Design of asymmetric electrolytes for aqueous zinc batteries

Abstract Aqueous Zn batteries are gaining increasing research attention in the energy storage area due to their intrinsic safety, potentially low cost and environmental friendliness; however, the zinc dendrite formation, zinc corrosion, passivation and the hydrogen evolution reaction induced by wate...

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Main Authors: Shengmei Chen, Chunyi Zhi
Format: Article
Language:English
Published: Nature Portfolio 2025-01-01
Series:Communications Chemistry
Online Access:https://doi.org/10.1038/s42004-024-01405-x
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author Shengmei Chen
Chunyi Zhi
author_facet Shengmei Chen
Chunyi Zhi
author_sort Shengmei Chen
collection DOAJ
description Abstract Aqueous Zn batteries are gaining increasing research attention in the energy storage area due to their intrinsic safety, potentially low cost and environmental friendliness; however, the zinc dendrite formation, zinc corrosion, passivation and the hydrogen evolution reaction induced by water at the anode side, and materials dissolution as well as intrinsic poor reaction kinetics at cathode side in aqueous systems, seriously shorten the cycling life and decrease energy density of batteries and greatly hinder their development. Recent advancements in asymmetric electrolytes with various functions are promising to overcome such challenges for zinc batteries at the same time. It has been proved that the applications of asymmetric electrolytes show significant contributions in the field of zinc-based batteries in suppressing side reactions while maintaining electrochemical performance to satisfy both anode and cathode. Therefore, this perspective summarizes recent advancements in asymmetric electrolytes’ design and applications for zinc batteries and outlines opportunities and future challenges, expecting continued research attention in this area.
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institution Kabale University
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publisher Nature Portfolio
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series Communications Chemistry
spelling doaj-art-4ab1bcf49c7442598d8405000e675d8a2025-01-26T12:19:10ZengNature PortfolioCommunications Chemistry2399-36692025-01-018111010.1038/s42004-024-01405-xDesign of asymmetric electrolytes for aqueous zinc batteriesShengmei Chen0Chunyi Zhi1Department of Materials Science and Engineering, City University of Hong KongDepartment of Materials Science and Engineering, City University of Hong KongAbstract Aqueous Zn batteries are gaining increasing research attention in the energy storage area due to their intrinsic safety, potentially low cost and environmental friendliness; however, the zinc dendrite formation, zinc corrosion, passivation and the hydrogen evolution reaction induced by water at the anode side, and materials dissolution as well as intrinsic poor reaction kinetics at cathode side in aqueous systems, seriously shorten the cycling life and decrease energy density of batteries and greatly hinder their development. Recent advancements in asymmetric electrolytes with various functions are promising to overcome such challenges for zinc batteries at the same time. It has been proved that the applications of asymmetric electrolytes show significant contributions in the field of zinc-based batteries in suppressing side reactions while maintaining electrochemical performance to satisfy both anode and cathode. Therefore, this perspective summarizes recent advancements in asymmetric electrolytes’ design and applications for zinc batteries and outlines opportunities and future challenges, expecting continued research attention in this area.https://doi.org/10.1038/s42004-024-01405-x
spellingShingle Shengmei Chen
Chunyi Zhi
Design of asymmetric electrolytes for aqueous zinc batteries
Communications Chemistry
title Design of asymmetric electrolytes for aqueous zinc batteries
title_full Design of asymmetric electrolytes for aqueous zinc batteries
title_fullStr Design of asymmetric electrolytes for aqueous zinc batteries
title_full_unstemmed Design of asymmetric electrolytes for aqueous zinc batteries
title_short Design of asymmetric electrolytes for aqueous zinc batteries
title_sort design of asymmetric electrolytes for aqueous zinc batteries
url https://doi.org/10.1038/s42004-024-01405-x
work_keys_str_mv AT shengmeichen designofasymmetricelectrolytesforaqueouszincbatteries
AT chunyizhi designofasymmetricelectrolytesforaqueouszincbatteries