-Solid Lithium Perchlorate, a Highly Efficient and Chemoselective Catalyst for the Acetalyzation of Aldehydes

-A simple, efficient, and general method has been developed for the chemoselective acetalization of aldehydes with 1,3-propanediol, 1,2-ethanediol and trimethyl orthoformate in the presence of solid lithium perchlorate under solvent-free conditions. Both cyclic and acyclic acetals of aldehydes were...

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Format: Article
Language:English
Published: University of Tehran 2005-03-01
Series:Journal of Sciences, Islamic Republic of Iran
Online Access:https://jsciences.ut.ac.ir/article_31625_b809e4da9298d29895a6c2684b62d555.pdf
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collection DOAJ
description -A simple, efficient, and general method has been developed for the chemoselective acetalization of aldehydes with 1,3-propanediol, 1,2-ethanediol and trimethyl orthoformate in the presence of solid lithium perchlorate under solvent-free conditions. Both cyclic and acyclic acetals of aldehydes were obtained under environmentally benign conditions in good to excellent yields.
format Article
id doaj-art-486e0a8e504c46f188594655ec8a8bcb
institution Kabale University
issn 1016-1104
2345-6914
language English
publishDate 2005-03-01
publisher University of Tehran
record_format Article
series Journal of Sciences, Islamic Republic of Iran
spelling doaj-art-486e0a8e504c46f188594655ec8a8bcb2025-08-20T03:54:07ZengUniversity of TehranJournal of Sciences, Islamic Republic of Iran1016-11042345-69142005-03-0116131625-Solid Lithium Perchlorate, a Highly Efficient and Chemoselective Catalyst for the Acetalyzation of Aldehydes-A simple, efficient, and general method has been developed for the chemoselective acetalization of aldehydes with 1,3-propanediol, 1,2-ethanediol and trimethyl orthoformate in the presence of solid lithium perchlorate under solvent-free conditions. Both cyclic and acyclic acetals of aldehydes were obtained under environmentally benign conditions in good to excellent yields.https://jsciences.ut.ac.ir/article_31625_b809e4da9298d29895a6c2684b62d555.pdf
spellingShingle -Solid Lithium Perchlorate, a Highly Efficient and Chemoselective Catalyst for the Acetalyzation of Aldehydes
Journal of Sciences, Islamic Republic of Iran
title -Solid Lithium Perchlorate, a Highly Efficient and Chemoselective Catalyst for the Acetalyzation of Aldehydes
title_full -Solid Lithium Perchlorate, a Highly Efficient and Chemoselective Catalyst for the Acetalyzation of Aldehydes
title_fullStr -Solid Lithium Perchlorate, a Highly Efficient and Chemoselective Catalyst for the Acetalyzation of Aldehydes
title_full_unstemmed -Solid Lithium Perchlorate, a Highly Efficient and Chemoselective Catalyst for the Acetalyzation of Aldehydes
title_short -Solid Lithium Perchlorate, a Highly Efficient and Chemoselective Catalyst for the Acetalyzation of Aldehydes
title_sort solid lithium perchlorate a highly efficient and chemoselective catalyst for the acetalyzation of aldehydes
url https://jsciences.ut.ac.ir/article_31625_b809e4da9298d29895a6c2684b62d555.pdf