H2 Chemistry and Protonation in the Dayside Venusian Upper Atmosphere

Although H _2 is present in low concentrations, it critically controls the structure and composition of planetary upper atmospheres through protonation under solar extreme-ultraviolet and soft X-ray irradiation. Recent studies highlight the importance of protonation on Venus. As H _2 concentrations...

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Bibliographic Details
Main Authors: Shiqi Wu, Xiaoshu Wu, Yanxing Liu, Jun Cui
Format: Article
Language:English
Published: IOP Publishing 2025-01-01
Series:The Astronomical Journal
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Online Access:https://doi.org/10.3847/1538-3881/ad9d43
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Summary:Although H _2 is present in low concentrations, it critically controls the structure and composition of planetary upper atmospheres through protonation under solar extreme-ultraviolet and soft X-ray irradiation. Recent studies highlight the importance of protonation on Venus. As H _2 concentrations in its upper atmosphere remain poorly constrained, we conduct a systematic model investigation of how the structure of the topside Venusian ionosphere responds to varying H _2 distributions. Our model results suggest that protonated species could outnumber nonprotonated species in the topside ionosphere when ambient H _2 concentrations exceed 5 ppm. Generally, increasing H _2 concentrations enhances the degree of protonation, manifesting as elevated levels of most protonated species, while nonprotonated species are generally depleted due to rapid reactions with H _2 . These trends, however, are not universal; nonmonotonic variations among multiple species like OH ^+ and O ${}_{2}^{+}$ emerge, driven by the complex chemical network that intricately links species distributions throughout the upper atmosphere. The results presented here provide a foundation for improved characterization of hydrogen escape on Venus during its evolutionary history.
ISSN:1538-3881