Optimization and Modification of the Hydrogen Peroxide to Propylene Oxide (HPPO) Process

The production of Propylene Oxide (PO) through the Hydrogen Peroxide to Propylene Oxide (HPPO) process represents a cleaner and more efficient route compared to conventional methods. This project focuses on the design and feasibility of a chemical plant with an annual capacity of 10,000 tons of PO u...

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Main Authors: Fikri Wisnu Pratama, Zaidan Fadhlan, Thariq Abrar Purnamadjati, Wisnu Satrio Adjie
Format: Article
Language:English
Published: Universitas Diponegoro 2025-12-01
Series:Journal of Chemical Engineering Research Progress
Subjects:
Online Access:https://journal.bcrec.id/index.php/jcerp/article/view/20419
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author Fikri Wisnu Pratama
Zaidan Fadhlan
Thariq Abrar Purnamadjati
Wisnu Satrio Adjie
author_facet Fikri Wisnu Pratama
Zaidan Fadhlan
Thariq Abrar Purnamadjati
Wisnu Satrio Adjie
author_sort Fikri Wisnu Pratama
collection DOAJ
description The production of Propylene Oxide (PO) through the Hydrogen Peroxide to Propylene Oxide (HPPO) process represents a cleaner and more efficient route compared to conventional methods. This project focuses on the design and feasibility of a chemical plant with an annual capacity of 10,000 tons of PO using propylene and hydrogen peroxide as feedstocks. The HPPO process, catalyzed by a titanium silicate (TS-1) catalyst, offers significant environmental and economic advantages, such as reduced by-products and lower energy consumption. The core reaction occurs in a convergent reactor under mild operating conditions, producing PO with water as the only by-product, thus minimizing environmental impact. This study focuses on process intensification and optimization of the Hydrogen Peroxide to Propylene Oxide (HPPO) process, with the goal of improving energy efficiency, enhancing mass utilization, optimizing reactor operating conditions, and minimizing waste generation through targeted process modifications. The results demonstrate that the HPPO process is a sustainable and economically viable option for small to medium-scale PO production, aligning with green chemistry principles and industrial scalability. Copyright © 2025 by Authors, Published by Universitas Diponegoro and BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).
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publishDate 2025-12-01
publisher Universitas Diponegoro
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series Journal of Chemical Engineering Research Progress
spelling doaj-art-4de48632f00044889adb4255fefba8f92025-08-20T03:56:18ZengUniversitas DiponegoroJournal of Chemical Engineering Research Progress3032-70592025-12-012220520910.9767/jcerp.204198565Optimization and Modification of the Hydrogen Peroxide to Propylene Oxide (HPPO) ProcessFikri Wisnu Pratama0Zaidan Fadhlan1Thariq Abrar Purnamadjati2Wisnu Satrio Adjie3Department of Chemical Engineering, Faculty of Engineering, Diponegoro University, Semarang, IndonesiaDepartment of Chemical Engineering, Faculty of Engineering, Diponegoro University, Semarang, IndonesiaDepartment of Chemical Engineering, Faculty of Engineering, Diponegoro University, Semarang, IndonesiaDepartment of Chemical Engineering, Faculty of Engineering, Diponegoro University, Semarang, IndonesiaThe production of Propylene Oxide (PO) through the Hydrogen Peroxide to Propylene Oxide (HPPO) process represents a cleaner and more efficient route compared to conventional methods. This project focuses on the design and feasibility of a chemical plant with an annual capacity of 10,000 tons of PO using propylene and hydrogen peroxide as feedstocks. The HPPO process, catalyzed by a titanium silicate (TS-1) catalyst, offers significant environmental and economic advantages, such as reduced by-products and lower energy consumption. The core reaction occurs in a convergent reactor under mild operating conditions, producing PO with water as the only by-product, thus minimizing environmental impact. This study focuses on process intensification and optimization of the Hydrogen Peroxide to Propylene Oxide (HPPO) process, with the goal of improving energy efficiency, enhancing mass utilization, optimizing reactor operating conditions, and minimizing waste generation through targeted process modifications. The results demonstrate that the HPPO process is a sustainable and economically viable option for small to medium-scale PO production, aligning with green chemistry principles and industrial scalability. Copyright © 2025 by Authors, Published by Universitas Diponegoro and BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).https://journal.bcrec.id/index.php/jcerp/article/view/20419propylene oxidehppo processprocess designprocess intensification
spellingShingle Fikri Wisnu Pratama
Zaidan Fadhlan
Thariq Abrar Purnamadjati
Wisnu Satrio Adjie
Optimization and Modification of the Hydrogen Peroxide to Propylene Oxide (HPPO) Process
Journal of Chemical Engineering Research Progress
propylene oxide
hppo process
process design
process intensification
title Optimization and Modification of the Hydrogen Peroxide to Propylene Oxide (HPPO) Process
title_full Optimization and Modification of the Hydrogen Peroxide to Propylene Oxide (HPPO) Process
title_fullStr Optimization and Modification of the Hydrogen Peroxide to Propylene Oxide (HPPO) Process
title_full_unstemmed Optimization and Modification of the Hydrogen Peroxide to Propylene Oxide (HPPO) Process
title_short Optimization and Modification of the Hydrogen Peroxide to Propylene Oxide (HPPO) Process
title_sort optimization and modification of the hydrogen peroxide to propylene oxide hppo process
topic propylene oxide
hppo process
process design
process intensification
url https://journal.bcrec.id/index.php/jcerp/article/view/20419
work_keys_str_mv AT fikriwisnupratama optimizationandmodificationofthehydrogenperoxidetopropyleneoxidehppoprocess
AT zaidanfadhlan optimizationandmodificationofthehydrogenperoxidetopropyleneoxidehppoprocess
AT thariqabrarpurnamadjati optimizationandmodificationofthehydrogenperoxidetopropyleneoxidehppoprocess
AT wisnusatrioadjie optimizationandmodificationofthehydrogenperoxidetopropyleneoxidehppoprocess