Curcumin Microcapsule Formulations for Prolong Persistence in the Photodynamic Inactivation of <i>Aedes aegypti</i> Larvae

<b>Background:</b> Viral diseases including dengue, zika, chikungunya, and yellow fever remain a significant public health challenge, primarily due to the increasing resistance of these vectors, the <i>Aedes aegypti</i> mosquito, to conventional control methods. <b>Obje...

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Main Authors: Matheus Garbuio, Larissa Marila de Souza, Lucas Danilo Dias, Jean Carlos Ferreira Machado, Natalia Mayumi Inada, Hernane da Silva Barud, Edgar Aparecido Sanches, Francisco Eduardo Gontijo Guimarães, Ana Paula da Silva, Alessandra Ramos Lima, Vanderlei Salvador Bagnato
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Language:English
Published: MDPI AG 2025-04-01
Series:Pharmaceutics
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Online Access:https://www.mdpi.com/1999-4923/17/4/496
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author Matheus Garbuio
Larissa Marila de Souza
Lucas Danilo Dias
Jean Carlos Ferreira Machado
Natalia Mayumi Inada
Hernane da Silva Barud
Edgar Aparecido Sanches
Francisco Eduardo Gontijo Guimarães
Ana Paula da Silva
Alessandra Ramos Lima
Vanderlei Salvador Bagnato
author_facet Matheus Garbuio
Larissa Marila de Souza
Lucas Danilo Dias
Jean Carlos Ferreira Machado
Natalia Mayumi Inada
Hernane da Silva Barud
Edgar Aparecido Sanches
Francisco Eduardo Gontijo Guimarães
Ana Paula da Silva
Alessandra Ramos Lima
Vanderlei Salvador Bagnato
author_sort Matheus Garbuio
collection DOAJ
description <b>Background:</b> Viral diseases including dengue, zika, chikungunya, and yellow fever remain a significant public health challenge, primarily due to the increasing resistance of these vectors, the <i>Aedes aegypti</i> mosquito, to conventional control methods. <b>Objectives:</b> Herein, a microencapsulated curcumin formulation was developed and characterized using spray-drying technology, with D-mannitol and starch as encapsulating agents. After microencapsulation, photolarvicidal tablet formulations (Formulated Curcumin Tablets—FCT) were prepared, varying the proportions of starch and pectin: FCT1 (60% starch), FCT2 (35% pectin and 25% starch), and FCT3 (42.5% pectin and 17.5% starch), while maintaining 10% curcumin and 30% D-mannitol in all formulations. The main goal was to enhance the stability and efficacy of curcumin as a photolarvicidal agent. <b>Methods:</b> The formulation was characterized by UV-Vis spectroscopy, confocal microscopy, thermal analysis (TG and DSC), scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FTIR), and photodegradation assays under fluorescent light. <b>Results:</b> The photodynamic inactivation (PDI) of <i>Ae. aegypti</i> larvae was evaluated under white, fluorescent light exposure, and the formulation exhibited a significantly enhanced larvicidal activity compared to free curcumin, with a 57-fold reduction in LC<sub>50</sub> (LC<sub>50-24h</sub> = 0.27 mg/L). Additionally, the most effective formulation, FCT2, maintained its residual activity for 27 days, reinforcing that curcumin microencapsulation, combined with PDI, can extend vector control. Release studies under different pH conditions confirmed a controlled release mechanism, favoring environmental stability. <b>Conclusions:</b> The results indicate that microencapsulated curcumin has great potential as a sustainable photoinsecticidal agent, offering stability, efficacy, and a promising alternative for managing <i>Ae. aegypti</i> larval populations.
