Deduction of full factorial design of HPLC technique for the simultaneous analysis of meloxicam and esomeprazole in their laboratory prepared tablets

Abstract A reversed phase HPLC method with UV detection was designed for the first time for the simultaneous estimation of meloxicam and esomeprazole in their combined tablet dosage forms. Full factorial design was used for rapid optimization of the proposed method. Chromatographic separation was re...

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Main Authors: Hesham Sameh Ramadan, Fathalla Belal, Aya Roshdy, Mohamed M. Salim
Format: Article
Language:English
Published: Nature Portfolio 2025-04-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-025-95706-3
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author Hesham Sameh Ramadan
Fathalla Belal
Aya Roshdy
Mohamed M. Salim
author_facet Hesham Sameh Ramadan
Fathalla Belal
Aya Roshdy
Mohamed M. Salim
author_sort Hesham Sameh Ramadan
collection DOAJ
description Abstract A reversed phase HPLC method with UV detection was designed for the first time for the simultaneous estimation of meloxicam and esomeprazole in their combined tablet dosage forms. Full factorial design was used for rapid optimization of the proposed method. Chromatographic separation was reached using isocratic elution on C18 column. The mobile phase was a mixture of methanol: acetonitrile: 0.05 M potassium dihydrogen phosphate buffer at pH 5, adjusted using phosphoric acid and/or NaOH when needed. The flow rate was 1 mL/min and the injection volume was 20 µL. The detection wavelength was 230 nm. The working ranges of the method were 5.0-100.0 and 10.0–100.0 µg/mL, LOD values were 0.8 and 1.8 µg/mL and LOQ values were 2.6 and 5.5 µg/mL for meloxicam and esomeprazole, respectively. The proposed method was successfully applied to their combined tablet dosage forms with acceptable % recoveries (100.4 − 100.7%) obtained. Four methods were used to evaluate the greenness of the proposed method, suggesting the acceptability of the greenness of the proposed method.
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spelling doaj-art-4c100e69f1b04f1f86972abd1ea590ad2025-08-20T03:18:30ZengNature PortfolioScientific Reports2045-23222025-04-0115111210.1038/s41598-025-95706-3Deduction of full factorial design of HPLC technique for the simultaneous analysis of meloxicam and esomeprazole in their laboratory prepared tabletsHesham Sameh Ramadan0Fathalla Belal1Aya Roshdy2Mohamed M. Salim3Department of Pharmaceutical Analytical Chemistry, Faculty of Pharmacy, Suez Canal UniversityDepartment of Pharmaceutical Analytical Chemistry, Faculty of Pharmacy, Mansoura UniversityDepartment of Pharmaceutical Chemistry, Faculty of Pharmacy, Horus University- EgyptDepartment of Pharmaceutical Chemistry, Faculty of Pharmacy, Horus University- EgyptAbstract A reversed phase HPLC method with UV detection was designed for the first time for the simultaneous estimation of meloxicam and esomeprazole in their combined tablet dosage forms. Full factorial design was used for rapid optimization of the proposed method. Chromatographic separation was reached using isocratic elution on C18 column. The mobile phase was a mixture of methanol: acetonitrile: 0.05 M potassium dihydrogen phosphate buffer at pH 5, adjusted using phosphoric acid and/or NaOH when needed. The flow rate was 1 mL/min and the injection volume was 20 µL. The detection wavelength was 230 nm. The working ranges of the method were 5.0-100.0 and 10.0–100.0 µg/mL, LOD values were 0.8 and 1.8 µg/mL and LOQ values were 2.6 and 5.5 µg/mL for meloxicam and esomeprazole, respectively. The proposed method was successfully applied to their combined tablet dosage forms with acceptable % recoveries (100.4 − 100.7%) obtained. Four methods were used to evaluate the greenness of the proposed method, suggesting the acceptability of the greenness of the proposed method.https://doi.org/10.1038/s41598-025-95706-3MeloxicamEsomeprazoleHPLCFactorial designPharmaceutical tablets
spellingShingle Hesham Sameh Ramadan
Fathalla Belal
Aya Roshdy
Mohamed M. Salim
Deduction of full factorial design of HPLC technique for the simultaneous analysis of meloxicam and esomeprazole in their laboratory prepared tablets
Scientific Reports
Meloxicam
Esomeprazole
HPLC
Factorial design
Pharmaceutical tablets
title Deduction of full factorial design of HPLC technique for the simultaneous analysis of meloxicam and esomeprazole in their laboratory prepared tablets
title_full Deduction of full factorial design of HPLC technique for the simultaneous analysis of meloxicam and esomeprazole in their laboratory prepared tablets
title_fullStr Deduction of full factorial design of HPLC technique for the simultaneous analysis of meloxicam and esomeprazole in their laboratory prepared tablets
title_full_unstemmed Deduction of full factorial design of HPLC technique for the simultaneous analysis of meloxicam and esomeprazole in their laboratory prepared tablets
title_short Deduction of full factorial design of HPLC technique for the simultaneous analysis of meloxicam and esomeprazole in their laboratory prepared tablets
title_sort deduction of full factorial design of hplc technique for the simultaneous analysis of meloxicam and esomeprazole in their laboratory prepared tablets
topic Meloxicam
Esomeprazole
HPLC
Factorial design
Pharmaceutical tablets
url https://doi.org/10.1038/s41598-025-95706-3
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