Stable Inverted Low-Bandgap Polymer Solar Cells with Aqueous Solution Processed Low-Temperature ZnO Buffer Layers

Efficient inverted low-bandgap polymer solar cells with an aqueous solution processed low-temperature ZnO buffer layer have been investigated. The low-bandgap material PTB-7 is employed so that more solar light can be efficiently harvested, and the aqueous solution processed ZnO electron transport b...

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Main Authors: Chunfu Zhang, Shangzheng Pang, Ting Heng, Hailong You, Genquan Han, Gang Lu, Fengqin He, Qubo Jiang, Jincheng Zhang
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2016/3675036
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author Chunfu Zhang
Shangzheng Pang
Ting Heng
Hailong You
Genquan Han
Gang Lu
Fengqin He
Qubo Jiang
Jincheng Zhang
author_facet Chunfu Zhang
Shangzheng Pang
Ting Heng
Hailong You
Genquan Han
Gang Lu
Fengqin He
Qubo Jiang
Jincheng Zhang
author_sort Chunfu Zhang
collection DOAJ
description Efficient inverted low-bandgap polymer solar cells with an aqueous solution processed low-temperature ZnO buffer layer have been investigated. The low-bandgap material PTB-7 is employed so that more solar light can be efficiently harvested, and the aqueous solution processed ZnO electron transport buffer layer is prepared at 150°C so that it can be compatible with the roll-to-roll process. Power conversion efficiency (PCE) of the inverted device reaches 7.12%, which is near the control conventional device. More importantly, the inverted device shows a better stability, keeping more than 90% of its original PCE after being stored for 625 hours, while PCE of the conventional device is only 75% of what it was. In addition, it is found that the ZnO thin film annealed in N2 can obviously increase PCE of the inverted device further to 7.26%.
format Article
id doaj-art-4c79b26fdfff44298efe605c782ca4e5
institution Kabale University
issn 1110-662X
1687-529X
language English
publishDate 2016-01-01
publisher Wiley
record_format Article
series International Journal of Photoenergy
spelling doaj-art-4c79b26fdfff44298efe605c782ca4e52025-08-20T03:36:14ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2016-01-01201610.1155/2016/36750363675036Stable Inverted Low-Bandgap Polymer Solar Cells with Aqueous Solution Processed Low-Temperature ZnO Buffer LayersChunfu Zhang0Shangzheng Pang1Ting Heng2Hailong You3Genquan Han4Gang Lu5Fengqin He6Qubo Jiang7Jincheng Zhang8State Key Discipline Laboratory of Wide Band Gap Semiconductor Technology, School of Microelectronics, Xidian University, 2 South Taibai Road, Xi’an 710071, ChinaState Key Discipline Laboratory of Wide Band Gap Semiconductor Technology, School of Microelectronics, Xidian University, 2 South Taibai Road, Xi’an 710071, ChinaState Key Discipline Laboratory of Wide Band Gap Semiconductor Technology, School of Microelectronics, Xidian University, 2 South Taibai Road, Xi’an 710071, ChinaState Key Discipline Laboratory of Wide Band Gap Semiconductor Technology, School of Microelectronics, Xidian University, 2 South Taibai Road, Xi’an 710071, ChinaState Key Discipline Laboratory of Wide Band Gap Semiconductor Technology, School of Microelectronics, Xidian University, 2 South Taibai Road, Xi’an 710071, ChinaHuanghe Hydropower Solar Industry Technology Co., Ltd., 369 South Yanta Road, Xi’an 710061, ChinaHuanghe Hydropower Solar Industry Technology Co., Ltd., 369 South Yanta Road, Xi’an 710061, ChinaGuilin University of Electronic Technology, No. 1 Jinji Road, Guilin 541004, ChinaState Key Discipline Laboratory of Wide Band Gap Semiconductor Technology, School of Microelectronics, Xidian University, 2 South Taibai Road, Xi’an 710071, ChinaEfficient inverted low-bandgap polymer solar cells with an aqueous solution processed low-temperature ZnO buffer layer have been investigated. The low-bandgap material PTB-7 is employed so that more solar light can be efficiently harvested, and the aqueous solution processed ZnO electron transport buffer layer is prepared at 150°C so that it can be compatible with the roll-to-roll process. Power conversion efficiency (PCE) of the inverted device reaches 7.12%, which is near the control conventional device. More importantly, the inverted device shows a better stability, keeping more than 90% of its original PCE after being stored for 625 hours, while PCE of the conventional device is only 75% of what it was. In addition, it is found that the ZnO thin film annealed in N2 can obviously increase PCE of the inverted device further to 7.26%.http://dx.doi.org/10.1155/2016/3675036
spellingShingle Chunfu Zhang
Shangzheng Pang
Ting Heng
Hailong You
Genquan Han
Gang Lu
Fengqin He
Qubo Jiang
Jincheng Zhang
Stable Inverted Low-Bandgap Polymer Solar Cells with Aqueous Solution Processed Low-Temperature ZnO Buffer Layers
International Journal of Photoenergy
title Stable Inverted Low-Bandgap Polymer Solar Cells with Aqueous Solution Processed Low-Temperature ZnO Buffer Layers
title_full Stable Inverted Low-Bandgap Polymer Solar Cells with Aqueous Solution Processed Low-Temperature ZnO Buffer Layers
title_fullStr Stable Inverted Low-Bandgap Polymer Solar Cells with Aqueous Solution Processed Low-Temperature ZnO Buffer Layers
title_full_unstemmed Stable Inverted Low-Bandgap Polymer Solar Cells with Aqueous Solution Processed Low-Temperature ZnO Buffer Layers
title_short Stable Inverted Low-Bandgap Polymer Solar Cells with Aqueous Solution Processed Low-Temperature ZnO Buffer Layers
title_sort stable inverted low bandgap polymer solar cells with aqueous solution processed low temperature zno buffer layers
url http://dx.doi.org/10.1155/2016/3675036
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