Single layer graphene protective layer on GaAs photocathodes for spin-polarized electron source

GaAs-based photocathodes are the primary choice for polarized electron sources, commonly used in polarized electron microscopes and polarized positron sources. GaAs photocathodes are typically activated with cesium and oxygen, which are highly reactive and require an ultra-high vacuum (∼10−11 Torr o...

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Main Authors: Jyoti Biswas, Mengjia Gaowei, Kali Prasanna Mondal, Erdong Wang, Jerzy T. Sadowski, Abdullah Al-Mahboob, Xiao Tong
Format: Article
Language:English
Published: AIP Publishing LLC 2025-06-01
Series:APL Materials
Online Access:http://dx.doi.org/10.1063/5.0271386
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author Jyoti Biswas
Mengjia Gaowei
Kali Prasanna Mondal
Erdong Wang
Jerzy T. Sadowski
Abdullah Al-Mahboob
Xiao Tong
author_facet Jyoti Biswas
Mengjia Gaowei
Kali Prasanna Mondal
Erdong Wang
Jerzy T. Sadowski
Abdullah Al-Mahboob
Xiao Tong
author_sort Jyoti Biswas
collection DOAJ
description GaAs-based photocathodes are the primary choice for polarized electron sources, commonly used in polarized electron microscopes and polarized positron sources. GaAs photocathodes are typically activated with cesium and oxygen, which are highly reactive and require an ultra-high vacuum (∼10−11 Torr or lower) to operate reliably, resulting in substantial operational difficulties. A short exposure to a mediocre vacuum results in an instantaneous loss of cathode quantum efficiency (QE) due to the chemical reaction of the active layer with residual gas molecules or back-bombardment ions during operation. Covering the GaAs cathode with a 2D material, such as monolayer graphene, could provide protection against such damage due to the inhibition of chemical reactions with residual gas molecules. In this paper, we have incorporated a method known as intercalation to pass the active material underneath the graphene and activate the superlattice GaAs/GaAsP (SL-GaAs) photocathode. X-ray photoelectron spectroscopy, low-energy electron microscopy, and Mott scattering measurements were performed to evaluate the formation of the photocathode under graphene, as well as its spectral response and electron spin polarization. Our results demonstrate that the successful activation of the SL-GaAs photocathode with a graphene protection layer is achieved with a moderate QE. Furthermore, we found that the electron spin polarization of the cathode with a surface protection layer is higher than the conventional cathode without a protection layer.
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spelling doaj-art-47827b7c883145dc984a9367bf03f8df2025-08-20T03:30:37ZengAIP Publishing LLCAPL Materials2166-532X2025-06-01136061101061101-710.1063/5.0271386Single layer graphene protective layer on GaAs photocathodes for spin-polarized electron sourceJyoti Biswas0Mengjia Gaowei1Kali Prasanna Mondal2Erdong Wang3Jerzy T. Sadowski4Abdullah Al-Mahboob5Xiao Tong6Electron-Ion Collider, Brookhaven National Laboratory, Upton, New York 11973, USACollider-Accelerator Department, Brookhaven National Laboratory, Upton, New York 11973, USACollider-Accelerator Department, Brookhaven National Laboratory, Upton, New York 11973, USAElectron-Ion Collider, Brookhaven National Laboratory, Upton, New York 11973, USACenter for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, USACenter for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, USACenter for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, USAGaAs-based photocathodes are the primary choice for polarized electron sources, commonly used in polarized electron microscopes and polarized positron sources. GaAs photocathodes are typically activated with cesium and oxygen, which are highly reactive and require an ultra-high vacuum (∼10−11 Torr or lower) to operate reliably, resulting in substantial operational difficulties. A short exposure to a mediocre vacuum results in an instantaneous loss of cathode quantum efficiency (QE) due to the chemical reaction of the active layer with residual gas molecules or back-bombardment ions during operation. Covering the GaAs cathode with a 2D material, such as monolayer graphene, could provide protection against such damage due to the inhibition of chemical reactions with residual gas molecules. In this paper, we have incorporated a method known as intercalation to pass the active material underneath the graphene and activate the superlattice GaAs/GaAsP (SL-GaAs) photocathode. X-ray photoelectron spectroscopy, low-energy electron microscopy, and Mott scattering measurements were performed to evaluate the formation of the photocathode under graphene, as well as its spectral response and electron spin polarization. Our results demonstrate that the successful activation of the SL-GaAs photocathode with a graphene protection layer is achieved with a moderate QE. Furthermore, we found that the electron spin polarization of the cathode with a surface protection layer is higher than the conventional cathode without a protection layer.http://dx.doi.org/10.1063/5.0271386
spellingShingle Jyoti Biswas
Mengjia Gaowei
Kali Prasanna Mondal
Erdong Wang
Jerzy T. Sadowski
Abdullah Al-Mahboob
Xiao Tong
Single layer graphene protective layer on GaAs photocathodes for spin-polarized electron source
APL Materials
title Single layer graphene protective layer on GaAs photocathodes for spin-polarized electron source
title_full Single layer graphene protective layer on GaAs photocathodes for spin-polarized electron source
title_fullStr Single layer graphene protective layer on GaAs photocathodes for spin-polarized electron source
title_full_unstemmed Single layer graphene protective layer on GaAs photocathodes for spin-polarized electron source
title_short Single layer graphene protective layer on GaAs photocathodes for spin-polarized electron source
title_sort single layer graphene protective layer on gaas photocathodes for spin polarized electron source
url http://dx.doi.org/10.1063/5.0271386
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