskiV. PlacekL. VerardiD. FabianiE. LindeU. W. GeddePoly(ethylene-co-vinyl acetate) (EVA) insulation of the cable applied in nuclear power plants was accelerated aged by gamma-rays at two various temperatures, namely 55 and 85°C. Radiation degradation in the dose range of 0–1500 kGy was monitored using a Differential Scanning Calorimetry method by measuring oxidative induction temperature (OITp), gel fraction, mechanical and electrical tests. It was confirmed that a dose rate effect in the range of 420–1500 Gy/h was negligible whereas progress of degradation with increasing dose was strongly temperature dependent. For the insulation accelerated aged at 85°C the OITp and permittivity measurements confirmed lower degradation than for the specimens radiation treated at 55°C at the same dose rates. It was postulated that an inverse thermal effect resulted from radiation induced cross-linking facilitated by melting of EVA crystallites at 85°C.http://www.expresspolymlett.com/letolt.php?file=EPL-0005694&mi=cdMaterial testingradiation degradationthermal degradationinverse thermal effectpoly(ethylene-co-vinyl acetate
spellingShingle G. Przybytniak
J. Boguski
V. Placek
L. Verardi
D. Fabiani
E. Linde
U. W. Gedde
Inverse effect in simultaneous thermal and radiation aging of EVA insulation
eXPRESS Polymer Letters
Material testing
radiation degradation
thermal degradation
inverse thermal effect
poly(ethylene-co-vinyl acetate
title Inverse effect in simultaneous thermal and radiation aging of EVA insulation
title_full Inverse effect in simultaneous thermal and radiation aging of EVA insulation
title_fullStr Inverse effect in simultaneous thermal and radiation aging of EVA insulation
title_full_unstemmed Inverse effect in simultaneous thermal and radiation aging of EVA insulation
title_short Inverse effect in simultaneous thermal and radiation aging of EVA insulation
title_sort inverse effect in simultaneous thermal and radiation aging of eva insulation
topic Material testing
radiation degradation
thermal degradation
inverse thermal effect
poly(ethylene-co-vinyl acetate
url http://www.expresspolymlett.com/letolt.php?file=EPL-0005694&mi=cd
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