Biodegradable Oxygen‐Generating Microneedle Patches for Regenerative Medicine Applications

Upon injury, regenerating skin is metabolically active and requires oxygen for physiological processes related to wound healing. Such processes can be halted in hypoxic conditions common in chronic wounds. Microneedle arrays (MNAs) have been demonstrated to improve therapeutic delivery and wound hea...

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Main Authors: Lindsay Barnum, Mohamadmahdi Samandari, Yasir Suhail, Steven Toro, Ashkan Novin, Pejman Ghelich, Jacob Quint, Farnooosh Saeedinejad, Manu Komma, Kshitiz, Ali Tamayol
Format: Article
Language:English
Published: Wiley-VCH 2025-01-01
Series:Advanced NanoBiomed Research
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Online Access:https://doi.org/10.1002/anbr.202400093
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author Lindsay Barnum
Mohamadmahdi Samandari
Yasir Suhail
Steven Toro
Ashkan Novin
Pejman Ghelich
Jacob Quint
Farnooosh Saeedinejad
Manu Komma
Kshitiz
Ali Tamayol
author_facet Lindsay Barnum
Mohamadmahdi Samandari
Yasir Suhail
Steven Toro
Ashkan Novin
Pejman Ghelich
Jacob Quint
Farnooosh Saeedinejad
Manu Komma
Kshitiz
Ali Tamayol
author_sort Lindsay Barnum
collection DOAJ
description Upon injury, regenerating skin is metabolically active and requires oxygen for physiological processes related to wound healing. Such processes can be halted in hypoxic conditions common in chronic wounds. Microneedle arrays (MNAs) have been demonstrated to improve therapeutic delivery and wound healing. Recently, few studies have explored the use of oxygen‐releasing MNAs; however, they involve complex manufacturing and handling and fail to eliminate cytotoxic byproducts. To address these challenges, biodegradable and mechanically robust gelatin methacryloyl‐based MNAs are developed that can penetrate the tissue and release oxygen upon exposure to interstitial fluid and wound exudates. The oxygen release rate and biocompatibility of the developed MNAs with different compositions are evaluated and optimized. Interestingly, in vitro studies demonstrate that the optimized compositions can release oxygen at therapeutic levels and significantly increase viability of chronically hypoxic cells to match that of normoxic cells. In vivo studies further confirm that the optimized oxygen‐generating MNAs do not cause any harm or impair healing in a murine model of acute skin injury. Additionally, transcriptomic analysis reveals upregulation of key pathways related to fibroblast motility, lipid metabolism, and a marked reduction in inflammatory signaling, all of which contribute to improved wound healing. The developed strategy can introduce new opportunities in elimination of hypoxia and therefore treatment of chronic wounds.
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spelling doaj-art-504cd12fb72b445aade72255eb227b6f2025-08-20T02:43:43ZengWiley-VCHAdvanced NanoBiomed Research2699-93072025-01-0151n/an/a10.1002/anbr.202400093Biodegradable Oxygen‐Generating Microneedle Patches for Regenerative Medicine ApplicationsLindsay Barnum0Mohamadmahdi Samandari1Yasir Suhail2Steven Toro3Ashkan Novin4Pejman Ghelich5Jacob Quint6Farnooosh Saeedinejad7Manu Komma8Kshitiz9Ali Tamayol10Department of Biomedical Engineering University of Connecticut Health Center Farmington CT 06030 USADepartment of Biomedical Engineering University of Connecticut Health Center Farmington CT 06030 USADepartment of Biomedical Engineering University of Connecticut Health Center Farmington CT 06030 USADepartment of Biomedical Engineering University of Connecticut Health Center Farmington CT 06030 USADepartment of Biomedical Engineering University of Connecticut Health Center Farmington CT 06030 USADepartment of Biomedical Engineering University of Connecticut Health Center Farmington CT 06030 USADepartment of Biomedical Engineering University of Connecticut Health Center Farmington CT 06030 USADepartment of Biomedical Engineering University of Connecticut Health Center Farmington CT 06030 USADepartment of Biomedical Engineering University of Connecticut Health Center Farmington CT 06030 USADepartment of Biomedical Engineering University of Connecticut Health Center Farmington CT 06030 USADepartment of Biomedical Engineering University of Connecticut Health Center Farmington CT 06030 USAUpon injury, regenerating skin is metabolically active and requires oxygen for physiological processes related to wound healing. Such processes can be halted in hypoxic conditions common in chronic wounds. Microneedle arrays (MNAs) have been demonstrated to improve therapeutic delivery and wound healing. Recently, few studies have explored the use of oxygen‐releasing MNAs; however, they involve complex manufacturing and handling and fail to eliminate cytotoxic byproducts. To address these challenges, biodegradable and mechanically robust gelatin methacryloyl‐based MNAs are developed that can penetrate the tissue and release oxygen upon exposure to interstitial fluid and wound exudates. The oxygen release rate and biocompatibility of the developed MNAs with different compositions are evaluated and optimized. Interestingly, in vitro studies demonstrate that the optimized compositions can release oxygen at therapeutic levels and significantly increase viability of chronically hypoxic cells to match that of normoxic cells. In vivo studies further confirm that the optimized oxygen‐generating MNAs do not cause any harm or impair healing in a murine model of acute skin injury. Additionally, transcriptomic analysis reveals upregulation of key pathways related to fibroblast motility, lipid metabolism, and a marked reduction in inflammatory signaling, all of which contribute to improved wound healing. The developed strategy can introduce new opportunities in elimination of hypoxia and therefore treatment of chronic wounds.https://doi.org/10.1002/anbr.202400093biomaterialsGelMAmicroneedlesoxygen‐generating materialswound healing
spellingShingle Lindsay Barnum
Mohamadmahdi Samandari
Yasir Suhail
Steven Toro
Ashkan Novin
Pejman Ghelich
Jacob Quint
Farnooosh Saeedinejad
Manu Komma
Kshitiz
Ali Tamayol
Biodegradable Oxygen‐Generating Microneedle Patches for Regenerative Medicine Applications
Advanced NanoBiomed Research
biomaterials
GelMA
microneedles
oxygen‐generating materials
wound healing
title Biodegradable Oxygen‐Generating Microneedle Patches for Regenerative Medicine Applications
title_full Biodegradable Oxygen‐Generating Microneedle Patches for Regenerative Medicine Applications
title_fullStr Biodegradable Oxygen‐Generating Microneedle Patches for Regenerative Medicine Applications
title_full_unstemmed Biodegradable Oxygen‐Generating Microneedle Patches for Regenerative Medicine Applications
title_short Biodegradable Oxygen‐Generating Microneedle Patches for Regenerative Medicine Applications
title_sort biodegradable oxygen generating microneedle patches for regenerative medicine applications
topic biomaterials
GelMA
microneedles
oxygen‐generating materials
wound healing
url https://doi.org/10.1002/anbr.202400093
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