5,6-dihydroxyflavone exerts anti-betacoronavirus activity by blocking viral entry to host cells

Baicalin, a bioactive flavone found in Scutellaria baicalensis Georgi has anti-SARS-CoV-2 infection by targeting viral 3C-like protease (3CLpro). However, little is known about the antiviral activity of its 7-deoxy analogue, 5,6-dihydroxyflavone (5,6-DHF), especially against betacoronaviruses (beta-...

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Main Authors: Yujia Cao, Kah Man Lai, Hongling Zheng, Yee Joo Tan, Dejian Huang
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Virus Research
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Online Access:http://www.sciencedirect.com/science/article/pii/S0168170225000553
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author Yujia Cao
Kah Man Lai
Hongling Zheng
Yee Joo Tan
Dejian Huang
author_facet Yujia Cao
Kah Man Lai
Hongling Zheng
Yee Joo Tan
Dejian Huang
author_sort Yujia Cao
collection DOAJ
description Baicalin, a bioactive flavone found in Scutellaria baicalensis Georgi has anti-SARS-CoV-2 infection by targeting viral 3C-like protease (3CLpro). However, little is known about the antiviral activity of its 7-deoxy analogue, 5,6-dihydroxyflavone (5,6-DHF), especially against betacoronaviruses (beta-CoVs). We found that 5,6-DHF exhibited more potent anti-SARS-CoV-2 Omicron variant EG.5.1.1 activity than baicalein by microneutralization test (MNT) and plaque reduction neutralization test (PRNT). 5,6-Dihydroxyl (catechol) groups at A ring of 5,6-DHF is essential for its suppression on SARS-CoV-2 Omicron variant EG.5.1.1 infection because blocking them with methyl or methylene groups obsolesce the activity. 3CLpro inhibition assay showed that the antiviral activity of 5,6-DHF is distinctive with baicalein. Time of addition test, molecular docking and spike-bearing pseudotyped virus entry assay suggested that 5,6-DHF interferes the spike-ACE2 interaction by targeting at receptor binding domain (RBD) of spike and hence inhibits the virus replication. In addition to SARS-CoV-2 Omicron variant EG.5.1.1, 5,6-DHF was also found effective against another common human beta-CoVs, HCoV-OC43, by blocking their entry to host cells. Taken together, the present study demonstrated the potential function of 5,6-DHF as a therapeutic candidate against beta-CoVs.
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spelling doaj-art-46c7c8bbe7a24dc99a1c1e3ec9e4a9192025-08-20T03:47:41ZengElsevierVirus Research1872-74922025-06-0135619957810.1016/j.virusres.2025.1995785,6-dihydroxyflavone exerts anti-betacoronavirus activity by blocking viral entry to host cellsYujia Cao0Kah Man Lai1Hongling Zheng2Yee Joo Tan3Dejian Huang4Department of Food Science and Technology, National University of Singapore, Singapore 117542, SingaporeInfectious Diseases Translational Research Program and Department of Microbiology and Immunology, Yong Loo Lin School of Medicine, National University of Singapore, Singapore 117545, SingaporeDepartment of Food Science and Technology, National University of Singapore, Singapore 117542, SingaporeInfectious Diseases Translational Research Program and Department of Microbiology and Immunology, Yong Loo Lin School of Medicine, National University of Singapore, Singapore 117545, Singapore; Corresponding authors.Department of Food Science and Technology, National University of Singapore, Singapore 117542, Singapore; National University of Singapore (Suzhou) Research Institute, 377 Linquan Street, Suzhou 215123, PR China; Corresponding authors.Baicalin, a bioactive flavone found in Scutellaria baicalensis Georgi has anti-SARS-CoV-2 infection by targeting viral 3C-like protease (3CLpro). However, little is known about the antiviral activity of its 7-deoxy analogue, 5,6-dihydroxyflavone (5,6-DHF), especially against betacoronaviruses (beta-CoVs). We found that 5,6-DHF exhibited more potent anti-SARS-CoV-2 Omicron variant EG.5.1.1 activity than baicalein by microneutralization test (MNT) and plaque reduction neutralization test (PRNT). 5,6-Dihydroxyl (catechol) groups at A ring of 5,6-DHF is essential for its suppression on SARS-CoV-2 Omicron variant EG.5.1.1 infection because blocking them with methyl or methylene groups obsolesce the activity. 3CLpro inhibition assay showed that the antiviral activity of 5,6-DHF is distinctive with baicalein. Time of addition test, molecular docking and spike-bearing pseudotyped virus entry assay suggested that 5,6-DHF interferes the spike-ACE2 interaction by targeting at receptor binding domain (RBD) of spike and hence inhibits the virus replication. In addition to SARS-CoV-2 Omicron variant EG.5.1.1, 5,6-DHF was also found effective against another common human beta-CoVs, HCoV-OC43, by blocking their entry to host cells. Taken together, the present study demonstrated the potential function of 5,6-DHF as a therapeutic candidate against beta-CoVs.http://www.sciencedirect.com/science/article/pii/S0168170225000553Anti-coronavirus5,6-dihydroxyflavoneReceptor-binding domainFlavonesSars-cov-2
spellingShingle Yujia Cao
Kah Man Lai
Hongling Zheng
Yee Joo Tan
Dejian Huang
5,6-dihydroxyflavone exerts anti-betacoronavirus activity by blocking viral entry to host cells
Virus Research
Anti-coronavirus
5,6-dihydroxyflavone
Receptor-binding domain
Flavones
Sars-cov-2
title 5,6-dihydroxyflavone exerts anti-betacoronavirus activity by blocking viral entry to host cells
title_full 5,6-dihydroxyflavone exerts anti-betacoronavirus activity by blocking viral entry to host cells
title_fullStr 5,6-dihydroxyflavone exerts anti-betacoronavirus activity by blocking viral entry to host cells
title_full_unstemmed 5,6-dihydroxyflavone exerts anti-betacoronavirus activity by blocking viral entry to host cells
title_short 5,6-dihydroxyflavone exerts anti-betacoronavirus activity by blocking viral entry to host cells
title_sort 5 6 dihydroxyflavone exerts anti betacoronavirus activity by blocking viral entry to host cells
topic Anti-coronavirus
5,6-dihydroxyflavone
Receptor-binding domain
Flavones
Sars-cov-2
url http://www.sciencedirect.com/science/article/pii/S0168170225000553
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