Unsymmetrical Schiff Base Functionalized as Monobasic Tridentate Ligand on Complexation with Some Transition Metal Ions
Cu(II), Co(II), Ni(II) and Mn(II) complexes of Schiff base derived from 2-aminophenol and pyrrole-2- carbaldehyde have been prepared. The complexes are formed by coordination of N and O atoms of the ligand. Their structures were characterized by physico-chemical and spectroscopic methods. Molecular...
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| Format: | Article |
| Language: | English |
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Wiley
2012-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2012/503936 |
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| author | Bibhesh K. Singh Narendar Bhojak Anant Prakash |
| author_facet | Bibhesh K. Singh Narendar Bhojak Anant Prakash |
| author_sort | Bibhesh K. Singh |
| collection | DOAJ |
| description | Cu(II), Co(II), Ni(II) and Mn(II) complexes of Schiff base derived from 2-aminophenol and pyrrole-2- carbaldehyde have been prepared. The complexes are formed by coordination of N and O atoms of the ligand. Their structures were characterized by physico-chemical and spectroscopic methods. Molecular structure of the complexes has been optimized by MM2 calculations and suggests a tetrahedral/ square planar geometry. The bio-efficacy of the ligand and their complexes has been examined against the growth of bacteria in vitro to evaluate their anti-microbial potential. |
| format | Article |
| id | doaj-art-45ba2e84fa9b46e186c42aeddd0d50d2 |
| institution | OA Journals |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-45ba2e84fa9b46e186c42aeddd0d50d22025-08-20T02:37:51ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-019253254410.1155/2012/503936Unsymmetrical Schiff Base Functionalized as Monobasic Tridentate Ligand on Complexation with Some Transition Metal IonsBibhesh K. Singh0Narendar Bhojak1Anant Prakash2Inorganic & Bioinorganic Research Lab, Department of Chemistry, Govt. Post Graduate College, Ranikhet-263645 (Uttarakhand), IndiaDepartment of Chemistry, Govt Dunger College, MGS University, Bikaner (Rajasthan), IndiaInorganic & Bioinorganic Research Lab, Department of Chemistry, Govt. Post Graduate College, Ranikhet-263645 (Uttarakhand), IndiaCu(II), Co(II), Ni(II) and Mn(II) complexes of Schiff base derived from 2-aminophenol and pyrrole-2- carbaldehyde have been prepared. The complexes are formed by coordination of N and O atoms of the ligand. Their structures were characterized by physico-chemical and spectroscopic methods. Molecular structure of the complexes has been optimized by MM2 calculations and suggests a tetrahedral/ square planar geometry. The bio-efficacy of the ligand and their complexes has been examined against the growth of bacteria in vitro to evaluate their anti-microbial potential.http://dx.doi.org/10.1155/2012/503936 |
| spellingShingle | Bibhesh K. Singh Narendar Bhojak Anant Prakash Unsymmetrical Schiff Base Functionalized as Monobasic Tridentate Ligand on Complexation with Some Transition Metal Ions E-Journal of Chemistry |
| title | Unsymmetrical Schiff Base Functionalized as Monobasic Tridentate Ligand on Complexation with Some Transition Metal Ions |
| title_full | Unsymmetrical Schiff Base Functionalized as Monobasic Tridentate Ligand on Complexation with Some Transition Metal Ions |
| title_fullStr | Unsymmetrical Schiff Base Functionalized as Monobasic Tridentate Ligand on Complexation with Some Transition Metal Ions |
| title_full_unstemmed | Unsymmetrical Schiff Base Functionalized as Monobasic Tridentate Ligand on Complexation with Some Transition Metal Ions |
| title_short | Unsymmetrical Schiff Base Functionalized as Monobasic Tridentate Ligand on Complexation with Some Transition Metal Ions |
| title_sort | unsymmetrical schiff base functionalized as monobasic tridentate ligand on complexation with some transition metal ions |
| url | http://dx.doi.org/10.1155/2012/503936 |
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