Polyethylene glycol precipitation is a useful method for excluding the interference of unexplained elevated CA 19-9

Abstract With improved living standards and increased health awareness among Chinese residents, carbohydrate antigen 19-9 (CA 19-9) has become a routine marker in health examinations. Elevated CA 19-9 levels are frequently observed in clinical practice. Although chemiluminescence technology is widel...

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Main Authors: Sha Lin, Qi Wang, Xiaopeng Yu, Yajun Tan, Yifan Yao, WeiLin Mao, GuangHua Ma
Format: Article
Language:English
Published: Nature Portfolio 2025-07-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-025-07065-8
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author Sha Lin
Qi Wang
Xiaopeng Yu
Yajun Tan
Yifan Yao
WeiLin Mao
GuangHua Ma
author_facet Sha Lin
Qi Wang
Xiaopeng Yu
Yajun Tan
Yifan Yao
WeiLin Mao
GuangHua Ma
author_sort Sha Lin
collection DOAJ
description Abstract With improved living standards and increased health awareness among Chinese residents, carbohydrate antigen 19-9 (CA 19-9) has become a routine marker in health examinations. Elevated CA 19-9 levels are frequently observed in clinical practice. Although chemiluminescence technology is widely recognized for its high sensitivity and specificity, it cannot eliminate interference, which may lead to deviations and misdiagnoses. This study aims to find a simple and effective method to confirm and exclude the interference of CA 19-9 on the Abbott platform. 342 individuals with unexplained elevated CA 19-9 in serial determinations for more than 6 months were included as cases. Serum samples from individuals with persistently elevated CA 19 -9 levels were evaluated via sialidase treatment, polyethylene glycol (PEG) precipitation, gel filtration chromatography (GFC), gradient dilution assays, heterophile antibody blocking assays and rheumatoid factor titer assays. Out of 342 individuals with elevated CA 19-9, 77 cases were confirmed as interferent by the sialidase treatment. There was a significant consistency between the PEG precipitation and sialidase treatment results (kappa = 0.920). Compared with the sialidase treatment method, the specificity of the PEG precipitation method was 96.2%, and the sensitivity was 100%. When the cutoff value for the CA 19-9 recovery after PEG precipitation was below 37.9%, the area under the curve (AUC) was highest at 0.993 (95% CI 98.5–99.8%). The PEG precipitation method is useful and reliable for patients with unexplained elevated CA 19-9. This method could effectively identify the interference, reduce clinical misdiagnosis, alleviate unnecessary financial burdens on patients.
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spelling doaj-art-4d89ccbc53554c11b9d4c16c4be3e10d2025-08-20T03:03:32ZengNature PortfolioScientific Reports2045-23222025-07-011511910.1038/s41598-025-07065-8Polyethylene glycol precipitation is a useful method for excluding the interference of unexplained elevated CA 19-9Sha Lin0Qi Wang1Xiaopeng Yu2Yajun Tan3Yifan Yao4WeiLin Mao5GuangHua Ma6Department of Laboratory Medicine, The First Affiliated Hospital, Zhejiang University School of MedicineDepartment of Laboratory Medicine, The First Affiliated Hospital, Zhejiang University School of MedicineState Key Laboratory for Diagnosis and Treatment of Infectious Diseases, Zhejiang UniversityDepartment of Laboratory Medicine, The First Affiliated Hospital, Zhejiang University School of MedicineDepartment of Laboratory Medicine, The First Affiliated Hospital, Zhejiang University School of MedicineDepartment of Laboratory Medicine, The First Affiliated Hospital, Zhejiang University School of MedicineDepartment of Laboratory Medicine, The First Affiliated Hospital, Zhejiang University School of MedicineAbstract With improved living standards and increased health awareness among Chinese residents, carbohydrate antigen 19-9 (CA 19-9) has become a routine marker in health examinations. Elevated CA 19-9 levels are frequently observed in clinical practice. Although chemiluminescence technology is widely recognized for its high sensitivity and specificity, it cannot eliminate interference, which may lead to deviations and misdiagnoses. This study aims to find a simple and effective method to confirm and exclude the interference of CA 19-9 on the Abbott platform. 342 individuals with unexplained elevated CA 19-9 in serial determinations for more than 6 months were included as cases. Serum samples from individuals with persistently elevated CA 19 -9 levels were evaluated via sialidase treatment, polyethylene glycol (PEG) precipitation, gel filtration chromatography (GFC), gradient dilution assays, heterophile antibody blocking assays and rheumatoid factor titer assays. Out of 342 individuals with elevated CA 19-9, 77 cases were confirmed as interferent by the sialidase treatment. There was a significant consistency between the PEG precipitation and sialidase treatment results (kappa = 0.920). Compared with the sialidase treatment method, the specificity of the PEG precipitation method was 96.2%, and the sensitivity was 100%. When the cutoff value for the CA 19-9 recovery after PEG precipitation was below 37.9%, the area under the curve (AUC) was highest at 0.993 (95% CI 98.5–99.8%). The PEG precipitation method is useful and reliable for patients with unexplained elevated CA 19-9. This method could effectively identify the interference, reduce clinical misdiagnosis, alleviate unnecessary financial burdens on patients.https://doi.org/10.1038/s41598-025-07065-8Immunoassay interferenceMacro-CA 19 -9Sialidase treatmentPEG
spellingShingle Sha Lin
Qi Wang
Xiaopeng Yu
Yajun Tan
Yifan Yao
WeiLin Mao
GuangHua Ma
Polyethylene glycol precipitation is a useful method for excluding the interference of unexplained elevated CA 19-9
Scientific Reports
Immunoassay interference
Macro-CA 19 -9
Sialidase treatment
PEG
title Polyethylene glycol precipitation is a useful method for excluding the interference of unexplained elevated CA 19-9
title_full Polyethylene glycol precipitation is a useful method for excluding the interference of unexplained elevated CA 19-9
title_fullStr Polyethylene glycol precipitation is a useful method for excluding the interference of unexplained elevated CA 19-9
title_full_unstemmed Polyethylene glycol precipitation is a useful method for excluding the interference of unexplained elevated CA 19-9
title_short Polyethylene glycol precipitation is a useful method for excluding the interference of unexplained elevated CA 19-9
title_sort polyethylene glycol precipitation is a useful method for excluding the interference of unexplained elevated ca 19 9
topic Immunoassay interference
Macro-CA 19 -9
Sialidase treatment
PEG
url https://doi.org/10.1038/s41598-025-07065-8
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