Ethanol extraction desalination test using pre-treated mine wastewater concentrated by reverse osmosis

ABSTRACT: This article investigates the efficiency of using ethanol as the extracting solvent for the desalination of pre-treated mine wastewater. The wastewater, concentrated through reverse osmosis (RO), had a salinity of 47,115.60 ppm before solvent extraction. Results showed that 13.31% of the s...

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Main Authors: Edgar E. Vásquez Salazar, Gorki Román Hernández, José A. Vargas Saavedra, Harold J. Villegas Romero
Format: Article
Language:English
Published: Elsevier 2024-01-01
Series:Desalination and Water Treatment
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Online Access:http://www.sciencedirect.com/science/article/pii/S1944398624002364
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author Edgar E. Vásquez Salazar
Gorki Román Hernández
José A. Vargas Saavedra
Harold J. Villegas Romero
author_facet Edgar E. Vásquez Salazar
Gorki Román Hernández
José A. Vargas Saavedra
Harold J. Villegas Romero
author_sort Edgar E. Vásquez Salazar
collection DOAJ
description ABSTRACT: This article investigates the efficiency of using ethanol as the extracting solvent for the desalination of pre-treated mine wastewater. The wastewater, concentrated through reverse osmosis (RO), had a salinity of 47,115.60 ppm before solvent extraction. Results showed that 13.31% of the salt was extracted via ethanol extraction using a ratio of 85:15 (v/v) ethanol to RO concentrate at 55 °C. An average salinity reduction of 46.04% was achieved. Ethanol was effective in reducing scaling ions such as calcium and sulfate and, to a lesser extent, magnesium. The highest removal efficiencies were achieved for the arsenic and manganese elements, despite their low inlet concentrations (0.299 ppm and 0.181 ppm, respectively). The removal efficiencies of monovalent ions were moderate. However, the results revealed concerning levels of iron, lithium, and boron, showing a high concentration of the two last elements in the product water. This study shows the significance of ethanol extraction desalination as a viable alternative to thermal desalination processes, especially for generating water that meets specific end-use needs.
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publisher Elsevier
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series Desalination and Water Treatment
spelling doaj-art-46bef69be31247cdb1d7828b6fe09cd62025-08-20T02:17:28ZengElsevierDesalination and Water Treatment1944-39862024-01-0131710020810.1016/j.dwt.2024.100208Ethanol extraction desalination test using pre-treated mine wastewater concentrated by reverse osmosisEdgar E. Vásquez Salazar0Gorki Román Hernández1José A. Vargas Saavedra2Harold J. Villegas Romero3Chemical Engineering Department (FIQ), Universidad Nacional de Trujillo (UNT), Trujillo, Perú; Corresponding author.Pontificia Universidad Católica del Perú (PUCP), Lima, PerúUniversidad Nacional del Callao, Lima, PerúUniversidad Nacional de Piura, Piura, PerúABSTRACT: This article investigates the efficiency of using ethanol as the extracting solvent for the desalination of pre-treated mine wastewater. The wastewater, concentrated through reverse osmosis (RO), had a salinity of 47,115.60 ppm before solvent extraction. Results showed that 13.31% of the salt was extracted via ethanol extraction using a ratio of 85:15 (v/v) ethanol to RO concentrate at 55 °C. An average salinity reduction of 46.04% was achieved. Ethanol was effective in reducing scaling ions such as calcium and sulfate and, to a lesser extent, magnesium. The highest removal efficiencies were achieved for the arsenic and manganese elements, despite their low inlet concentrations (0.299 ppm and 0.181 ppm, respectively). The removal efficiencies of monovalent ions were moderate. However, the results revealed concerning levels of iron, lithium, and boron, showing a high concentration of the two last elements in the product water. This study shows the significance of ethanol extraction desalination as a viable alternative to thermal desalination processes, especially for generating water that meets specific end-use needs.http://www.sciencedirect.com/science/article/pii/S1944398624002364Extracting solventEthanol extractionThermal desalinationScaling ionsMonovalent ions
spellingShingle Edgar E. Vásquez Salazar
Gorki Román Hernández
José A. Vargas Saavedra
Harold J. Villegas Romero
Ethanol extraction desalination test using pre-treated mine wastewater concentrated by reverse osmosis
Desalination and Water Treatment
Extracting solvent
Ethanol extraction
Thermal desalination
Scaling ions
Monovalent ions
title Ethanol extraction desalination test using pre-treated mine wastewater concentrated by reverse osmosis
title_full Ethanol extraction desalination test using pre-treated mine wastewater concentrated by reverse osmosis
title_fullStr Ethanol extraction desalination test using pre-treated mine wastewater concentrated by reverse osmosis
title_full_unstemmed Ethanol extraction desalination test using pre-treated mine wastewater concentrated by reverse osmosis
title_short Ethanol extraction desalination test using pre-treated mine wastewater concentrated by reverse osmosis
title_sort ethanol extraction desalination test using pre treated mine wastewater concentrated by reverse osmosis
topic Extracting solvent
Ethanol extraction
Thermal desalination
Scaling ions
Monovalent ions
url http://www.sciencedirect.com/science/article/pii/S1944398624002364
work_keys_str_mv AT edgarevasquezsalazar ethanolextractiondesalinationtestusingpretreatedminewastewaterconcentratedbyreverseosmosis
AT gorkiromanhernandez ethanolextractiondesalinationtestusingpretreatedminewastewaterconcentratedbyreverseosmosis
AT joseavargassaavedra ethanolextractiondesalinationtestusingpretreatedminewastewaterconcentratedbyreverseosmosis
AT haroldjvillegasromero ethanolextractiondesalinationtestusingpretreatedminewastewaterconcentratedbyreverseosmosis