Technoeconomic Insights into Metal Hydrides for Stationary Hydrogen Storage

Abstract Metal hydrides (MHs) are promising candidates for storing hydrogen at ambient conditions at high volumetric energy densities. Recent developments suggest hydride‐based systems can cycle and operate at favorable pressures and temperatures that work well with fuel cells used in stationary pow...

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Main Authors: Xinyi Wang, Peng Peng, Matthew D. Witman, Vitalie Stavila, Mark D. Allendorf, Hanna M. Breunig
Format: Article
Language:English
Published: Wiley 2025-06-01
Series:Advanced Science
Subjects:
Online Access:https://doi.org/10.1002/advs.202415736
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author Xinyi Wang
Peng Peng
Matthew D. Witman
Vitalie Stavila
Mark D. Allendorf
Hanna M. Breunig
author_facet Xinyi Wang
Peng Peng
Matthew D. Witman
Vitalie Stavila
Mark D. Allendorf
Hanna M. Breunig
author_sort Xinyi Wang
collection DOAJ
description Abstract Metal hydrides (MHs) are promising candidates for storing hydrogen at ambient conditions at high volumetric energy densities. Recent developments suggest hydride‐based systems can cycle and operate at favorable pressures and temperatures that work well with fuel cells used in stationary power applications. In this study, we present a comprehensive design and cost analysis of MH‐based long duration hydrogen storage facilities for a variety of power end users (0 to 20 megawatts (MW) supplied over 0 to 100 hours), to offer insights on technical targets for material development and operation strategies. Our findings indicate that hydride‐based storage systems hold significant size advantage in physical footprint, requiring up to 65% less land than 170‐bar compressed gas storage. Metal hydride systems can be cost competitive with 350‐bar compressed gas systems, with TiFe0.85Mn0.05 achieving $0.45/kWh and complex MH Mg(NH2)2‐2.1LiH‐0.1KH achieving $0.38/kWh. Extending charging times and increasing operating cycles significantly reduce levelized cost of storage, especially for complex MHs. Key strategies to further enhance the competitiveness of MHs include leveraging waste heat from fuel cells, reducing use of critical minerals, and achieving MH production costs of US$10/kg.
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spelling doaj-art-477c2cd7a6ba4a09ad14d421810ce8ec2025-08-20T02:32:26ZengWileyAdvanced Science2198-38442025-06-011221n/an/a10.1002/advs.202415736Technoeconomic Insights into Metal Hydrides for Stationary Hydrogen StorageXinyi Wang0Peng Peng1Matthew D. Witman2Vitalie Stavila3Mark D. Allendorf4Hanna M. Breunig5Lawrence Berkeley National Laboratory Berkeley CA 94720 USALawrence Berkeley National Laboratory Berkeley CA 94720 USASandia National Laboratories Livermore CA 94550 USASandia National Laboratories Livermore CA 94550 USASandia National Laboratories Livermore CA 94550 USALawrence Berkeley National Laboratory Berkeley CA 94720 USAAbstract Metal hydrides (MHs) are promising candidates for storing hydrogen at ambient conditions at high volumetric energy densities. Recent developments suggest hydride‐based systems can cycle and operate at favorable pressures and temperatures that work well with fuel cells used in stationary power applications. In this study, we present a comprehensive design and cost analysis of MH‐based long duration hydrogen storage facilities for a variety of power end users (0 to 20 megawatts (MW) supplied over 0 to 100 hours), to offer insights on technical targets for material development and operation strategies. Our findings indicate that hydride‐based storage systems hold significant size advantage in physical footprint, requiring up to 65% less land than 170‐bar compressed gas storage. Metal hydride systems can be cost competitive with 350‐bar compressed gas systems, with TiFe0.85Mn0.05 achieving $0.45/kWh and complex MH Mg(NH2)2‐2.1LiH‐0.1KH achieving $0.38/kWh. Extending charging times and increasing operating cycles significantly reduce levelized cost of storage, especially for complex MHs. Key strategies to further enhance the competitiveness of MHs include leveraging waste heat from fuel cells, reducing use of critical minerals, and achieving MH production costs of US$10/kg.https://doi.org/10.1002/advs.202415736critical mineralsHydrogen storagemetal hydridetechno‐economic analysis
spellingShingle Xinyi Wang
Peng Peng
Matthew D. Witman
Vitalie Stavila
Mark D. Allendorf
Hanna M. Breunig
Technoeconomic Insights into Metal Hydrides for Stationary Hydrogen Storage
Advanced Science
critical minerals
Hydrogen storage
metal hydride
techno‐economic analysis
title Technoeconomic Insights into Metal Hydrides for Stationary Hydrogen Storage
title_full Technoeconomic Insights into Metal Hydrides for Stationary Hydrogen Storage
title_fullStr Technoeconomic Insights into Metal Hydrides for Stationary Hydrogen Storage
title_full_unstemmed Technoeconomic Insights into Metal Hydrides for Stationary Hydrogen Storage
title_short Technoeconomic Insights into Metal Hydrides for Stationary Hydrogen Storage
title_sort technoeconomic insights into metal hydrides for stationary hydrogen storage
topic critical minerals
Hydrogen storage
metal hydride
techno‐economic analysis
url https://doi.org/10.1002/advs.202415736
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AT matthewdwitman technoeconomicinsightsintometalhydridesforstationaryhydrogenstorage
AT vitaliestavila technoeconomicinsightsintometalhydridesforstationaryhydrogenstorage
AT markdallendorf technoeconomicinsightsintometalhydridesforstationaryhydrogenstorage
AT hannambreunig technoeconomicinsightsintometalhydridesforstationaryhydrogenstorage