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spelling doaj-art-4501e75bd4a54b99ae3a0c74e66f2d372025-08-20T02:28:20ZengMDPI AGPharmaceutics1999-49232025-04-0117449610.3390/pharmaceutics17040496Curcumin Microcapsule Formulations for Prolong Persistence in the Photodynamic Inactivation of <i>Aedes aegypti</i> LarvaeMatheus Garbuio0Larissa Marila de Souza1Lucas Danilo Dias2Jean Carlos Ferreira Machado3Natalia Mayumi Inada4Hernane da Silva Barud5Edgar Aparecido Sanches6Francisco Eduardo Gontijo Guimarães7Ana Paula da Silva8Alessandra Ramos Lima9Vanderlei Salvador Bagnato10São Carlos Institute of Physics (IFSC), University of São Paulo (USP), São Carlos 13566-590, SP, BrazilSão Carlos Institute of Physics (IFSC), University of São Paulo (USP), São Carlos 13566-590, SP, BrazilLaboratório de Novos Materiais, Universidade Evangélica de Goiás (UniEvangélica), Anápolis 75083-515, GO, BrazilBiopolymers and Biomaterials Laboratory (BioPolMat), University of Araraquara—UNIARA, Araraquara 14801-320, SP, BrazilSão Carlos Institute of Physics (IFSC), University of São Paulo (USP), São Carlos 13566-590, SP, BrazilBiopolymers and Biomaterials Laboratory (BioPolMat), University of Araraquara—UNIARA, Araraquara 14801-320, SP, BrazilLaboratory of Nanostructured Polymers (NANOPOL), Federal University of Amazonas (UFAM), Manaus 69080-005, AM, BrazilSão Carlos Institute of Physics (IFSC), University of São Paulo (USP), São Carlos 13566-590, SP, BrazilSão Carlos Institute of Physics (IFSC), University of São Paulo (USP), São Carlos 13566-590, SP, BrazilSão Carlos Institute of Physics (IFSC), University of São Paulo (USP), São Carlos 13566-590, SP, BrazilSão Carlos Institute of Physics (IFSC), University of São Paulo (USP), São Carlos 13566-590, SP, Brazil<b>Background:</b> Viral diseases including dengue, zika, chikungunya, and yellow fever remain a significant public health challenge, primarily due to the increasing resistance of these vectors, the <i>Aedes aegypti</i> mosquito, to conventional control methods. <b>Objectives:</b> Herein, a microencapsulated curcumin formulation was developed and characterized using spray-drying technology, with D-mannitol and starch as encapsulating agents. After microencapsulation, photolarvicidal tablet formulations (Formulated Curcumin Tablets—FCT) were prepared, varying the proportions of starch and pectin: FCT1 (60% starch), FCT2 (35% pectin and 25% starch), and FCT3 (42.5% pectin and 17.5% starch), while maintaining 10% curcumin and 30% D-mannitol in all formulations. The main goal was to enhance the stability and efficacy of curcumin as a photolarvicidal agent. <b>Methods:</b> The formulation was characterized by UV-Vis spectroscopy, confocal microscopy, thermal analysis (TG and DSC), scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FTIR), and photodegradation assays under fluorescent light. <b>Results:</b> The photodynamic inactivation (PDI) of <i>Ae. aegypti</i> larvae was evaluated under white, fluorescent light exposure, and the formulation exhibited a significantly enhanced larvicidal activity compared to free curcumin, with a 57-fold reduction in LC<sub>50</sub> (LC<sub>50-24h</sub> = 0.27 mg/L). Additionally, the most effective formulation, FCT2, maintained its residual activity for 27 days, reinforcing that curcumin microencapsulation, combined with PDI, can extend vector control. Release studies under different pH conditions confirmed a controlled release mechanism, favoring environmental stability. <b>Conclusions:</b> The results indicate that microencapsulated curcumin has great potential as a sustainable photoinsecticidal agent, offering stability, efficacy, and a promising alternative for managing <i>Ae. aegypti</i> larval populations.https://www.mdpi.com/1999-4923/17/4/496photodynamic inactivationcurcumin microencapsulationvector controlphotoinsecticidespray drying
spellingShingle Matheus Garbuio
Larissa Marila de Souza
Lucas Danilo Dias
Jean Carlos Ferreira Machado
Natalia Mayumi Inada
Hernane da Silva Barud
Edgar Aparecido Sanches
Francisco Eduardo Gontijo Guimarães
Ana Paula da Silva
Alessandra Ramos Lima
Vanderlei Salvador Bagnato
Curcumin Microcapsule Formulations for Prolong Persistence in the Photodynamic Inactivation of <i>Aedes aegypti</i> Larvae
Pharmaceutics
photodynamic inactivation
curcumin microencapsulation
vector control
photoinsecticide
spray drying
title Curcumin Microcapsule Formulations for Prolong Persistence in the Photodynamic Inactivation of <i>Aedes aegypti</i> Larvae
title_full Curcumin Microcapsule Formulations for Prolong Persistence in the Photodynamic Inactivation of <i>Aedes aegypti</i> Larvae
title_fullStr Curcumin Microcapsule Formulations for Prolong Persistence in the Photodynamic Inactivation of <i>Aedes aegypti</i> Larvae
title_full_unstemmed Curcumin Microcapsule Formulations for Prolong Persistence in the Photodynamic Inactivation of <i>Aedes aegypti</i> Larvae
title_short Curcumin Microcapsule Formulations for Prolong Persistence in the Photodynamic Inactivation of <i>Aedes aegypti</i> Larvae
title_sort curcumin microcapsule formulations for prolong persistence in the photodynamic inactivation of i aedes aegypti i larvae
topic photodynamic inactivation
curcumin microencapsulation
vector control
photoinsecticide
spray drying
url https://www.mdpi.com/1999-4923/17/4/496
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