Algorithm for using dual energy computed tomography to determine chemical composition: A feasibility study.

Using dual-energy computed tomography (CT), this study aims to develop an algorithm to identify the chemical constituents of an unknown material (compound or mixture) and improve the accuracy of material discrimination. The algorithm requires mass attenuation coefficients (MAC) that were obtained us...

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Main Authors: Dong Hyeok Choi, So Hyun Ahn, Kwangwoo Park, Min Cheol Han, Jin Sung Kim
Format: Article
Language:English
Published: Public Library of Science (PLoS) 2025-01-01
Series:PLoS ONE
Online Access:https://doi.org/10.1371/journal.pone.0322805
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author Dong Hyeok Choi
So Hyun Ahn
Kwangwoo Park
Min Cheol Han
Jin Sung Kim
author_facet Dong Hyeok Choi
So Hyun Ahn
Kwangwoo Park
Min Cheol Han
Jin Sung Kim
author_sort Dong Hyeok Choi
collection DOAJ
description Using dual-energy computed tomography (CT), this study aims to develop an algorithm to identify the chemical constituents of an unknown material (compound or mixture) and improve the accuracy of material discrimination. The algorithm requires mass attenuation coefficients (MAC) that were obtained using a dual energy CT as an input, identifies the elemental composition, and then calculates its weight fraction. To evaluate the functionality of the developed algorithm, it was used to determine the chemical constituents for human tissues. Furthermore, the results were compared with those provided by the National Institute of Standards and Technology (NIST). We used dual energies 80/140 kVp for spectral CT scans, as inputs to the algorithm, in addition to a set of 50/80 and 80/100 keV for mono-energetic X-rays. The algorithm correctly determined the chemical constituent elements of unknown materials. Results were obtained for the fractional weights of each component for mono-energetic X-rays and spectral X-ray use. For mono-energetic X-rays, the differences were < 0.01% for compounds and 6.02% for mixture, respectively. For the spectral X-rays, the differences in 2.98% for compounds and 6.03% for mixtures, respectively. We developed an algorithm to determine the type and weight fraction of an element using the MAC of dual-energy CT. The algorithm can exclude the inherent uncertainty of SPR calculations and improve the accuracy of dose calculations in radiation therapy planning.
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institution Kabale University
issn 1932-6203
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spelling doaj-art-48401b16ab454fbc9b6ac18ca42dce122025-08-20T03:50:06ZengPublic Library of Science (PLoS)PLoS ONE1932-62032025-01-01206e032280510.1371/journal.pone.0322805Algorithm for using dual energy computed tomography to determine chemical composition: A feasibility study.Dong Hyeok ChoiSo Hyun AhnKwangwoo ParkMin Cheol HanJin Sung KimUsing dual-energy computed tomography (CT), this study aims to develop an algorithm to identify the chemical constituents of an unknown material (compound or mixture) and improve the accuracy of material discrimination. The algorithm requires mass attenuation coefficients (MAC) that were obtained using a dual energy CT as an input, identifies the elemental composition, and then calculates its weight fraction. To evaluate the functionality of the developed algorithm, it was used to determine the chemical constituents for human tissues. Furthermore, the results were compared with those provided by the National Institute of Standards and Technology (NIST). We used dual energies 80/140 kVp for spectral CT scans, as inputs to the algorithm, in addition to a set of 50/80 and 80/100 keV for mono-energetic X-rays. The algorithm correctly determined the chemical constituent elements of unknown materials. Results were obtained for the fractional weights of each component for mono-energetic X-rays and spectral X-ray use. For mono-energetic X-rays, the differences were < 0.01% for compounds and 6.02% for mixture, respectively. For the spectral X-rays, the differences in 2.98% for compounds and 6.03% for mixtures, respectively. We developed an algorithm to determine the type and weight fraction of an element using the MAC of dual-energy CT. The algorithm can exclude the inherent uncertainty of SPR calculations and improve the accuracy of dose calculations in radiation therapy planning.https://doi.org/10.1371/journal.pone.0322805
spellingShingle Dong Hyeok Choi
So Hyun Ahn
Kwangwoo Park
Min Cheol Han
Jin Sung Kim
Algorithm for using dual energy computed tomography to determine chemical composition: A feasibility study.
PLoS ONE
title Algorithm for using dual energy computed tomography to determine chemical composition: A feasibility study.
title_full Algorithm for using dual energy computed tomography to determine chemical composition: A feasibility study.
title_fullStr Algorithm for using dual energy computed tomography to determine chemical composition: A feasibility study.
title_full_unstemmed Algorithm for using dual energy computed tomography to determine chemical composition: A feasibility study.
title_short Algorithm for using dual energy computed tomography to determine chemical composition: A feasibility study.
title_sort algorithm for using dual energy computed tomography to determine chemical composition a feasibility study
url https://doi.org/10.1371/journal.pone.0322805
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