Application of Long-Range Surface Plasmon Resonance for ABO Blood Typing

In this study, we demonstrate a long-range surface plasmon resonance (LR-SPR) biosensor for the detection of whole cell by captured antigens A and B on the surface of red blood cells (RBCs) as a model. The LR-SPR sensor chip consists of high-refractive index glass, a Cytop film layer, and a thin gol...

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Main Authors: Wanida Tangkawsakul, Toemsak Srikhirin, Kazunari Shinbo, Keizo Kato, Futao Kaneko, Akira Baba
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:International Journal of Analytical Chemistry
Online Access:http://dx.doi.org/10.1155/2016/1432781
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author Wanida Tangkawsakul
Toemsak Srikhirin
Kazunari Shinbo
Keizo Kato
Futao Kaneko
Akira Baba
author_facet Wanida Tangkawsakul
Toemsak Srikhirin
Kazunari Shinbo
Keizo Kato
Futao Kaneko
Akira Baba
author_sort Wanida Tangkawsakul
collection DOAJ
description In this study, we demonstrate a long-range surface plasmon resonance (LR-SPR) biosensor for the detection of whole cell by captured antigens A and B on the surface of red blood cells (RBCs) as a model. The LR-SPR sensor chip consists of high-refractive index glass, a Cytop film layer, and a thin gold (Au) film, which makes the evanescent field intensity and the penetration depth longer than conventional SPR. Therefore, the LR-SPR biosensor has improved capability for detecting large analytes, such as RBCs. The antibodies specific to blood group A and group B (Anti-A and Anti-B) are covalently immobilized on a grafting self-assembled monolayer (SAM)/Au surface on the biosensor. For blood typing, RBC samples can be detected by the LR-SPR biosensor through a change in the refractive index. We determined that the results of blood typing using the LR-SPR biosensor are consistent with the results obtained from the agglutination test. We obtained the lowest detection limits of 1.58 × 105 cells/ml for RBC-A and 3.83 × 105 cells/ml for RBC-B, indicating that the LR-SPR chip has a higher sensitivity than conventional SPR biosensors (3.3 × 108 cells/ml). The surface of the biosensor can be efficiently regenerated using 20 mM NaOH. In summary, as the LR-SPR technique is sensitive and has a simple experimental setup, it can easily be applied for ABO blood group typing.
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spelling doaj-art-4840a2a553344ea7bdbb8f96af24fa372025-08-20T02:38:02ZengWileyInternational Journal of Analytical Chemistry1687-87601687-87792016-01-01201610.1155/2016/14327811432781Application of Long-Range Surface Plasmon Resonance for ABO Blood TypingWanida Tangkawsakul0Toemsak Srikhirin1Kazunari Shinbo2Keizo Kato3Futao Kaneko4Akira Baba5Graduate School of Science and Technology and Center for Transdisciplinary Research, Niigata University, 8050 Ikarashi 2-Nocho, Nishi-ku, Niigata 950-2181, JapanMaterials Science and Engineering Programme, Multidisciplinary Unit and Center of Intelligence Materials and Systems, NANOTEC Center of Excellence at Mahidol University, Department of Physics, Faculty of Science, Mahidol University, Rama 6 Rd., Phayathai, Rajathavee, Bangkok 10400, ThailandGraduate School of Science and Technology and Center for Transdisciplinary Research, Niigata University, 8050 Ikarashi 2-Nocho, Nishi-ku, Niigata 950-2181, JapanGraduate School of Science and Technology and Center for Transdisciplinary Research, Niigata University, 8050 Ikarashi 2-Nocho, Nishi-ku, Niigata 950-2181, JapanGraduate School of Science and Technology and Center for Transdisciplinary Research, Niigata University, 8050 Ikarashi 2-Nocho, Nishi-ku, Niigata 950-2181, JapanGraduate School of Science and Technology and Center for Transdisciplinary Research, Niigata University, 8050 Ikarashi 2-Nocho, Nishi-ku, Niigata 950-2181, JapanIn this study, we demonstrate a long-range surface plasmon resonance (LR-SPR) biosensor for the detection of whole cell by captured antigens A and B on the surface of red blood cells (RBCs) as a model. The LR-SPR sensor chip consists of high-refractive index glass, a Cytop film layer, and a thin gold (Au) film, which makes the evanescent field intensity and the penetration depth longer than conventional SPR. Therefore, the LR-SPR biosensor has improved capability for detecting large analytes, such as RBCs. The antibodies specific to blood group A and group B (Anti-A and Anti-B) are covalently immobilized on a grafting self-assembled monolayer (SAM)/Au surface on the biosensor. For blood typing, RBC samples can be detected by the LR-SPR biosensor through a change in the refractive index. We determined that the results of blood typing using the LR-SPR biosensor are consistent with the results obtained from the agglutination test. We obtained the lowest detection limits of 1.58 × 105 cells/ml for RBC-A and 3.83 × 105 cells/ml for RBC-B, indicating that the LR-SPR chip has a higher sensitivity than conventional SPR biosensors (3.3 × 108 cells/ml). The surface of the biosensor can be efficiently regenerated using 20 mM NaOH. In summary, as the LR-SPR technique is sensitive and has a simple experimental setup, it can easily be applied for ABO blood group typing.http://dx.doi.org/10.1155/2016/1432781
spellingShingle Wanida Tangkawsakul
Toemsak Srikhirin
Kazunari Shinbo
Keizo Kato
Futao Kaneko
Akira Baba
Application of Long-Range Surface Plasmon Resonance for ABO Blood Typing
International Journal of Analytical Chemistry
title Application of Long-Range Surface Plasmon Resonance for ABO Blood Typing
title_full Application of Long-Range Surface Plasmon Resonance for ABO Blood Typing
title_fullStr Application of Long-Range Surface Plasmon Resonance for ABO Blood Typing
title_full_unstemmed Application of Long-Range Surface Plasmon Resonance for ABO Blood Typing
title_short Application of Long-Range Surface Plasmon Resonance for ABO Blood Typing
title_sort application of long range surface plasmon resonance for abo blood typing
url http://dx.doi.org/10.1155/2016/1432781
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AT keizokato applicationoflongrangesurfaceplasmonresonanceforabobloodtyping
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