Antimicrobial Polyethylene through Melt Compounding with Quaternary Ammonium Salts

Selected mono- and bicationic quats were compounded with polyethylene. The physicochemical surface properties, leaching behavior, and antibacterial activity of such modified samples were investigated. Contact angle measurements and fluorescein binding assays showed the presence of quaternary ammoniu...

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Main Authors: Fernanda F. Rossetti, Konstantin Siegmann, Joachim Köser, Irene Wegner, Ismail Keskin, Götz Schlotterbeck, Martin Winkler
Format: Article
Language:English
Published: Wiley 2017-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2017/2823604
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author Fernanda F. Rossetti
Konstantin Siegmann
Joachim Köser
Irene Wegner
Ismail Keskin
Götz Schlotterbeck
Martin Winkler
author_facet Fernanda F. Rossetti
Konstantin Siegmann
Joachim Köser
Irene Wegner
Ismail Keskin
Götz Schlotterbeck
Martin Winkler
author_sort Fernanda F. Rossetti
collection DOAJ
description Selected mono- and bicationic quats were compounded with polyethylene. The physicochemical surface properties, leaching behavior, and antibacterial activity of such modified samples were investigated. Contact angle measurements and fluorescein binding assays showed the presence of quaternary ammonium groups at the surface. After storing the samples in 50°C warm water for 30 days, several were still antimicrobially active. No correlation between the number of exposed N+ head groups after leaching and the antibacterial activity was observed. There is however a qualitative correlation of the antibacterial activity with the contact angles and surface concentrations of N+ before leaching/storing in warm water.
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institution Kabale University
issn 1687-9422
1687-9430
language English
publishDate 2017-01-01
publisher Wiley
record_format Article
series International Journal of Polymer Science
spelling doaj-art-44c51ce1fdf14e3c8755eca1022899cf2025-02-03T01:02:18ZengWileyInternational Journal of Polymer Science1687-94221687-94302017-01-01201710.1155/2017/28236042823604Antimicrobial Polyethylene through Melt Compounding with Quaternary Ammonium SaltsFernanda F. Rossetti0Konstantin Siegmann1Joachim Köser2Irene Wegner3Ismail Keskin4Götz Schlotterbeck5Martin Winkler6Institute of Materials and Process Engineering, School of Engineering, Zurich University of Applied Sciences (ZHAW), 8400 Winterthur, SwitzerlandInstitute of Materials and Process Engineering, School of Engineering, Zurich University of Applied Sciences (ZHAW), 8400 Winterthur, SwitzerlandInstitut für Chemie und Bioanalytik, Hochschule für Life Sciences, Fachhochschule Nordwestschweiz, 4132 Muttenz, SwitzerlandInstitut für Chemie und Bioanalytik, Hochschule für Life Sciences, Fachhochschule Nordwestschweiz, 4132 Muttenz, SwitzerlandInstitut für Chemie und Bioanalytik, Hochschule für Life Sciences, Fachhochschule Nordwestschweiz, 4132 Muttenz, SwitzerlandInstitut für Chemie und Bioanalytik, Hochschule für Life Sciences, Fachhochschule Nordwestschweiz, 4132 Muttenz, SwitzerlandInstitute of Materials and Process Engineering, School of Engineering, Zurich University of Applied Sciences (ZHAW), 8400 Winterthur, SwitzerlandSelected mono- and bicationic quats were compounded with polyethylene. The physicochemical surface properties, leaching behavior, and antibacterial activity of such modified samples were investigated. Contact angle measurements and fluorescein binding assays showed the presence of quaternary ammonium groups at the surface. After storing the samples in 50°C warm water for 30 days, several were still antimicrobially active. No correlation between the number of exposed N+ head groups after leaching and the antibacterial activity was observed. There is however a qualitative correlation of the antibacterial activity with the contact angles and surface concentrations of N+ before leaching/storing in warm water.http://dx.doi.org/10.1155/2017/2823604
spellingShingle Fernanda F. Rossetti
Konstantin Siegmann
Joachim Köser
Irene Wegner
Ismail Keskin
Götz Schlotterbeck
Martin Winkler
Antimicrobial Polyethylene through Melt Compounding with Quaternary Ammonium Salts
International Journal of Polymer Science
title Antimicrobial Polyethylene through Melt Compounding with Quaternary Ammonium Salts
title_full Antimicrobial Polyethylene through Melt Compounding with Quaternary Ammonium Salts
title_fullStr Antimicrobial Polyethylene through Melt Compounding with Quaternary Ammonium Salts
title_full_unstemmed Antimicrobial Polyethylene through Melt Compounding with Quaternary Ammonium Salts
title_short Antimicrobial Polyethylene through Melt Compounding with Quaternary Ammonium Salts
title_sort antimicrobial polyethylene through melt compounding with quaternary ammonium salts
url http://dx.doi.org/10.1155/2017/2823604
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