Characterization of Triphenylamino-Based Polymethine Dyes

In this high-technology application, age functional dyes especially polymethine dyes have captured much attention of the researchers due to their immense potential for high-tech uses. Polymethine dyes show promising absorption spectra in the visible range, which can be easily exploited for the use o...

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Main Authors: Saleem Ullah, Irshad Ahmad, Yatimah Alias, Ismail Yusoff, Muhammad Aqeel Ashraf
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/136908
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author Saleem Ullah
Irshad Ahmad
Yatimah Alias
Ismail Yusoff
Muhammad Aqeel Ashraf
author_facet Saleem Ullah
Irshad Ahmad
Yatimah Alias
Ismail Yusoff
Muhammad Aqeel Ashraf
author_sort Saleem Ullah
collection DOAJ
description In this high-technology application, age functional dyes especially polymethine dyes have captured much attention of the researchers due to their immense potential for high-tech uses. Polymethine dyes show promising absorption spectra in the visible range, which can be easily exploited for the use of written text copying, photographic imaging, or photothermographic recording materials. Keeping this in mind, our research is composed of an investigation of two triphenylamino-based polymethine dyes, a known polymethine dye 3 and a new one polymethine dye 5, which have been synthesized by the reaction of 4-(diphenylamino) benzaldehyde 2 and 4,4′-(phenylazanediyl) dibenzaldehyde 4 with 4,4′-vinylidene-bis(N, N-dimethylaniline) 1. Based on bis-dimethylaminophenylethylene moiety, the new polymethine dye showed more high absorption spectra in the range of 600–700 nm than that of the known polymethine dye based on bis-dimethylaminophenylethylene moiety. Their maximum spectra were exhibited at 637 nm and 653 nm, respectively. Their leuco-converted reversible colored forms were also investigated.
format Article
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institution Kabale University
issn 2090-9063
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language English
publishDate 2013-01-01
publisher Wiley
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series Journal of Chemistry
spelling doaj-art-462742f69c194906a49e0fdb60d415892025-02-03T07:26:10ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/136908136908Characterization of Triphenylamino-Based Polymethine DyesSaleem Ullah0Irshad Ahmad1Yatimah Alias2Ismail Yusoff3Muhammad Aqeel Ashraf4Department of Chemistry, University of Jyväskylä, FI-40014 Jyväskylä, FinlandChemical Resource Laboratory, Bio-Resources Division, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama, 226-8503, JapanDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, MalaysiaDepartment of Geology, University of Malaya, 50603 Kuala Lumpur, MalaysiaDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, MalaysiaIn this high-technology application, age functional dyes especially polymethine dyes have captured much attention of the researchers due to their immense potential for high-tech uses. Polymethine dyes show promising absorption spectra in the visible range, which can be easily exploited for the use of written text copying, photographic imaging, or photothermographic recording materials. Keeping this in mind, our research is composed of an investigation of two triphenylamino-based polymethine dyes, a known polymethine dye 3 and a new one polymethine dye 5, which have been synthesized by the reaction of 4-(diphenylamino) benzaldehyde 2 and 4,4′-(phenylazanediyl) dibenzaldehyde 4 with 4,4′-vinylidene-bis(N, N-dimethylaniline) 1. Based on bis-dimethylaminophenylethylene moiety, the new polymethine dye showed more high absorption spectra in the range of 600–700 nm than that of the known polymethine dye based on bis-dimethylaminophenylethylene moiety. Their maximum spectra were exhibited at 637 nm and 653 nm, respectively. Their leuco-converted reversible colored forms were also investigated.http://dx.doi.org/10.1155/2013/136908
spellingShingle Saleem Ullah
Irshad Ahmad
Yatimah Alias
Ismail Yusoff
Muhammad Aqeel Ashraf
Characterization of Triphenylamino-Based Polymethine Dyes
Journal of Chemistry
title Characterization of Triphenylamino-Based Polymethine Dyes
title_full Characterization of Triphenylamino-Based Polymethine Dyes
title_fullStr Characterization of Triphenylamino-Based Polymethine Dyes
title_full_unstemmed Characterization of Triphenylamino-Based Polymethine Dyes
title_short Characterization of Triphenylamino-Based Polymethine Dyes
title_sort characterization of triphenylamino based polymethine dyes
url http://dx.doi.org/10.1155/2013/136908
work_keys_str_mv AT saleemullah characterizationoftriphenylaminobasedpolymethinedyes
AT irshadahmad characterizationoftriphenylaminobasedpolymethinedyes
AT yatimahalias characterizationoftriphenylaminobasedpolymethinedyes
AT ismailyusoff characterizationoftriphenylaminobasedpolymethinedyes
AT muhammadaqeelashraf characterizationoftriphenylaminobasedpolymethinedyes