POLYETHYLENEIMINE (PEI) ON SILICA AS CATALYST IN KNOEVENAGEL AND MICHAEL REACTIONS

After the synthesis of polyethylenimine supported on silica, it has been used as a new and efficient catalyst in Knoevenagel and Michael condensations. The presence of the polyethylenimine in the catalytic system together with silica displays an acido-basic character allows a better catalytic activi...

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Main Authors: FATIHA ZAOUI, DIDIER VILLEMIN, NATHALIE BAR, MOHAMED A. DIDI
Format: Article
Language:English
Published: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2017-03-01
Series:Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
Subjects:
Online Access:http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201701&vol=1&aid=4484
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author FATIHA ZAOUI
DIDIER VILLEMIN
NATHALIE BAR
MOHAMED A. DIDI
author_facet FATIHA ZAOUI
DIDIER VILLEMIN
NATHALIE BAR
MOHAMED A. DIDI
author_sort FATIHA ZAOUI
collection DOAJ
description After the synthesis of polyethylenimine supported on silica, it has been used as a new and efficient catalyst in Knoevenagel and Michael condensations. The presence of the polyethylenimine in the catalytic system together with silica displays an acido-basic character allows a better catalytic activity in the condensations. Carried out under microwave irradiation, without organic solvent and during short time, the syntheses are respectful towards green chemistry. The solid catalyst can be easily reused. This catalyst has the acido-basic character at the same time.
format Article
id doaj-art-46b6073f8c654483af36bef059678743
institution OA Journals
issn 1582-540X
1582-540X
language English
publishDate 2017-03-01
publisher Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
record_format Article
series Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
spelling doaj-art-46b6073f8c654483af36bef0596787432025-08-20T02:00:42ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X1582-540X2017-03-0118118POLYETHYLENEIMINE (PEI) ON SILICA AS CATALYST IN KNOEVENAGEL AND MICHAEL REACTIONSFATIHA ZAOUI0 DIDIER VILLEMIN1NATHALIE BAR2MOHAMED A. DIDI31. University of Saïda, Faculty of Sciences, Department of Chemistry, PB 139, 20000, Saïda, Algeria 2. University of Tlemcen, Faculty of Sciences, Department of Chemistry, Laboratory of Separation and Purification Technology, PB 119, 13000, Tlemcen, AlgeriaUniversity of Caen, ENSICAEN, Laboratory of Molecular and Thio-organic Chemistry (LCMT), UMR CNRS 6507, INC3M, FR 3038, Labex EMC3, 14050 Caen, FranceUniversity of Caen, ENSICAEN, Laboratory of Molecular and Thio-organic Chemistry (LCMT), UMR CNRS 6507, INC3M, FR 3038, Labex EMC3, 14050 Caen, FranceUniversity of Tlemcen, Faculty of Sciences, Department of Chemistry, Laboratory of Separation and Purification Technology, PB 119, 13000, Tlemcen, AlgeriaAfter the synthesis of polyethylenimine supported on silica, it has been used as a new and efficient catalyst in Knoevenagel and Michael condensations. The presence of the polyethylenimine in the catalytic system together with silica displays an acido-basic character allows a better catalytic activity in the condensations. Carried out under microwave irradiation, without organic solvent and during short time, the syntheses are respectful towards green chemistry. The solid catalyst can be easily reused. This catalyst has the acido-basic character at the same time.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201701&vol=1&aid=4484catalystKnoevenagelMichaelpolyethyleniminesilica
spellingShingle FATIHA ZAOUI
DIDIER VILLEMIN
NATHALIE BAR
MOHAMED A. DIDI
POLYETHYLENEIMINE (PEI) ON SILICA AS CATALYST IN KNOEVENAGEL AND MICHAEL REACTIONS
Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
catalyst
Knoevenagel
Michael
polyethylenimine
silica
title POLYETHYLENEIMINE (PEI) ON SILICA AS CATALYST IN KNOEVENAGEL AND MICHAEL REACTIONS
title_full POLYETHYLENEIMINE (PEI) ON SILICA AS CATALYST IN KNOEVENAGEL AND MICHAEL REACTIONS
title_fullStr POLYETHYLENEIMINE (PEI) ON SILICA AS CATALYST IN KNOEVENAGEL AND MICHAEL REACTIONS
title_full_unstemmed POLYETHYLENEIMINE (PEI) ON SILICA AS CATALYST IN KNOEVENAGEL AND MICHAEL REACTIONS
title_short POLYETHYLENEIMINE (PEI) ON SILICA AS CATALYST IN KNOEVENAGEL AND MICHAEL REACTIONS
title_sort polyethyleneimine pei on silica as catalyst in knoevenagel and michael reactions
topic catalyst
Knoevenagel
Michael
polyethylenimine
silica
url http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201701&vol=1&aid=4484
work_keys_str_mv AT fatihazaoui polyethyleneiminepeionsilicaascatalystinknoevenagelandmichaelreactions
AT didiervillemin polyethyleneiminepeionsilicaascatalystinknoevenagelandmichaelreactions
AT nathaliebar polyethyleneiminepeionsilicaascatalystinknoevenagelandmichaelreactions
AT mohamedadidi polyethyleneiminepeionsilicaascatalystinknoevenagelandmichaelreactions