Air Regeneration of a Silicalite Column Loaded with Ethanol: Modelling and Energy Estimation

Concentration-thermal swing adsorption (CTSA) using an ethanol-selective adsorbent can be an attractive option to reduce the energy costs associated with the separation of ethanol from water. In this process, ethanol regeneration is the only step with significant energy consumption, in which the ads...

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Main Authors: José A. Delgado, Vicente I. Agueda, María A. Uguina, José L. Sotelo, Alvaro García, Alicia García-Sanz
Format: Article
Language:English
Published: SAGE Publishing 2012-07-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/0263-6174.30.7.601
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author José A. Delgado
Vicente I. Agueda
María A. Uguina
José L. Sotelo
Alvaro García
Alicia García-Sanz
author_facet José A. Delgado
Vicente I. Agueda
María A. Uguina
José L. Sotelo
Alvaro García
Alicia García-Sanz
author_sort José A. Delgado
collection DOAJ
description Concentration-thermal swing adsorption (CTSA) using an ethanol-selective adsorbent can be an attractive option to reduce the energy costs associated with the separation of ethanol from water. In this process, ethanol regeneration is the only step with significant energy consumption, in which the adsorbent column saturated with liquid ethanol is purged with a hot inert gas to recover ethanol by condensation. Despite many showing interest in applying CTSA, the method has received little attention in the open literature, and consequently little information is available about its energy requirement. In this work, we experimentally measured the regeneration dynamics of a heated silicalite column saturated with liquid ethanol by air purge using different column wall temperatures and purge gas flow rates. Using a theoretical model based on conservation equations, the mass and heat transfer kinetics in this process are adequately reproduced. The proposed model has been used to estimate the overall energy requirement of the ethanol vapourization/desorption and the subsequent condensation processes.
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issn 0263-6174
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language English
publishDate 2012-07-01
publisher SAGE Publishing
record_format Article
series Adsorption Science & Technology
spelling doaj-art-499dc1f2bfee42cd9895c0be1513bec32025-08-20T02:43:25ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382012-07-013010.1260/0263-6174.30.7.601Air Regeneration of a Silicalite Column Loaded with Ethanol: Modelling and Energy EstimationJosé A. DelgadoVicente I. AguedaMaría A. UguinaJosé L. SoteloAlvaro GarcíaAlicia García-SanzConcentration-thermal swing adsorption (CTSA) using an ethanol-selective adsorbent can be an attractive option to reduce the energy costs associated with the separation of ethanol from water. In this process, ethanol regeneration is the only step with significant energy consumption, in which the adsorbent column saturated with liquid ethanol is purged with a hot inert gas to recover ethanol by condensation. Despite many showing interest in applying CTSA, the method has received little attention in the open literature, and consequently little information is available about its energy requirement. In this work, we experimentally measured the regeneration dynamics of a heated silicalite column saturated with liquid ethanol by air purge using different column wall temperatures and purge gas flow rates. Using a theoretical model based on conservation equations, the mass and heat transfer kinetics in this process are adequately reproduced. The proposed model has been used to estimate the overall energy requirement of the ethanol vapourization/desorption and the subsequent condensation processes.https://doi.org/10.1260/0263-6174.30.7.601
spellingShingle José A. Delgado
Vicente I. Agueda
María A. Uguina
José L. Sotelo
Alvaro García
Alicia García-Sanz
Air Regeneration of a Silicalite Column Loaded with Ethanol: Modelling and Energy Estimation
Adsorption Science & Technology
title Air Regeneration of a Silicalite Column Loaded with Ethanol: Modelling and Energy Estimation
title_full Air Regeneration of a Silicalite Column Loaded with Ethanol: Modelling and Energy Estimation
title_fullStr Air Regeneration of a Silicalite Column Loaded with Ethanol: Modelling and Energy Estimation
title_full_unstemmed Air Regeneration of a Silicalite Column Loaded with Ethanol: Modelling and Energy Estimation
title_short Air Regeneration of a Silicalite Column Loaded with Ethanol: Modelling and Energy Estimation
title_sort air regeneration of a silicalite column loaded with ethanol modelling and energy estimation
url https://doi.org/10.1260/0263-6174.30.7.601
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