Interplay between multipolar order and multipole-induced superconductivity in PrTi2Al20

Abstract Multipolar moments entail a new route to tackle frontier problems in superconductivity (SC). A key progress in the search for multipolar SC is the discovery of PrT r 2Al20 (T r = Ti, V), which possesses quadrupolar and octupolar but no magnetic dipolar moments. The Kondo entanglement of the...

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Main Authors: Akito Sakai, Yosuke Matsumoto, Mingxuan Fu, Takachika Isomae, Masaki Tsujimoto, Eoin O’Farrell, Daisuke Nishio-Hamane, Satoru Nakatsuji
Format: Article
Language:English
Published: Nature Portfolio 2025-03-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-025-57262-2
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author Akito Sakai
Yosuke Matsumoto
Mingxuan Fu
Takachika Isomae
Masaki Tsujimoto
Eoin O’Farrell
Daisuke Nishio-Hamane
Satoru Nakatsuji
author_facet Akito Sakai
Yosuke Matsumoto
Mingxuan Fu
Takachika Isomae
Masaki Tsujimoto
Eoin O’Farrell
Daisuke Nishio-Hamane
Satoru Nakatsuji
author_sort Akito Sakai
collection DOAJ
description Abstract Multipolar moments entail a new route to tackle frontier problems in superconductivity (SC). A key progress in the search for multipolar SC is the discovery of PrT r 2Al20 (T r = Ti, V), which possesses quadrupolar and octupolar but no magnetic dipolar moments. The Kondo entanglement of these multipolar moments with conduction electrons leads to exotic SC within the multipolar ordered phase, though the precise nature of the SC remains unexplored. We experimentally investigate the SC gap structure of SC in PrTi2Al20 and its La-doping evolution. Our results indicate deviations from a single s-wave gap, instead favoring nodal d-wave or multiple gaps. While the SC is robust against La dilution, the SC gap structure changes with minimal La doping, coinciding with a sharp change in the ferroquadrupolar (FQ) order. This suggests an intimate link between the quadrupolar order parameter and SC pairing, providing insight into the coexistence of SC with multipolar order.
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issn 2041-1723
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spelling doaj-art-47f17cdf7f9e4126a5875bd22840a44f2025-08-20T01:57:27ZengNature PortfolioNature Communications2041-17232025-03-011611810.1038/s41467-025-57262-2Interplay between multipolar order and multipole-induced superconductivity in PrTi2Al20Akito Sakai0Yosuke Matsumoto1Mingxuan Fu2Takachika Isomae3Masaki Tsujimoto4Eoin O’Farrell5Daisuke Nishio-Hamane6Satoru Nakatsuji7Department of Physics, University of TokyoInstitute for Solid State Physics, University of TokyoDepartment of Physics, University of TokyoDepartment of Physics, University of TokyoInstitute for Solid State Physics, University of TokyoInstitute for Solid State Physics, University of TokyoInstitute for Solid State Physics, University of TokyoDepartment of Physics, University of TokyoAbstract Multipolar moments entail a new route to tackle frontier problems in superconductivity (SC). A key progress in the search for multipolar SC is the discovery of PrT r 2Al20 (T r = Ti, V), which possesses quadrupolar and octupolar but no magnetic dipolar moments. The Kondo entanglement of these multipolar moments with conduction electrons leads to exotic SC within the multipolar ordered phase, though the precise nature of the SC remains unexplored. We experimentally investigate the SC gap structure of SC in PrTi2Al20 and its La-doping evolution. Our results indicate deviations from a single s-wave gap, instead favoring nodal d-wave or multiple gaps. While the SC is robust against La dilution, the SC gap structure changes with minimal La doping, coinciding with a sharp change in the ferroquadrupolar (FQ) order. This suggests an intimate link between the quadrupolar order parameter and SC pairing, providing insight into the coexistence of SC with multipolar order.https://doi.org/10.1038/s41467-025-57262-2
spellingShingle Akito Sakai
Yosuke Matsumoto
Mingxuan Fu
Takachika Isomae
Masaki Tsujimoto
Eoin O’Farrell
Daisuke Nishio-Hamane
Satoru Nakatsuji
Interplay between multipolar order and multipole-induced superconductivity in PrTi2Al20
Nature Communications
title Interplay between multipolar order and multipole-induced superconductivity in PrTi2Al20
title_full Interplay between multipolar order and multipole-induced superconductivity in PrTi2Al20
title_fullStr Interplay between multipolar order and multipole-induced superconductivity in PrTi2Al20
title_full_unstemmed Interplay between multipolar order and multipole-induced superconductivity in PrTi2Al20
title_short Interplay between multipolar order and multipole-induced superconductivity in PrTi2Al20
title_sort interplay between multipolar order and multipole induced superconductivity in prti2al20
url https://doi.org/10.1038/s41467-025-57262-2
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