New composite fibres for natural and waste waters decontamination from cesium radionuclides

New composite adsorbent based on modified polyacrylonitrile fibers is synthesized by in situ deposition of potassium-nickel ferrocyanide layer on the fibers’ surface. It is shown that the ferrocyanide phase forms a compact homogeneous layer on the fibers’ surface consisted of rounded nanoaggregates...

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Main Authors: Yu. V. Bondar, S. V. Kuzenko, V. M. Slyvinsky, T. I. Koromyslichenko
Format: Article
Language:English
Published: Institute for Nuclear Research, National Academy of Sciences of Ukraine 2017-08-01
Series:Ядерна фізика та енергетика
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Online Access:http://jnpae.kinr.kiev.ua/18.1/html/18.1.0106.html
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author Yu. V. Bondar
S. V. Kuzenko
V. M. Slyvinsky
T. I. Koromyslichenko
author_facet Yu. V. Bondar
S. V. Kuzenko
V. M. Slyvinsky
T. I. Koromyslichenko
author_sort Yu. V. Bondar
collection DOAJ
description New composite adsorbent based on modified polyacrylonitrile fibers is synthesized by in situ deposition of potassium-nickel ferrocyanide layer on the fibers’ surface. It is shown that the ferrocyanide phase forms a compact homogeneous layer on the fibers’ surface consisted of rounded nanoaggregates (∼ 40 - 50 nm). Composite fibers are chemically stable in both acidic and alkaline solutions. Sorption experiments have demonstrated that synthesized fibers are high-selective adsorbents and can be used for the purification of natural waters and high-salt solutions from cesium radionuclides.
format Article
id doaj-art-49fd3f87a1154b57911393a41dcf606e
institution DOAJ
issn 1818-331X
2074-0565
language English
publishDate 2017-08-01
publisher Institute for Nuclear Research, National Academy of Sciences of Ukraine
record_format Article
series Ядерна фізика та енергетика
spelling doaj-art-49fd3f87a1154b57911393a41dcf606e2025-08-20T02:39:22ZengInstitute for Nuclear Research, National Academy of Sciences of UkraineЯдерна фізика та енергетика1818-331X2074-05652017-08-01181106114New composite fibres for natural and waste waters decontamination from cesium radionuclidesYu. V. Bondar0S. V. Kuzenko1V. M. Slyvinsky2T. I. Koromyslichenko3State Institution "Institute of Environmental Geochemistry", National Academy of Sciences of Ukraine, Kyiv, Ukraine State Institution "Institute of Environmental Geochemistry", National Academy of Sciences of Ukraine, Kyiv, Ukraine State Institution "Institute of Environmental Geochemistry", National Academy of Sciences of Ukraine, Kyiv, Ukraine M. P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation, National Academy of Sciences of Ukraine, Kyiv, Ukraine New composite adsorbent based on modified polyacrylonitrile fibers is synthesized by in situ deposition of potassium-nickel ferrocyanide layer on the fibers’ surface. It is shown that the ferrocyanide phase forms a compact homogeneous layer on the fibers’ surface consisted of rounded nanoaggregates (∼ 40 - 50 nm). Composite fibers are chemically stable in both acidic and alkaline solutions. Sorption experiments have demonstrated that synthesized fibers are high-selective adsorbents and can be used for the purification of natural waters and high-salt solutions from cesium radionuclides.http://jnpae.kinr.kiev.ua/18.1/html/18.1.0106.htmlcomposite adsorbentpolyacrylonitrile fiberspotassium-nickel ferrocyanideselectivity137Cshigh-salt solutionsliquid radioactive waste
spellingShingle Yu. V. Bondar
S. V. Kuzenko
V. M. Slyvinsky
T. I. Koromyslichenko
New composite fibres for natural and waste waters decontamination from cesium radionuclides
Ядерна фізика та енергетика
composite adsorbent
polyacrylonitrile fibers
potassium-nickel ferrocyanide
selectivity
137Cs
high-salt solutions
liquid radioactive waste
title New composite fibres for natural and waste waters decontamination from cesium radionuclides
title_full New composite fibres for natural and waste waters decontamination from cesium radionuclides
title_fullStr New composite fibres for natural and waste waters decontamination from cesium radionuclides
title_full_unstemmed New composite fibres for natural and waste waters decontamination from cesium radionuclides
title_short New composite fibres for natural and waste waters decontamination from cesium radionuclides
title_sort new composite fibres for natural and waste waters decontamination from cesium radionuclides
topic composite adsorbent
polyacrylonitrile fibers
potassium-nickel ferrocyanide
selectivity
137Cs
high-salt solutions
liquid radioactive waste
url http://jnpae.kinr.kiev.ua/18.1/html/18.1.0106.html
work_keys_str_mv AT yuvbondar newcompositefibresfornaturalandwastewatersdecontaminationfromcesiumradionuclides
AT svkuzenko newcompositefibresfornaturalandwastewatersdecontaminationfromcesiumradionuclides
AT vmslyvinsky newcompositefibresfornaturalandwastewatersdecontaminationfromcesiumradionuclides
AT tikoromyslichenko newcompositefibresfornaturalandwastewatersdecontaminationfromcesiumradionuclides