Carbon-Coated CF-Si/Al Anodes for Improved Lithium-Ion Battery Performance

Despite their high specific capacity, magnetron-sputtered Si/Al thin films face rapid capacity decay due to stress-induced cracking, delamination, and detrimental electrolyte reactions. This study introduces a carbon-coated composite anode that overcomes these limitations, delivering superior revers...

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Main Authors: Liangliang Zeng, Peng Li, Mi Ouyang, Shujuan Gao, Kun Liang
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Batteries
Subjects:
Online Access:https://www.mdpi.com/2313-0105/11/3/114
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author Liangliang Zeng
Peng Li
Mi Ouyang
Shujuan Gao
Kun Liang
author_facet Liangliang Zeng
Peng Li
Mi Ouyang
Shujuan Gao
Kun Liang
author_sort Liangliang Zeng
collection DOAJ
description Despite their high specific capacity, magnetron-sputtered Si/Al thin films face rapid capacity decay due to stress-induced cracking, delamination, and detrimental electrolyte reactions. This study introduces a carbon-coated composite anode that overcomes these limitations, delivering superior reversible capacity, exceptional rate capability, and stable cycling performance. An electrochemical evaluation reveals that the CF-Si/Al@C-500-1h composite exhibits marked enhancements in capacity retention (43.5% after 100 cycles at 0.6 A·g<sup>−1</sup>) and rate capability, maintaining 579.1 mAh·g<sup>−1</sup> at 3 A·g<sup>−1</sup> (1 C). The carbon layer enhances electrical conductivity, buffers volume expansion during lithiation/delithiation, and suppresses silicon aggregation and electrolyte side reactions. Coupled with an aluminum framework, this architecture ensures robust structural integrity and efficient lithium-ion transport. These advancements position CF-Si/Al@C-500-1h as a promising anode material for next-generation lithium-ion batteries, while insights into scalable fabrication and carbon integration strategies pave the way for practical applications.
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series Batteries
spelling doaj-art-4c2a67062b1a4dae8b5fcd64d3b6b9862025-08-20T02:11:12ZengMDPI AGBatteries2313-01052025-03-0111311410.3390/batteries11030114Carbon-Coated CF-Si/Al Anodes for Improved Lithium-Ion Battery PerformanceLiangliang Zeng0Peng Li1Mi Ouyang2Shujuan Gao3Kun Liang4College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaZhejiang Key Laboratory of Data-Driven High-Safety Energy Materials and Applications, Ningbo Key Laboratory of Special Energy Materials and Chemistry, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, ChinaCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaNingbo Guangxin Nanomaterials Co., Ltd., Ningbo 315000, ChinaZhejiang Key Laboratory of Data-Driven High-Safety Energy Materials and Applications, Ningbo Key Laboratory of Special Energy Materials and Chemistry, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, ChinaDespite their high specific capacity, magnetron-sputtered Si/Al thin films face rapid capacity decay due to stress-induced cracking, delamination, and detrimental electrolyte reactions. This study introduces a carbon-coated composite anode that overcomes these limitations, delivering superior reversible capacity, exceptional rate capability, and stable cycling performance. An electrochemical evaluation reveals that the CF-Si/Al@C-500-1h composite exhibits marked enhancements in capacity retention (43.5% after 100 cycles at 0.6 A·g<sup>−1</sup>) and rate capability, maintaining 579.1 mAh·g<sup>−1</sup> at 3 A·g<sup>−1</sup> (1 C). The carbon layer enhances electrical conductivity, buffers volume expansion during lithiation/delithiation, and suppresses silicon aggregation and electrolyte side reactions. Coupled with an aluminum framework, this architecture ensures robust structural integrity and efficient lithium-ion transport. These advancements position CF-Si/Al@C-500-1h as a promising anode material for next-generation lithium-ion batteries, while insights into scalable fabrication and carbon integration strategies pave the way for practical applications.https://www.mdpi.com/2313-0105/11/3/114Li-ion batterymagnetron sputteringco-sputteringcyclic stability
spellingShingle Liangliang Zeng
Peng Li
Mi Ouyang
Shujuan Gao
Kun Liang
Carbon-Coated CF-Si/Al Anodes for Improved Lithium-Ion Battery Performance
Batteries
Li-ion battery
magnetron sputtering
co-sputtering
cyclic stability
title Carbon-Coated CF-Si/Al Anodes for Improved Lithium-Ion Battery Performance
title_full Carbon-Coated CF-Si/Al Anodes for Improved Lithium-Ion Battery Performance
title_fullStr Carbon-Coated CF-Si/Al Anodes for Improved Lithium-Ion Battery Performance
title_full_unstemmed Carbon-Coated CF-Si/Al Anodes for Improved Lithium-Ion Battery Performance
title_short Carbon-Coated CF-Si/Al Anodes for Improved Lithium-Ion Battery Performance
title_sort carbon coated cf si al anodes for improved lithium ion battery performance
topic Li-ion battery
magnetron sputtering
co-sputtering
cyclic stability
url https://www.mdpi.com/2313-0105/11/3/114
work_keys_str_mv AT liangliangzeng carboncoatedcfsialanodesforimprovedlithiumionbatteryperformance
AT pengli carboncoatedcfsialanodesforimprovedlithiumionbatteryperformance
AT miouyang carboncoatedcfsialanodesforimprovedlithiumionbatteryperformance
AT shujuangao carboncoatedcfsialanodesforimprovedlithiumionbatteryperformance
AT kunliang carboncoatedcfsialanodesforimprovedlithiumionbatteryperformance