5-(Sulfamoyl)thien-2-yl 1,3-oxazole inhibitors of carbonic anhydrase II with hydrophilic periphery

Hydrophilic derivatives of an earlier described series of carbonic anhydrase inhibitors have been designed, prepared and profiled against a panel of carbonic anhydrase isoforms, including the glaucoma-related hCA II. For all hydrophilic derivatives, computational prediction of intraocular permeabili...

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Main Authors: Stanislav Kalinin, Alexander Kovalenko, Annika Valtari, Alessio Nocentini, Maxim Gureev, Arto Urtti, Mikhail Korsakov, Claudiu T. Supuran, Mikhail Krasavin
Format: Article
Language:English
Published: Taylor & Francis Group 2022-12-01
Series:Journal of Enzyme Inhibition and Medicinal Chemistry
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Online Access:https://www.tandfonline.com/doi/10.1080/14756366.2022.2056733
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author Stanislav Kalinin
Alexander Kovalenko
Annika Valtari
Alessio Nocentini
Maxim Gureev
Arto Urtti
Mikhail Korsakov
Claudiu T. Supuran
Mikhail Krasavin
author_facet Stanislav Kalinin
Alexander Kovalenko
Annika Valtari
Alessio Nocentini
Maxim Gureev
Arto Urtti
Mikhail Korsakov
Claudiu T. Supuran
Mikhail Krasavin
author_sort Stanislav Kalinin
collection DOAJ
description Hydrophilic derivatives of an earlier described series of carbonic anhydrase inhibitors have been designed, prepared and profiled against a panel of carbonic anhydrase isoforms, including the glaucoma-related hCA II. For all hydrophilic derivatives, computational prediction of intraocular permeability routes showed the predominance of conjunctival rather than corneal absorption. The potentially reactive primary or secondary amine periphery of these compounds makes them suitable candidates for bioconjugation to polymeric drug carriers. As was shown previously, the most active hCA II inhibitor is efficacious in alleviating intraocular pressure in normotensive rabbits with efficacy matching that of dorzolamide.
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institution Kabale University
issn 1475-6366
1475-6374
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spelling doaj-art-4bd8215628fd4666b45c04fefe090d2d2025-08-20T03:31:27ZengTaylor & Francis GroupJournal of Enzyme Inhibition and Medicinal Chemistry1475-63661475-63742022-12-013711005101110.1080/14756366.2022.20567335-(Sulfamoyl)thien-2-yl 1,3-oxazole inhibitors of carbonic anhydrase II with hydrophilic peripheryStanislav Kalinin0Alexander Kovalenko1Annika Valtari2Alessio Nocentini3Maxim Gureev4Arto Urtti5Mikhail Korsakov6Claudiu T. Supuran7Mikhail Krasavin8Institute of Chemistry, Saint Petersburg State University, St. Petersburg, Russian FederationInstitute of Chemistry, Saint Petersburg State University, St. Petersburg, Russian FederationSchool of Pharmacy, University of Eastern Finland, Kuopio, FinlandDepartment of Neurofarba, Universita degli Studi di Firenze, Florence, ItalyDigital Biodesign and Personalized Healthcare Research Center, Sechenov First Moscow State Medical University, Moscow, Russian FederationInstitute of Chemistry, Saint Petersburg State University, St. Petersburg, Russian FederationPharmaceutical Technology Transfer Center, Ushinsky Yaroslavl State Pedagogical University, Yaroslavl, Russian FederationDepartment of Neurofarba, Universita degli Studi di Firenze, Florence, ItalyInstitute of Chemistry, Saint Petersburg State University, St. Petersburg, Russian FederationHydrophilic derivatives of an earlier described series of carbonic anhydrase inhibitors have been designed, prepared and profiled against a panel of carbonic anhydrase isoforms, including the glaucoma-related hCA II. For all hydrophilic derivatives, computational prediction of intraocular permeability routes showed the predominance of conjunctival rather than corneal absorption. The potentially reactive primary or secondary amine periphery of these compounds makes them suitable candidates for bioconjugation to polymeric drug carriers. As was shown previously, the most active hCA II inhibitor is efficacious in alleviating intraocular pressure in normotensive rabbits with efficacy matching that of dorzolamide.https://www.tandfonline.com/doi/10.1080/14756366.2022.2056733Glaucomaintraocular pressurehydrophilicitybioconjugationintraocular delivery
spellingShingle Stanislav Kalinin
Alexander Kovalenko
Annika Valtari
Alessio Nocentini
Maxim Gureev
Arto Urtti
Mikhail Korsakov
Claudiu T. Supuran
Mikhail Krasavin
5-(Sulfamoyl)thien-2-yl 1,3-oxazole inhibitors of carbonic anhydrase II with hydrophilic periphery
Journal of Enzyme Inhibition and Medicinal Chemistry
Glaucoma
intraocular pressure
hydrophilicity
bioconjugation
intraocular delivery
title 5-(Sulfamoyl)thien-2-yl 1,3-oxazole inhibitors of carbonic anhydrase II with hydrophilic periphery
title_full 5-(Sulfamoyl)thien-2-yl 1,3-oxazole inhibitors of carbonic anhydrase II with hydrophilic periphery
title_fullStr 5-(Sulfamoyl)thien-2-yl 1,3-oxazole inhibitors of carbonic anhydrase II with hydrophilic periphery
title_full_unstemmed 5-(Sulfamoyl)thien-2-yl 1,3-oxazole inhibitors of carbonic anhydrase II with hydrophilic periphery
title_short 5-(Sulfamoyl)thien-2-yl 1,3-oxazole inhibitors of carbonic anhydrase II with hydrophilic periphery
title_sort 5 sulfamoyl thien 2 yl 1 3 oxazole inhibitors of carbonic anhydrase ii with hydrophilic periphery
topic Glaucoma
intraocular pressure
hydrophilicity
bioconjugation
intraocular delivery
url https://www.tandfonline.com/doi/10.1080/14756366.2022.2056733
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