Two-Dimensional Metal–Organic Framework Nanostructures and Their Composites in Chemical Warfare Agent Detoxification: A Review

This review summarizes the application of two-dimensional metal–organic framework (2D MOF) nanostructures and their composites in the detoxification of chemical warfare agents (CWAs). Two-dimensional MOFs, characterized by their high specific surface area, abundant active sites, and structural tunab...

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Main Authors: Cheng-an Tao, Shiyin Zhao, Yujiao Li, Jianfang Wang
Format: Article
Language:English
Published: MDPI AG 2025-02-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/15/2/182
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author Cheng-an Tao
Shiyin Zhao
Yujiao Li
Jianfang Wang
author_facet Cheng-an Tao
Shiyin Zhao
Yujiao Li
Jianfang Wang
author_sort Cheng-an Tao
collection DOAJ
description This review summarizes the application of two-dimensional metal–organic framework (2D MOF) nanostructures and their composites in the detoxification of chemical warfare agents (CWAs). Two-dimensional MOFs, characterized by their high specific surface area, abundant active sites, and structural tunability, exhibit promising catalytic performance in CWA detoxification. Various preparation methods, including top–down exfoliation and bottom–up assembly, are discussed for the synthesis of 2D MOF nanosheets. The catalytic performance of 2D MOFs and their composites in detoxifying CWAs is evaluated, highlighting their advantages in terms of reaction kinetics and ease of recycling. Additionally, the advances and challenges in this field are discussed, aiming to promote further research into and development of 2D MOF-based materials for CWA detoxification.
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issn 2073-4352
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series Crystals
spelling doaj-art-4cbb71f38a8a41a2ba155751fb0ab07b2025-08-20T03:12:14ZengMDPI AGCrystals2073-43522025-02-0115218210.3390/cryst15020182Two-Dimensional Metal–Organic Framework Nanostructures and Their Composites in Chemical Warfare Agent Detoxification: A ReviewCheng-an Tao0Shiyin Zhao1Yujiao Li2Jianfang Wang3College of Science, National University of Defense Technology, Changsha 410073, ChinaCollege of Science, National University of Defense Technology, Changsha 410073, ChinaCollege of Science, National University of Defense Technology, Changsha 410073, ChinaCollege of Science, National University of Defense Technology, Changsha 410073, ChinaThis review summarizes the application of two-dimensional metal–organic framework (2D MOF) nanostructures and their composites in the detoxification of chemical warfare agents (CWAs). Two-dimensional MOFs, characterized by their high specific surface area, abundant active sites, and structural tunability, exhibit promising catalytic performance in CWA detoxification. Various preparation methods, including top–down exfoliation and bottom–up assembly, are discussed for the synthesis of 2D MOF nanosheets. The catalytic performance of 2D MOFs and their composites in detoxifying CWAs is evaluated, highlighting their advantages in terms of reaction kinetics and ease of recycling. Additionally, the advances and challenges in this field are discussed, aiming to promote further research into and development of 2D MOF-based materials for CWA detoxification.https://www.mdpi.com/2073-4352/15/2/182metal–organic frameworktwo-dimensionalchemical warfare agentcompositechemical protection
spellingShingle Cheng-an Tao
Shiyin Zhao
Yujiao Li
Jianfang Wang
Two-Dimensional Metal–Organic Framework Nanostructures and Their Composites in Chemical Warfare Agent Detoxification: A Review
Crystals
metal–organic framework
two-dimensional
chemical warfare agent
composite
chemical protection
title Two-Dimensional Metal–Organic Framework Nanostructures and Their Composites in Chemical Warfare Agent Detoxification: A Review
title_full Two-Dimensional Metal–Organic Framework Nanostructures and Their Composites in Chemical Warfare Agent Detoxification: A Review
title_fullStr Two-Dimensional Metal–Organic Framework Nanostructures and Their Composites in Chemical Warfare Agent Detoxification: A Review
title_full_unstemmed Two-Dimensional Metal–Organic Framework Nanostructures and Their Composites in Chemical Warfare Agent Detoxification: A Review
title_short Two-Dimensional Metal–Organic Framework Nanostructures and Their Composites in Chemical Warfare Agent Detoxification: A Review
title_sort two dimensional metal organic framework nanostructures and their composites in chemical warfare agent detoxification a review
topic metal–organic framework
two-dimensional
chemical warfare agent
composite
chemical protection
url https://www.mdpi.com/2073-4352/15/2/182
work_keys_str_mv AT chengantao twodimensionalmetalorganicframeworknanostructuresandtheircompositesinchemicalwarfareagentdetoxificationareview
AT shiyinzhao twodimensionalmetalorganicframeworknanostructuresandtheircompositesinchemicalwarfareagentdetoxificationareview
AT yujiaoli twodimensionalmetalorganicframeworknanostructuresandtheircompositesinchemicalwarfareagentdetoxificationareview
AT jianfangwang twodimensionalmetalorganicframeworknanostructuresandtheircompositesinchemicalwarfareagentdetoxificationareview