Long-term aging at 475°C: Effects on the microstructure and properties of custom 465® alloy

This study examines the effects of long-term aging at 475 °C on the microstructure and mechanical properties of the precipitation-hardened stainless-steel alloy, Custom 465®. The research combines theoretical insights with experimental analyses to investigate key transformations occurring during ext...

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Main Authors: Muhammad Ahmad Iqbal, Anum Shafiq
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Results in Engineering
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Online Access:http://www.sciencedirect.com/science/article/pii/S2590123025007819
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author Muhammad Ahmad Iqbal
Anum Shafiq
author_facet Muhammad Ahmad Iqbal
Anum Shafiq
author_sort Muhammad Ahmad Iqbal
collection DOAJ
description This study examines the effects of long-term aging at 475 °C on the microstructure and mechanical properties of the precipitation-hardened stainless-steel alloy, Custom 465®. The research combines theoretical insights with experimental analyses to investigate key transformations occurring during extended thermal exposure. Advanced characterization techniques, including TEM and XRD, showed that quality heat treatment facilitates the precipitation of η-Ni₃Ti particles and the development of a minor portion of RA within tempered lath martensite. Prolonged aging for 1000 and 2000 hours enhances the precipitation of η-Ni₃Ti particles and the α′-Cr-rich phase through the spinodal decomposition of the α-solid solution, accompanied by an increase in the amount of reverted austenite. The mechanical properties of the alloy were found to evolve with aging time. While strength values decreased slightly, elongation and impact energy remained stable, highlighting the critical role of reverted austenite in mitigating the embrittlement caused by the α′-Cr-rich phase. These findings underscore the complex interplay between phase transformations and mechanical behavior, suggesting that controlled heat treatment can optimize the balance between strength and ductility. This research provides valuable insights into the thermal stability of Custom 465® alloy, with implications for its application in demanding engineering environments.
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spelling doaj-art-4a1c95fb4b5c4d22afea37e8ae730b712025-08-20T02:49:25ZengElsevierResults in Engineering2590-12302025-06-012610470410.1016/j.rineng.2025.104704Long-term aging at 475°C: Effects on the microstructure and properties of custom 465® alloyMuhammad Ahmad Iqbal0Anum Shafiq1Institute of Advanced Materials, Bahauddin Zakariya University Multan, Pakistan; Corresponding authors.IT4Innovations, VSB – Technical University of Ostrava, 708 00 Ostrava, Czech Republic; Corresponding authors.This study examines the effects of long-term aging at 475 °C on the microstructure and mechanical properties of the precipitation-hardened stainless-steel alloy, Custom 465®. The research combines theoretical insights with experimental analyses to investigate key transformations occurring during extended thermal exposure. Advanced characterization techniques, including TEM and XRD, showed that quality heat treatment facilitates the precipitation of η-Ni₃Ti particles and the development of a minor portion of RA within tempered lath martensite. Prolonged aging for 1000 and 2000 hours enhances the precipitation of η-Ni₃Ti particles and the α′-Cr-rich phase through the spinodal decomposition of the α-solid solution, accompanied by an increase in the amount of reverted austenite. The mechanical properties of the alloy were found to evolve with aging time. While strength values decreased slightly, elongation and impact energy remained stable, highlighting the critical role of reverted austenite in mitigating the embrittlement caused by the α′-Cr-rich phase. These findings underscore the complex interplay between phase transformations and mechanical behavior, suggesting that controlled heat treatment can optimize the balance between strength and ductility. This research provides valuable insights into the thermal stability of Custom 465® alloy, with implications for its application in demanding engineering environments.http://www.sciencedirect.com/science/article/pii/S2590123025007819Long-term aging475 °C embrittlementprecipitation hardened stainless steelspinodal decompositionreverted austenitemechanical properties
spellingShingle Muhammad Ahmad Iqbal
Anum Shafiq
Long-term aging at 475°C: Effects on the microstructure and properties of custom 465® alloy
Results in Engineering
Long-term aging
475 °C embrittlement
precipitation hardened stainless steel
spinodal decomposition
reverted austenite
mechanical properties
title Long-term aging at 475°C: Effects on the microstructure and properties of custom 465® alloy
title_full Long-term aging at 475°C: Effects on the microstructure and properties of custom 465® alloy
title_fullStr Long-term aging at 475°C: Effects on the microstructure and properties of custom 465® alloy
title_full_unstemmed Long-term aging at 475°C: Effects on the microstructure and properties of custom 465® alloy
title_short Long-term aging at 475°C: Effects on the microstructure and properties of custom 465® alloy
title_sort long term aging at 475°c effects on the microstructure and properties of custom 465 r alloy
topic Long-term aging
475 °C embrittlement
precipitation hardened stainless steel
spinodal decomposition
reverted austenite
mechanical properties
url http://www.sciencedirect.com/science/article/pii/S2590123025007819
work_keys_str_mv AT muhammadahmadiqbal longtermagingat475ceffectsonthemicrostructureandpropertiesofcustom465alloy
AT anumshafiq longtermagingat475ceffectsonthemicrostructureandpropertiesofcustom465alloy