Chitosan-based polyelectrolyte complex in combination with allotropic forms of carbon as a basis of thin-film organic electronics

Using atomic force microscopy, scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy, the morphology and mobility of charge carriers in composite films with a thickness of no more than 500 nm obtained on the basis of a polyelectrolyte complex of chitosan and chi...

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Main Authors: Rufina Zilberg, Renat Salikhov, Ilnur Mullagaliev, Yulia Teres, Elena Bulysheva, Timur Salikhov, Anastasia Ostaltsova, Ivan Vakulin
Format: Article
Language:English
Published: Ural Federal University 2024-06-01
Series:Chimica Techno Acta
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Online Access:https://chimicatechnoacta.ru/article/view/7761
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author Rufina Zilberg
Renat Salikhov
Ilnur Mullagaliev
Yulia Teres
Elena Bulysheva
Timur Salikhov
Anastasia Ostaltsova
Ivan Vakulin
author_facet Rufina Zilberg
Renat Salikhov
Ilnur Mullagaliev
Yulia Teres
Elena Bulysheva
Timur Salikhov
Anastasia Ostaltsova
Ivan Vakulin
author_sort Rufina Zilberg
collection DOAJ
description Using atomic force microscopy, scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy, the morphology and mobility of charge carriers in composite films with a thickness of no more than 500 nm obtained on the basis of a polyelectrolyte complex of chitosan and chitosan succinamide with addition of particles of carbon materials were studied and estimated.  The following carbon materials were used: single-walled carbon nanotubes, graphene oxide, and carbon-containing sorbents with different specific surfaces (Carboblack C and Carbopack). Moreover, the studied materials in the form of films were used as a transport layer in the structure of field-effect transistors. The output and transfer characteristics of the transistors obtained were measured. According to the measurement results, the mobility of charge carriers, µ, ranges from 0.341 to 1.123 cm2 V–1·s–1, depending on the type of carbon material added. The best result was demonstrated by films based on a composite containing simultaneously single-walled carbon nanotubes and graphene oxide (μ = 10.972 cm2 V–1·s–1).
format Article
id doaj-art-4b9fe62d304c4ae3b301b94624ee8863
institution OA Journals
issn 2411-1414
language English
publishDate 2024-06-01
publisher Ural Federal University
record_format Article
series Chimica Techno Acta
spelling doaj-art-4b9fe62d304c4ae3b301b94624ee88632025-08-20T02:17:49ZengUral Federal UniversityChimica Techno Acta2411-14142024-06-0111310.15826/chimtech.2024.11.3.025374Chitosan-based polyelectrolyte complex in combination with allotropic forms of carbon as a basis of thin-film organic electronicsRufina Zilberg0Renat Salikhov1Ilnur Mullagaliev2Yulia Teres3Elena Bulysheva4Timur Salikhov5Anastasia Ostaltsova6Ivan Vakulin7Ufa University of Science and TechnologyUfa University of Science and TechnologyUfa University of Science and TechnologyUfa University of Science and TechnologyUfa University of Science and TechnologyUfa University of Science and TechnologyUfa University of Science and TechnologyUfa University of Science and TechnologyUsing atomic force microscopy, scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy, the morphology and mobility of charge carriers in composite films with a thickness of no more than 500 nm obtained on the basis of a polyelectrolyte complex of chitosan and chitosan succinamide with addition of particles of carbon materials were studied and estimated.  The following carbon materials were used: single-walled carbon nanotubes, graphene oxide, and carbon-containing sorbents with different specific surfaces (Carboblack C and Carbopack). Moreover, the studied materials in the form of films were used as a transport layer in the structure of field-effect transistors. The output and transfer characteristics of the transistors obtained were measured. According to the measurement results, the mobility of charge carriers, µ, ranges from 0.341 to 1.123 cm2 V–1·s–1, depending on the type of carbon material added. The best result was demonstrated by films based on a composite containing simultaneously single-walled carbon nanotubes and graphene oxide (μ = 10.972 cm2 V–1·s–1).https://chimicatechnoacta.ru/article/view/7761thin filmspolyelectrolyte complex of chitosan and chitosan succinateoxide graphenecarboblack ccarbopackswcntvoltammetryfield-effect transistor
spellingShingle Rufina Zilberg
Renat Salikhov
Ilnur Mullagaliev
Yulia Teres
Elena Bulysheva
Timur Salikhov
Anastasia Ostaltsova
Ivan Vakulin
Chitosan-based polyelectrolyte complex in combination with allotropic forms of carbon as a basis of thin-film organic electronics
Chimica Techno Acta
thin films
polyelectrolyte complex of chitosan and chitosan succinate
oxide graphene
carboblack c
carbopack
swcnt
voltammetry
field-effect transistor
title Chitosan-based polyelectrolyte complex in combination with allotropic forms of carbon as a basis of thin-film organic electronics
title_full Chitosan-based polyelectrolyte complex in combination with allotropic forms of carbon as a basis of thin-film organic electronics
title_fullStr Chitosan-based polyelectrolyte complex in combination with allotropic forms of carbon as a basis of thin-film organic electronics
title_full_unstemmed Chitosan-based polyelectrolyte complex in combination with allotropic forms of carbon as a basis of thin-film organic electronics
title_short Chitosan-based polyelectrolyte complex in combination with allotropic forms of carbon as a basis of thin-film organic electronics
title_sort chitosan based polyelectrolyte complex in combination with allotropic forms of carbon as a basis of thin film organic electronics
topic thin films
polyelectrolyte complex of chitosan and chitosan succinate
oxide graphene
carboblack c
carbopack
swcnt
voltammetry
field-effect transistor
url https://chimicatechnoacta.ru/article/view/7761
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