Reusable alginate-based hybrid granular activated carbon from sugarcane bagasse residues for secondary decolorization of clear liquor in sugar refining
To overcome limitations associated with powdered adsorbents in sugar refining and to support the valorization of sugar industry byproducts, alginate-based hybrid granular activated carbons (GACs) were developed by incorporating sugarcane bagasse-derived activated carbon (SCB-AC) and acid-leached sug...
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| Language: | English |
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Elsevier
2025-09-01
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| Series: | Results in Engineering |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2590123025017359 |
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| author | Pensiri Prachakittikul Pimonpan Inthapat Nakorn Worasuwannarak Sutthira Sutthasupa Suwanna Kitpati Boontanon Atthapon Srifa Wanida Koo-amornpattana Paeka Klaitong Weerawut Chaiwat |
| author_facet | Pensiri Prachakittikul Pimonpan Inthapat Nakorn Worasuwannarak Sutthira Sutthasupa Suwanna Kitpati Boontanon Atthapon Srifa Wanida Koo-amornpattana Paeka Klaitong Weerawut Chaiwat |
| author_sort | Pensiri Prachakittikul |
| collection | DOAJ |
| description | To overcome limitations associated with powdered adsorbents in sugar refining and to support the valorization of sugar industry byproducts, alginate-based hybrid granular activated carbons (GACs) were developed by incorporating sugarcane bagasse-derived activated carbon (SCB-AC) and acid-leached sugarcane bagasse ash (L-SCBA) into calcium alginate hydrogels. Among the five formulations evaluated, the hybrid GAC with a 1:2 weight ratio of L-SCBA to SCB-AC (L-SCBA1:SCB-AC2) achieved a decolorization efficiency of approximately 63% in batch experiments using synthetic clear liquor (500 IU, pH 7), reducing the effluent color to 187 IU within the typical industrial target of 200 ± 50 IU. Although this formulation exhibited a relatively low BET surface area (282 m2/g), it outperformed a commercial hybrid GAC (MPS1:CPAC2). This was probably due to the presence of surface functional groups and its pH-responsive adsorption behavior. Regeneration with 40% ethanol under mild conditions preserved over 80% decolorization efficiency across four consecutive cycles, without observable granule deformation. Fixed-bed column in continuous experiments further confirmed that lower flow rates extended breakthrough time, while performance declined in actual clear liquor presumably due to diffusion limitations from inorganic impurities and increased viscosity. These results demonstrate the potential of SCB-based hybrid GACs as a promising, reusable, and scalable alternative to conventional powdered activated carbon for secondary decolorization of clear liquor in sugar refining, applicable in both batch and column modes. |
| format | Article |
| id | doaj-art-469edb71a20445688fe24f04a8bf602e |
| institution | DOAJ |
| issn | 2590-1230 |
| language | English |
| publishDate | 2025-09-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Results in Engineering |
| spelling | doaj-art-469edb71a20445688fe24f04a8bf602e2025-08-20T03:21:55ZengElsevierResults in Engineering2590-12302025-09-012710566410.1016/j.rineng.2025.105664Reusable alginate-based hybrid granular activated carbon from sugarcane bagasse residues for secondary decolorization of clear liquor in sugar refiningPensiri Prachakittikul0Pimonpan Inthapat1Nakorn Worasuwannarak2Sutthira Sutthasupa3Suwanna Kitpati Boontanon4Atthapon Srifa5Wanida Koo-amornpattana6Paeka Klaitong7Weerawut Chaiwat8Division of Environmental Engineering and Disaster Management, Mahidol University, Kanchanaburi Campus, Kanchanaburi 71150, ThailandDepartment of Chemical Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, ThailandThe Joint Graduate School of Energy and Environment, King Mongkut’s University of Technology Thonburi, Bangkok 10140, ThailandDivision of Packaging Technology, Faculty of Agro Industry, Chiang Mai University, Chiang Mai 50100, ThailandDepartment of Civil and Environmental Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, ThailandDepartment of Chemical Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, ThailandDepartment of Chemical Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, ThailandDepartment of Chemical Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, ThailandDepartment of Chemical Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, Thailand; Corresponding author.To overcome limitations associated with powdered adsorbents in sugar refining and to support the valorization of sugar industry byproducts, alginate-based hybrid granular activated carbons (GACs) were developed by incorporating sugarcane bagasse-derived activated carbon (SCB-AC) and acid-leached sugarcane bagasse ash (L-SCBA) into calcium alginate hydrogels. Among the five formulations evaluated, the hybrid GAC with a 1:2 weight ratio of L-SCBA to SCB-AC (L-SCBA1:SCB-AC2) achieved a decolorization efficiency of approximately 63% in batch experiments using synthetic clear liquor (500 IU, pH 7), reducing the effluent color to 187 IU within the typical industrial target of 200 ± 50 IU. Although this formulation exhibited a relatively low BET surface area (282 m2/g), it outperformed a commercial hybrid GAC (MPS1:CPAC2). This was probably due to the presence of surface functional groups and its pH-responsive adsorption behavior. Regeneration with 40% ethanol under mild conditions preserved over 80% decolorization efficiency across four consecutive cycles, without observable granule deformation. Fixed-bed column in continuous experiments further confirmed that lower flow rates extended breakthrough time, while performance declined in actual clear liquor presumably due to diffusion limitations from inorganic impurities and increased viscosity. These results demonstrate the potential of SCB-based hybrid GACs as a promising, reusable, and scalable alternative to conventional powdered activated carbon for secondary decolorization of clear liquor in sugar refining, applicable in both batch and column modes.http://www.sciencedirect.com/science/article/pii/S2590123025017359AlginateHybrid granular activated carbonSugarcane bagasseDecolorizationClear liquor |
| spellingShingle | Pensiri Prachakittikul Pimonpan Inthapat Nakorn Worasuwannarak Sutthira Sutthasupa Suwanna Kitpati Boontanon Atthapon Srifa Wanida Koo-amornpattana Paeka Klaitong Weerawut Chaiwat Reusable alginate-based hybrid granular activated carbon from sugarcane bagasse residues for secondary decolorization of clear liquor in sugar refining Results in Engineering Alginate Hybrid granular activated carbon Sugarcane bagasse Decolorization Clear liquor |
| title | Reusable alginate-based hybrid granular activated carbon from sugarcane bagasse residues for secondary decolorization of clear liquor in sugar refining |
| title_full | Reusable alginate-based hybrid granular activated carbon from sugarcane bagasse residues for secondary decolorization of clear liquor in sugar refining |
| title_fullStr | Reusable alginate-based hybrid granular activated carbon from sugarcane bagasse residues for secondary decolorization of clear liquor in sugar refining |
| title_full_unstemmed | Reusable alginate-based hybrid granular activated carbon from sugarcane bagasse residues for secondary decolorization of clear liquor in sugar refining |
| title_short | Reusable alginate-based hybrid granular activated carbon from sugarcane bagasse residues for secondary decolorization of clear liquor in sugar refining |
| title_sort | reusable alginate based hybrid granular activated carbon from sugarcane bagasse residues for secondary decolorization of clear liquor in sugar refining |
| topic | Alginate Hybrid granular activated carbon Sugarcane bagasse Decolorization Clear liquor |
| url | http://www.sciencedirect.com/science/article/pii/S2590123025017359 |
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