Sulfonated Magnetic Nanocomposite Based on Reactive PGMA-MAn Copolymer@Fe3O4 Nanoparticles: Effective Removal of Cu(II) Ions from Aqueous Solutions
Chelating magnetic nanocomposites have been considered as suitable materials for removal of heavy metal ions for water treatment. In this work poly(glycidyl methacrylate-maleic anhydride) copolymer (PGMA-MAn) is modified with 4-aminobenzenesulfonic acid (ABSAc) and subsequently the product reacted w...
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| Language: | English |
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Wiley
2016-01-01
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| Series: | International Journal of Polymer Science |
| Online Access: | http://dx.doi.org/10.1155/2016/2610541 |
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| author | Reza Hasanzadeh Peyman Najafi Moghadam Naeimeh Bahri-Laleh Ehsan Nazarzadeh Zare |
| author_facet | Reza Hasanzadeh Peyman Najafi Moghadam Naeimeh Bahri-Laleh Ehsan Nazarzadeh Zare |
| author_sort | Reza Hasanzadeh |
| collection | DOAJ |
| description | Chelating magnetic nanocomposites have been considered as suitable materials for removal of heavy metal ions for water treatment. In this work poly(glycidyl methacrylate-maleic anhydride) copolymer (PGMA-MAn) is modified with 4-aminobenzenesulfonic acid (ABSAc) and subsequently the product reacted with modified Fe3O4 nanoparticles and 1,2-ethanedithiol (EDT) in the presence of ultrasonic irradiation for preparation of tridimensional chelating magnetic nanocomposite. Synthesized magnetic nanocomposite was characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), X-ray diffraction analysis (XRD), vibrating sample magnetometer (VSM), energy dispersive X-ray analysis (EDX), elemental mapping analysis (EMA), Brunauer-Emmett-Teller (BET), and thermal gravimetric analysis (TGA). The adsorption behavior of Cu(II) ions was investigated by synthesized nanocomposite in various parameters such as pH, contact time, metal ion concentration, and adsorbent dosage. The equilibrium distribution coefficient (kd) was determined and the findings prove that the kd value is approximately high in the case of all selected metal ions. The synthesized nanocomposite exhibited good tendency for removing Cu(II) ions from aqueous solutions even at an acidic pH. |
| format | Article |
| id | doaj-art-4e2d03072f6f4e77953f5f57414cb1a5 |
| institution | OA Journals |
| issn | 1687-9422 1687-9430 |
| language | English |
| publishDate | 2016-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Polymer Science |
| spelling | doaj-art-4e2d03072f6f4e77953f5f57414cb1a52025-08-20T02:38:46ZengWileyInternational Journal of Polymer Science1687-94221687-94302016-01-01201610.1155/2016/26105412610541Sulfonated Magnetic Nanocomposite Based on Reactive PGMA-MAn Copolymer@Fe3O4 Nanoparticles: Effective Removal of Cu(II) Ions from Aqueous SolutionsReza Hasanzadeh0Peyman Najafi Moghadam1Naeimeh Bahri-Laleh2Ehsan Nazarzadeh Zare3Department of Organic Chemistry, Faculty of Chemistry, Urmia University, Urmia, IranDepartment of Organic Chemistry, Faculty of Chemistry, Urmia University, Urmia, IranDepartment of Polymerization Engineering, Iran Polymer and Petrochemical Institute (IPPI), P.O. Box 14965/115, Tehran, IranDepartment of Chemistry, Faculty of Science, Gonbad Kavous University, Gonbad, IranChelating magnetic nanocomposites have been considered as suitable materials for removal of heavy metal ions for water treatment. In this work poly(glycidyl methacrylate-maleic anhydride) copolymer (PGMA-MAn) is modified with 4-aminobenzenesulfonic acid (ABSAc) and subsequently the product reacted with modified Fe3O4 nanoparticles and 1,2-ethanedithiol (EDT) in the presence of ultrasonic irradiation for preparation of tridimensional chelating magnetic nanocomposite. Synthesized magnetic nanocomposite was characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), X-ray diffraction analysis (XRD), vibrating sample magnetometer (VSM), energy dispersive X-ray analysis (EDX), elemental mapping analysis (EMA), Brunauer-Emmett-Teller (BET), and thermal gravimetric analysis (TGA). The adsorption behavior of Cu(II) ions was investigated by synthesized nanocomposite in various parameters such as pH, contact time, metal ion concentration, and adsorbent dosage. The equilibrium distribution coefficient (kd) was determined and the findings prove that the kd value is approximately high in the case of all selected metal ions. The synthesized nanocomposite exhibited good tendency for removing Cu(II) ions from aqueous solutions even at an acidic pH.http://dx.doi.org/10.1155/2016/2610541 |
| spellingShingle | Reza Hasanzadeh Peyman Najafi Moghadam Naeimeh Bahri-Laleh Ehsan Nazarzadeh Zare Sulfonated Magnetic Nanocomposite Based on Reactive PGMA-MAn Copolymer@Fe3O4 Nanoparticles: Effective Removal of Cu(II) Ions from Aqueous Solutions International Journal of Polymer Science |
| title | Sulfonated Magnetic Nanocomposite Based on Reactive PGMA-MAn Copolymer@Fe3O4 Nanoparticles: Effective Removal of Cu(II) Ions from Aqueous Solutions |
| title_full | Sulfonated Magnetic Nanocomposite Based on Reactive PGMA-MAn Copolymer@Fe3O4 Nanoparticles: Effective Removal of Cu(II) Ions from Aqueous Solutions |
| title_fullStr | Sulfonated Magnetic Nanocomposite Based on Reactive PGMA-MAn Copolymer@Fe3O4 Nanoparticles: Effective Removal of Cu(II) Ions from Aqueous Solutions |
| title_full_unstemmed | Sulfonated Magnetic Nanocomposite Based on Reactive PGMA-MAn Copolymer@Fe3O4 Nanoparticles: Effective Removal of Cu(II) Ions from Aqueous Solutions |
| title_short | Sulfonated Magnetic Nanocomposite Based on Reactive PGMA-MAn Copolymer@Fe3O4 Nanoparticles: Effective Removal of Cu(II) Ions from Aqueous Solutions |
| title_sort | sulfonated magnetic nanocomposite based on reactive pgma man copolymer fe3o4 nanoparticles effective removal of cu ii ions from aqueous solutions |
| url | http://dx.doi.org/10.1155/2016/2610541 |
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