Accumulation of perfluoroalkyl acids as forever chemicals in Antarctic waters

Abstract Perfluoroalkyl acids have been widely used during the last fifty years in a myriad of industrial and consumer applications, and are a paradigm of persistent “forever chemicals”. Earlier studies suggested a limited occurrence in the Southern Ocean as a consequence of the Antarctic circumpola...

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Main Authors: Núria Trilla-Prieto, Jordi Dachs, Jon Iriarte, Naiara Berrojalbiz, Pere Colomer-Vidal, Gemma Casas, Odei Garcia-Garin, Maria Vila-Costa, Begoña Jiménez
Format: Article
Language:English
Published: Nature Portfolio 2025-07-01
Series:Communications Earth & Environment
Online Access:https://doi.org/10.1038/s43247-025-02535-3
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author Núria Trilla-Prieto
Jordi Dachs
Jon Iriarte
Naiara Berrojalbiz
Pere Colomer-Vidal
Gemma Casas
Odei Garcia-Garin
Maria Vila-Costa
Begoña Jiménez
author_facet Núria Trilla-Prieto
Jordi Dachs
Jon Iriarte
Naiara Berrojalbiz
Pere Colomer-Vidal
Gemma Casas
Odei Garcia-Garin
Maria Vila-Costa
Begoña Jiménez
author_sort Núria Trilla-Prieto
collection DOAJ
description Abstract Perfluoroalkyl acids have been widely used during the last fifty years in a myriad of industrial and consumer applications, and are a paradigm of persistent “forever chemicals”. Earlier studies suggested a limited occurrence in the Southern Ocean as a consequence of the Antarctic circumpolar current preventing their oceanic transport southwards. Here we show perfluoroalkyl acids in the Bransfield Strait and Bellingshausen Sea (west of Antarctic Peninsula) at concentrations of comparable magnitude to those measured in the North Atlantic, a region impacted by historical sources. Atmospheric wet deposition of perfluoroalkyl acids previously aerosolized by sea-spray arises as the perfluoroalkyl acids source to Antarctica. The prevailing marine and atmospheric circulation in the region encapsulate these chemicals in the Antarctic region once these have crossed the Antarctic divergence. This work underscores the importance of persistence driving chemical’s environmental risk, and raises concern on the impact of the larger pool of per- and polyfluoroalkyl substances.
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institution Kabale University
issn 2662-4435
language English
publishDate 2025-07-01
publisher Nature Portfolio
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series Communications Earth & Environment
spelling doaj-art-4c418dcc48b146e0b2cbeb5e4c808b812025-08-20T03:42:10ZengNature PortfolioCommunications Earth & Environment2662-44352025-07-01611810.1038/s43247-025-02535-3Accumulation of perfluoroalkyl acids as forever chemicals in Antarctic watersNúria Trilla-Prieto0Jordi Dachs1Jon Iriarte2Naiara Berrojalbiz3Pere Colomer-Vidal4Gemma Casas5Odei Garcia-Garin6Maria Vila-Costa7Begoña Jiménez8Department of Environmental Chemistry, IDAEA-CSICDepartment of Environmental Chemistry, IDAEA-CSICDepartment of Environmental Chemistry, IDAEA-CSICDepartment of Environmental Chemistry, IDAEA-CSICDepartment of Instrumental Analysis and Environmental Chemistry, IQOG-CSICDepartment of Environmental Chemistry, IDAEA-CSICDepartment of Evolutionary Biology, Ecology and Environmental Sciences, Biodiversity Research Institute (IRBio), Universitat de BarcelonaDepartment of Environmental Chemistry, IDAEA-CSICDepartment of Instrumental Analysis and Environmental Chemistry, IQOG-CSICAbstract Perfluoroalkyl acids have been widely used during the last fifty years in a myriad of industrial and consumer applications, and are a paradigm of persistent “forever chemicals”. Earlier studies suggested a limited occurrence in the Southern Ocean as a consequence of the Antarctic circumpolar current preventing their oceanic transport southwards. Here we show perfluoroalkyl acids in the Bransfield Strait and Bellingshausen Sea (west of Antarctic Peninsula) at concentrations of comparable magnitude to those measured in the North Atlantic, a region impacted by historical sources. Atmospheric wet deposition of perfluoroalkyl acids previously aerosolized by sea-spray arises as the perfluoroalkyl acids source to Antarctica. The prevailing marine and atmospheric circulation in the region encapsulate these chemicals in the Antarctic region once these have crossed the Antarctic divergence. This work underscores the importance of persistence driving chemical’s environmental risk, and raises concern on the impact of the larger pool of per- and polyfluoroalkyl substances.https://doi.org/10.1038/s43247-025-02535-3
spellingShingle Núria Trilla-Prieto
Jordi Dachs
Jon Iriarte
Naiara Berrojalbiz
Pere Colomer-Vidal
Gemma Casas
Odei Garcia-Garin
Maria Vila-Costa
Begoña Jiménez
Accumulation of perfluoroalkyl acids as forever chemicals in Antarctic waters
Communications Earth & Environment
title Accumulation of perfluoroalkyl acids as forever chemicals in Antarctic waters
title_full Accumulation of perfluoroalkyl acids as forever chemicals in Antarctic waters
title_fullStr Accumulation of perfluoroalkyl acids as forever chemicals in Antarctic waters
title_full_unstemmed Accumulation of perfluoroalkyl acids as forever chemicals in Antarctic waters
title_short Accumulation of perfluoroalkyl acids as forever chemicals in Antarctic waters
title_sort accumulation of perfluoroalkyl acids as forever chemicals in antarctic waters
url https://doi.org/10.1038/s43247-025-02535-3
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