Crystal structure and Hirshfeld surface analysis of 4-methyl-N-[2-(5-methylfuran-2-yl)phenyl]-N-[(5-phenylfuran-2-yl)methyl]benzenesulfonamide
In the title compound, C29H25NO4S, the molecular conformation is stable with intramolecular C—H...O and C—H...N interactions being observed. In the crystal, molecules are linked by C—H...O interactions, forming layers parallel to the (100) plane. In addition, π–π [centroid-to-centroid distance = 3.4...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2025-08-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | https://journals.iucr.org/paper?S2056989025006231 |
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| author | Selbi Annadurdyyeva Anastasia E. Levina Victor N. Khrustalev Roya Z. Nazarova Khudayar I. Hasanov Nurlana D. Sadikhova Mehmet Akkurt Gizachew Mulugeta Manahelohe |
| author_facet | Selbi Annadurdyyeva Anastasia E. Levina Victor N. Khrustalev Roya Z. Nazarova Khudayar I. Hasanov Nurlana D. Sadikhova Mehmet Akkurt Gizachew Mulugeta Manahelohe |
| author_sort | Selbi Annadurdyyeva |
| collection | DOAJ |
| description | In the title compound, C29H25NO4S, the molecular conformation is stable with intramolecular C—H...O and C—H...N interactions being observed. In the crystal, molecules are linked by C—H...O interactions, forming layers parallel to the (100) plane. In addition, π–π [centroid-to-centroid distance = 3.4961 (7) Å] and C—H...π interactions connect the molecules within the layers. The layers are also bound to each other by van der Waals interactions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from H...H (53.2%), C...H/H...C (28.9%) and O...H/H...O (13.8%) contacts. |
| format | Article |
| id | doaj-art-447e1263dce44b49836b099123745dd9 |
| institution | Kabale University |
| issn | 2056-9890 |
| language | English |
| publishDate | 2025-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj-art-447e1263dce44b49836b099123745dd92025-08-20T03:44:29ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902025-08-0181870671010.1107/S2056989025006231ee2017Crystal structure and Hirshfeld surface analysis of 4-methyl-N-[2-(5-methylfuran-2-yl)phenyl]-N-[(5-phenylfuran-2-yl)methyl]benzenesulfonamideSelbi Annadurdyyeva0Anastasia E. Levina1Victor N. Khrustalev2Roya Z. Nazarova3Khudayar I. Hasanov4Nurlana D. Sadikhova5Mehmet Akkurt6Gizachew Mulugeta Manahelohe7RUDN University, 6 Miklukho-Maklaya St., Moscow 117198, Russian FederationRUDN University, 6 Miklukho-Maklaya St., Moscow 117198, Russian FederationRUDN University, 6 Miklukho-Maklaya St., Moscow 117198, Russian FederationBaku Engineering University, Khirdalan, Hasan Aliyev str. 120, AZ0101, Absheron, AzerbaijanAzerbaijan Medical University, Scientific Research Centre (SRC), A. Kasumzade St. 14, AZ 1022, Baku, AzerbaijanDepartment of Organic Chemistry, Baku State University, Z. Xalilov Str. 23, AZ 1148 Baku, AzerbaijanDepartment of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, TürkiyeDepartment of Chemistry, University of Gondar, PO Box 196, Gondar, EthiopiaIn the title compound, C29H25NO4S, the molecular conformation is stable with intramolecular C—H...O and C—H...N interactions being observed. In the crystal, molecules are linked by C—H...O interactions, forming layers parallel to the (100) plane. In addition, π–π [centroid-to-centroid distance = 3.4961 (7) Å] and C—H...π interactions connect the molecules within the layers. The layers are also bound to each other by van der Waals interactions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from H...H (53.2%), C...H/H...C (28.9%) and O...H/H...O (13.8%) contacts.https://journals.iucr.org/paper?S2056989025006231crystal structurehydrogen bondvan der waals interactionshirshfeld surface analysis |
| spellingShingle | Selbi Annadurdyyeva Anastasia E. Levina Victor N. Khrustalev Roya Z. Nazarova Khudayar I. Hasanov Nurlana D. Sadikhova Mehmet Akkurt Gizachew Mulugeta Manahelohe Crystal structure and Hirshfeld surface analysis of 4-methyl-N-[2-(5-methylfuran-2-yl)phenyl]-N-[(5-phenylfuran-2-yl)methyl]benzenesulfonamide Acta Crystallographica Section E: Crystallographic Communications crystal structure hydrogen bond van der waals interactions hirshfeld surface analysis |
| title | Crystal structure and Hirshfeld surface analysis of 4-methyl-N-[2-(5-methylfuran-2-yl)phenyl]-N-[(5-phenylfuran-2-yl)methyl]benzenesulfonamide |
| title_full | Crystal structure and Hirshfeld surface analysis of 4-methyl-N-[2-(5-methylfuran-2-yl)phenyl]-N-[(5-phenylfuran-2-yl)methyl]benzenesulfonamide |
| title_fullStr | Crystal structure and Hirshfeld surface analysis of 4-methyl-N-[2-(5-methylfuran-2-yl)phenyl]-N-[(5-phenylfuran-2-yl)methyl]benzenesulfonamide |
| title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of 4-methyl-N-[2-(5-methylfuran-2-yl)phenyl]-N-[(5-phenylfuran-2-yl)methyl]benzenesulfonamide |
| title_short | Crystal structure and Hirshfeld surface analysis of 4-methyl-N-[2-(5-methylfuran-2-yl)phenyl]-N-[(5-phenylfuran-2-yl)methyl]benzenesulfonamide |
| title_sort | crystal structure and hirshfeld surface analysis of 4 methyl n 2 5 methylfuran 2 yl phenyl n 5 phenylfuran 2 yl methyl benzenesulfonamide |
| topic | crystal structure hydrogen bond van der waals interactions hirshfeld surface analysis |
| url | https://journals.iucr.org/paper?S2056989025006231 |
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