Synthesis, crystal structure and Hirshfeld surface analysis of 1,1′-[oxybis(ethane-2,1-diyl)]bis(2-methylsulfanyl-1H-benzo[d]imidazole)
The asymmetric unit of the title compound, C20H22N4OS2, consists of two independent molecules, one of which is disordered. In each molecule, the mean planes of the terminal benzimidazole moieties are inclined to one another by about 68°. In the crystal, tetramolecular strands are generated by C—H......
Saved in:
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2025-06-01
|
| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | https://journals.iucr.org/paper?S2056989025003809 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849434258129551360 |
|---|---|
| author | Ahmed Moussaif Lhoussaine El Ghayati Camille Kalonji Mubengayi Abdulsalam Alsubari El Mokhtar Essassi Joel T. Mague Youssef Ramli |
| author_facet | Ahmed Moussaif Lhoussaine El Ghayati Camille Kalonji Mubengayi Abdulsalam Alsubari El Mokhtar Essassi Joel T. Mague Youssef Ramli |
| author_sort | Ahmed Moussaif |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, C20H22N4OS2, consists of two independent molecules, one of which is disordered. In each molecule, the mean planes of the terminal benzimidazole moieties are inclined to one another by about 68°. In the crystal, tetramolecular strands are generated by C—H...N hydrogen bonds and C—H...π(ring) interactions and are linked by C—H...π(ring) and π-stacking interactions. |
| format | Article |
| id | doaj-art-45faeb2bd6c8476281d8d60653a7a057 |
| institution | Kabale University |
| issn | 2056-9890 |
| language | English |
| publishDate | 2025-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj-art-45faeb2bd6c8476281d8d60653a7a0572025-08-20T03:26:43ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902025-06-0181646446810.1107/S2056989025003809vm2313Synthesis, crystal structure and Hirshfeld surface analysis of 1,1′-[oxybis(ethane-2,1-diyl)]bis(2-methylsulfanyl-1H-benzo[d]imidazole)Ahmed Moussaif0Lhoussaine El Ghayati1Camille Kalonji Mubengayi2Abdulsalam Alsubari3El Mokhtar Essassi4Joel T. Mague5Youssef Ramli6National Center for Nuclear Energy, Science and Technology, Rabat, MoroccoLaboratory of Heterocyclic Organic Chemistry, Medicines Science Research Center, Pharmacochemistry Competence Center, Mohammed V University in Rabat, Faculte des Sciences, Av. Ibn Battouta, BP 1014, Rabat, MoroccoLaboratoire de Chimie et Biochimie, Institut Superieur des Techniques Medicales, Kinshasa, Republique Democratique, CongoLaboratory of Medicinal Chemistry, Faculty of Clinical Pharmacy, 21 September University, YemenLaboratory of Heterocyclic Organic Chemistry, Medicines Science Research Center, Pharmacochemistry Competence Center, Mohammed V University in Rabat, Faculte des Sciences, Av. Ibn Battouta, BP 1014, Rabat, MoroccoDepartment of Chemistry, Tulane University, New Orleans, LA 70118, USALaboratory of Medicinal Chemistry, Drug Sciences Research Center, Faculty of Medicine and Pharmacy, Mohammed V University in Rabat, MoroccoThe asymmetric unit of the title compound, C20H22N4OS2, consists of two independent molecules, one of which is disordered. In each molecule, the mean planes of the terminal benzimidazole moieties are inclined to one another by about 68°. In the crystal, tetramolecular strands are generated by C—H...N hydrogen bonds and C—H...π(ring) interactions and are linked by C—H...π(ring) and π-stacking interactions.https://journals.iucr.org/paper?S2056989025003809crystal structurebenzimidazolethioetherhydrogen bondπ-stackingc—h...π(ring) interactions |
| spellingShingle | Ahmed Moussaif Lhoussaine El Ghayati Camille Kalonji Mubengayi Abdulsalam Alsubari El Mokhtar Essassi Joel T. Mague Youssef Ramli Synthesis, crystal structure and Hirshfeld surface analysis of 1,1′-[oxybis(ethane-2,1-diyl)]bis(2-methylsulfanyl-1H-benzo[d]imidazole) Acta Crystallographica Section E: Crystallographic Communications crystal structure benzimidazole thioether hydrogen bond π-stacking c—h...π(ring) interactions |
| title | Synthesis, crystal structure and Hirshfeld surface analysis of 1,1′-[oxybis(ethane-2,1-diyl)]bis(2-methylsulfanyl-1H-benzo[d]imidazole) |
| title_full | Synthesis, crystal structure and Hirshfeld surface analysis of 1,1′-[oxybis(ethane-2,1-diyl)]bis(2-methylsulfanyl-1H-benzo[d]imidazole) |
| title_fullStr | Synthesis, crystal structure and Hirshfeld surface analysis of 1,1′-[oxybis(ethane-2,1-diyl)]bis(2-methylsulfanyl-1H-benzo[d]imidazole) |
| title_full_unstemmed | Synthesis, crystal structure and Hirshfeld surface analysis of 1,1′-[oxybis(ethane-2,1-diyl)]bis(2-methylsulfanyl-1H-benzo[d]imidazole) |
| title_short | Synthesis, crystal structure and Hirshfeld surface analysis of 1,1′-[oxybis(ethane-2,1-diyl)]bis(2-methylsulfanyl-1H-benzo[d]imidazole) |
| title_sort | synthesis crystal structure and hirshfeld surface analysis of 1 1 oxybis ethane 2 1 diyl bis 2 methylsulfanyl 1h benzo d imidazole |
| topic | crystal structure benzimidazole thioether hydrogen bond π-stacking c—h...π(ring) interactions |
| url | https://journals.iucr.org/paper?S2056989025003809 |
| work_keys_str_mv | AT ahmedmoussaif synthesiscrystalstructureandhirshfeldsurfaceanalysisof11oxybisethane21diylbis2methylsulfanyl1hbenzodimidazole AT lhoussaineelghayati synthesiscrystalstructureandhirshfeldsurfaceanalysisof11oxybisethane21diylbis2methylsulfanyl1hbenzodimidazole AT camillekalonjimubengayi synthesiscrystalstructureandhirshfeldsurfaceanalysisof11oxybisethane21diylbis2methylsulfanyl1hbenzodimidazole AT abdulsalamalsubari synthesiscrystalstructureandhirshfeldsurfaceanalysisof11oxybisethane21diylbis2methylsulfanyl1hbenzodimidazole AT elmokhtaressassi synthesiscrystalstructureandhirshfeldsurfaceanalysisof11oxybisethane21diylbis2methylsulfanyl1hbenzodimidazole AT joeltmague synthesiscrystalstructureandhirshfeldsurfaceanalysisof11oxybisethane21diylbis2methylsulfanyl1hbenzodimidazole AT yousseframli synthesiscrystalstructureandhirshfeldsurfaceanalysisof11oxybisethane21diylbis2methylsulfanyl1hbenzodimidazole |