Sturdy spin-momentum locking in a chiral organic superconductor

Among noncentrosymmetric structures, chirality has recently been recognized as a novel source of asymmetrical charge/spin transports as exemplified by electrical magnetochiral anisotropy (EMChA) and chirality-induced spin selectivity. Although similar bulk-charge rectification and the Rashba-Edelste...

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Bibliographic Details
Main Authors: Takuro Sato, Hiroshi Goto, Hiroshi M. Yamamoto
Format: Article
Language:English
Published: American Physical Society 2025-04-01
Series:Physical Review Research
Online Access:http://doi.org/10.1103/PhysRevResearch.7.023056
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Summary:Among noncentrosymmetric structures, chirality has recently been recognized as a novel source of asymmetrical charge/spin transports as exemplified by electrical magnetochiral anisotropy (EMChA) and chirality-induced spin selectivity. Although similar bulk-charge rectification and the Rashba-Edelstein effect in polar systems are quantitively reproducible by theory based on the electronic band structures, the relevance of band parameters in chiral effects remains elusive. Here, by working with a chiral organic superconductor, we experimentally demonstrate a gigantic EMChA and large superconducting diode effect, both of which are difficult to be explained solely by its band parameters. A two-critical-current signature and an enhanced critical field suggested triplet-mixed Cooper pairs with anomalously enhanced spin-orbit coupling above atomic limit. Our results clearly highlight a unique spin-momentum locking with large stiffness beyond the expectation, suggesting an unknown driving force for spin polarization inherent to chirality.
ISSN:2643-1564