Obtaining of Nanocrystals ZnS:Mn by Means of Self-Propagating High-Temperature Synthesis

In the paper has been investigation optical properties and crystal structure of nanocrystals ZnS:Mn (dimension nanocrystals 6 ± 5 nm) by means of self-propagating high-temperature synthesis with impurity of MnCl2 and Mn(NO3)2. On the basis of analysis of EPR and X-Ray diffraction spectra has been sh...

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Bibliographic Details
Main Authors: M.F. Bulaniy, A.V. Kovalenko, A.S. Morozov, O.V. Khmelenko
Format: Article
Language:English
Published: Sumy State University 2017-04-01
Series:Журнал нано- та електронної фізики
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Online Access:http://jnep.sumdu.edu.ua/download/numbers/2017/2/articles/jnep_V9_02007.pdf
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Summary:In the paper has been investigation optical properties and crystal structure of nanocrystals ZnS:Mn (dimension nanocrystals 6 ± 5 nm) by means of self-propagating high-temperature synthesis with impurity of MnCl2 and Mn(NO3)2. On the basis of analysis of EPR and X-Ray diffraction spectra has been shown that nanocrystals of ZnS:Mn consist on 80 ± 5 % of hexagonal phase, in this nanocrystals also presence cubic phase of ZnS and hexagonal phase Mn0,75Zn0,25S, also ions Mn2+ presence in phase of ZnS and phase of Mn0,75Zn0,25S. It has been analyzes the redistribution intensity of individual bands of photoluminescence in nanocrystals compared with volume crystals of ZnS:Mn.
ISSN:2077-6772