Studying of the conjugate catalytics degidration of methanol to formaldehyde in the presence of hydrogen peroxide
From the studies of the kinetics of methanol conjugate dehydration process, a kinetic model has been proposed and kinetic parameters calculated. It was discovered that when other substances like ethane, ethylene were used as initiators the catalyst surface coked rapidly. On the K-1 model in the pres...
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| Format: | Article |
| Language: | Russian |
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MIREA - Russian Technological University
2009-08-01
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| Series: | Тонкие химические технологии |
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| Online Access: | https://www.finechem-mirea.ru/jour/article/view/1081 |
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| author | V. F. Tretyakov A. M. Ilolov N. A. Frantsuzova R. M. Talyshinsk |
| author_facet | V. F. Tretyakov A. M. Ilolov N. A. Frantsuzova R. M. Talyshinsk |
| author_sort | V. F. Tretyakov |
| collection | DOAJ |
| description | From the studies of the kinetics of methanol conjugate dehydration process, a kinetic model has been proposed and kinetic parameters calculated. It was discovered that when other substances like ethane, ethylene were used as initiators the catalyst surface coked rapidly. On the K-1 model in the presence of hydrogen peroxide (1% in water solution of the initial methanol) the temperature of the dehydration process reduces by 50-60ºС at 50% formaldehyde yield and allows for the reaction to be carried out at a temperature of 820-830ºС |
| format | Article |
| id | doaj-art-5063ebeebb4149069b0f4ff114804287 |
| institution | Kabale University |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| publishDate | 2009-08-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj-art-5063ebeebb4149069b0f4ff1148042872025-08-20T03:56:24ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752009-08-014460701075Studying of the conjugate catalytics degidration of methanol to formaldehyde in the presence of hydrogen peroxideV. F. Tretyakov0A. M. Ilolov1N. A. Frantsuzova2R. M. Talyshinsk3M.V. Lomonosov Moscow State University of Fine Chemical Technologies,86, Vernadskogo pr., Moscow 119571Институт нефтехимического синтеза им. А.В. Топчиева РАНM.V. Lomonosov Moscow State University of Fine Chemical Technologies,86, Vernadskogo pr., Moscow 119571Институт нефтехимического синтеза им. А.В. Топчиева РАНFrom the studies of the kinetics of methanol conjugate dehydration process, a kinetic model has been proposed and kinetic parameters calculated. It was discovered that when other substances like ethane, ethylene were used as initiators the catalyst surface coked rapidly. On the K-1 model in the presence of hydrogen peroxide (1% in water solution of the initial methanol) the temperature of the dehydration process reduces by 50-60ºС at 50% formaldehyde yield and allows for the reaction to be carried out at a temperature of 820-830ºСhttps://www.finechem-mirea.ru/jour/article/view/1081methanol, formaldehyde, dehydration, cataliytic conjugatic, hydrogen peroxide |
| spellingShingle | V. F. Tretyakov A. M. Ilolov N. A. Frantsuzova R. M. Talyshinsk Studying of the conjugate catalytics degidration of methanol to formaldehyde in the presence of hydrogen peroxide Тонкие химические технологии methanol, formaldehyde, dehydration, cataliytic conjugatic, hydrogen peroxide |
| title | Studying of the conjugate catalytics degidration of methanol to formaldehyde in the presence of hydrogen peroxide |
| title_full | Studying of the conjugate catalytics degidration of methanol to formaldehyde in the presence of hydrogen peroxide |
| title_fullStr | Studying of the conjugate catalytics degidration of methanol to formaldehyde in the presence of hydrogen peroxide |
| title_full_unstemmed | Studying of the conjugate catalytics degidration of methanol to formaldehyde in the presence of hydrogen peroxide |
| title_short | Studying of the conjugate catalytics degidration of methanol to formaldehyde in the presence of hydrogen peroxide |
| title_sort | studying of the conjugate catalytics degidration of methanol to formaldehyde in the presence of hydrogen peroxide |
| topic | methanol, formaldehyde, dehydration, cataliytic conjugatic, hydrogen peroxide |
| url | https://www.finechem-mirea.ru/jour/article/view/1081 |
| work_keys_str_mv | AT vftretyakov studyingoftheconjugatecatalyticsdegidrationofmethanoltoformaldehydeinthepresenceofhydrogenperoxide AT amilolov studyingoftheconjugatecatalyticsdegidrationofmethanoltoformaldehydeinthepresenceofhydrogenperoxide AT nafrantsuzova studyingoftheconjugatecatalyticsdegidrationofmethanoltoformaldehydeinthepresenceofhydrogenperoxide AT rmtalyshinsk studyingoftheconjugatecatalyticsdegidrationofmethanoltoformaldehydeinthepresenceofhydrogenperoxide |