A Piezoelectric Sensor Based on MWCNT-Enhanced Polyvinyl Chloride Gel for Contact Perception of Grippers

In contrast to traditional hydrogels, which are susceptible to water evaporation and structural degradation, non-hydrogel materials are engineered for superior stability and consistent performance. Here, we report an innovative piezoelectric polyvinyl chloride/multi-walled carbon nanotube polymer ge...

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Main Authors: Qiyun Zhong, Qingsong He, Diyi Liu, Xinyu Lu, Siyuan Liu, Yuze Ye, Yefu Wang
Format: Article
Language:English
Published: MDPI AG 2025-06-01
Series:Biomimetics
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Online Access:https://www.mdpi.com/2313-7673/10/6/363
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author Qiyun Zhong
Qingsong He
Diyi Liu
Xinyu Lu
Siyuan Liu
Yuze Ye
Yefu Wang
author_facet Qiyun Zhong
Qingsong He
Diyi Liu
Xinyu Lu
Siyuan Liu
Yuze Ye
Yefu Wang
author_sort Qiyun Zhong
collection DOAJ
description In contrast to traditional hydrogels, which are susceptible to water evaporation and structural degradation, non-hydrogel materials are engineered for superior stability and consistent performance. Here, we report an innovative piezoelectric polyvinyl chloride/multi-walled carbon nanotube polymer gel (PVC/MWCNT polymer gel, PMPG) with exceptional linearity (as low as 1.31%), high sensitivity (50–310.17 mV), rapid response (172–189 ms), and thermal stability. Under strain induction, ordered rearrangement of dipoles in PMPG and the enhancement of MWCNTs generate a potential difference. Increasing MWCNT content enhances output voltage, sensitivity, conductivity, maximum stress, Young’s modulus, and toughness, while reducing nonlinear error. Higher dibutyl adipate (DBA) content increases output voltage and slightly improves sensitivity but decreases mechanical strength. The optimal PMPG (PVC:DBA = 1:5, 1 wt% MWCNTs) exhibited outstanding performance. It exhibits a nonlinear error as low as 1.31%, a conductivity of 25.4 μS/cm, an 80% compressive strain tolerance (273 kPa stress), and dimensional stability for 90 days in air. By integrating PMPG with machine learning algorithms, soft robotic grippers gain advanced contact perception capabilities, enabling applications in medicine, rescue, exploration, and other fields requiring fine manipulation and adaptability. This work highlights PMPG’s potential as a stable, high-performance material for soft robotics and beyond.
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institution Kabale University
issn 2313-7673
language English
publishDate 2025-06-01
publisher MDPI AG
record_format Article
series Biomimetics
spelling doaj-art-45ab3390f3e94dcdbce5302cf2e2c9612025-08-20T03:26:10ZengMDPI AGBiomimetics2313-76732025-06-0110636310.3390/biomimetics10060363A Piezoelectric Sensor Based on MWCNT-Enhanced Polyvinyl Chloride Gel for Contact Perception of GrippersQiyun Zhong0Qingsong He1Diyi Liu2Xinyu Lu3Siyuan Liu4Yuze Ye5Yefu Wang6Jiangsu Provincial Key Laboratory of Bionic Materials and Equipment, College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, ChinaJiangsu Provincial Key Laboratory of Bionic Materials and Equipment, College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, ChinaJiangsu Provincial Key Laboratory of Bionic Materials and Equipment, College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, ChinaJiangsu Provincial Key Laboratory of Bionic Materials and Equipment, College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, ChinaJiangsu Provincial Key Laboratory of Bionic Materials and Equipment, College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, ChinaJiangsu Provincial Key Laboratory of Bionic Materials and Equipment, College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, ChinaThe First Affiliated Hospital of Nanjing Medical University, Nanjing 210029, ChinaIn contrast to traditional hydrogels, which are susceptible to water evaporation and structural degradation, non-hydrogel materials are engineered for superior stability and consistent performance. Here, we report an innovative piezoelectric polyvinyl chloride/multi-walled carbon nanotube polymer gel (PVC/MWCNT polymer gel, PMPG) with exceptional linearity (as low as 1.31%), high sensitivity (50–310.17 mV), rapid response (172–189 ms), and thermal stability. Under strain induction, ordered rearrangement of dipoles in PMPG and the enhancement of MWCNTs generate a potential difference. Increasing MWCNT content enhances output voltage, sensitivity, conductivity, maximum stress, Young’s modulus, and toughness, while reducing nonlinear error. Higher dibutyl adipate (DBA) content increases output voltage and slightly improves sensitivity but decreases mechanical strength. The optimal PMPG (PVC:DBA = 1:5, 1 wt% MWCNTs) exhibited outstanding performance. It exhibits a nonlinear error as low as 1.31%, a conductivity of 25.4 μS/cm, an 80% compressive strain tolerance (273 kPa stress), and dimensional stability for 90 days in air. By integrating PMPG with machine learning algorithms, soft robotic grippers gain advanced contact perception capabilities, enabling applications in medicine, rescue, exploration, and other fields requiring fine manipulation and adaptability. This work highlights PMPG’s potential as a stable, high-performance material for soft robotics and beyond.https://www.mdpi.com/2313-7673/10/6/363piezoelectric sensorpolyvinyl chloride gelMWCNT-enhancedKNNcontact perception
spellingShingle Qiyun Zhong
Qingsong He
Diyi Liu
Xinyu Lu
Siyuan Liu
Yuze Ye
Yefu Wang
A Piezoelectric Sensor Based on MWCNT-Enhanced Polyvinyl Chloride Gel for Contact Perception of Grippers
Biomimetics
piezoelectric sensor
polyvinyl chloride gel
MWCNT-enhanced
KNN
contact perception
title A Piezoelectric Sensor Based on MWCNT-Enhanced Polyvinyl Chloride Gel for Contact Perception of Grippers
title_full A Piezoelectric Sensor Based on MWCNT-Enhanced Polyvinyl Chloride Gel for Contact Perception of Grippers
title_fullStr A Piezoelectric Sensor Based on MWCNT-Enhanced Polyvinyl Chloride Gel for Contact Perception of Grippers
title_full_unstemmed A Piezoelectric Sensor Based on MWCNT-Enhanced Polyvinyl Chloride Gel for Contact Perception of Grippers
title_short A Piezoelectric Sensor Based on MWCNT-Enhanced Polyvinyl Chloride Gel for Contact Perception of Grippers
title_sort piezoelectric sensor based on mwcnt enhanced polyvinyl chloride gel for contact perception of grippers
topic piezoelectric sensor
polyvinyl chloride gel
MWCNT-enhanced
KNN
contact perception
url https://www.mdpi.com/2313-7673/10/6/363
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