Superior wear performance of CoCrNi matrix composite reinforced with quasi-continuously networked graphene nanosheets and in-situ carbide

The biological materials evolved in nature generally exhibit interpenetrating network structures, which may offer useful inspiration for the architectural design of wear-resistant composites. Here, a strategy for designing self-lubricating medium entropy alloy (MEA) composites with high strength and...

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Main Authors: Wenting Ye, Mingda Xie, Qing Zhou, Biao Chen, Yixue Li, Lei Jia, Haifeng Wang, Weimin Liu
Format: Article
Language:English
Published: Tsinghua University Press 2025-07-01
Series:Friction
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Online Access:https://www.sciopen.com/article/10.26599/FRICT.2025.9441001
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author Wenting Ye
Mingda Xie
Qing Zhou
Biao Chen
Yixue Li
Lei Jia
Haifeng Wang
Weimin Liu
author_facet Wenting Ye
Mingda Xie
Qing Zhou
Biao Chen
Yixue Li
Lei Jia
Haifeng Wang
Weimin Liu
author_sort Wenting Ye
collection DOAJ
description The biological materials evolved in nature generally exhibit interpenetrating network structures, which may offer useful inspiration for the architectural design of wear-resistant composites. Here, a strategy for designing self-lubricating medium entropy alloy (MEA) composites with high strength and excellent anti-wear performance was proposed through quasi-continuously networked in-situ carbides and graphene nanosheets. The discontinuous coating of graphene on the MEA powder surface inhibits continuous metallurgy bonding of the MEA powders during sintering, generating the typical quasi-continuously networked architecture. A good combination of mechanical properties with high fracture strength over 2 GPa and large compressive plasticity over 30% benefits from metallurgy bonding that prevents crack initiation and extension. The wear rate of an order of 10−6 m3·N−1·m−1 ascribing to an amorphous-crystalline nanocomposite surface, tribo-film induced by graphene, as well as the gradient worn subsurface during friction was achieved by the MEA composite, which is an order of magnitude lower than the unreinforced MEA matrix.
format Article
id doaj-art-4407bcd2de9e47f1a8e763869da5674c
institution Kabale University
issn 2223-7690
2223-7704
language English
publishDate 2025-07-01
publisher Tsinghua University Press
record_format Article
series Friction
spelling doaj-art-4407bcd2de9e47f1a8e763869da5674c2025-08-20T03:59:44ZengTsinghua University PressFriction2223-76902223-77042025-07-01138944100110.26599/FRICT.2025.9441001Superior wear performance of CoCrNi matrix composite reinforced with quasi-continuously networked graphene nanosheets and in-situ carbideWenting Ye0Mingda Xie1Qing Zhou2Biao Chen3Yixue Li4Lei Jia5Haifeng Wang6Weimin Liu7Research & Development Institute of Northwestern Polytechnical University in Shenzhen, Shenzhen 518063, ChinaResearch & Development Institute of Northwestern Polytechnical University in Shenzhen, Shenzhen 518063, ChinaResearch & Development Institute of Northwestern Polytechnical University in Shenzhen, Shenzhen 518063, ChinaResearch & Development Institute of Northwestern Polytechnical University in Shenzhen, Shenzhen 518063, ChinaAnalytical & Testing Center, Northwestern Polytechnical University, Xi’an 710072, ChinaSchool of Materials Science and Engineering, Xi'an University of Technology, Xi'an 710048, ChinaResearch & Development Institute of Northwestern Polytechnical University in Shenzhen, Shenzhen 518063, ChinaState Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, ChinaThe biological materials evolved in nature generally exhibit interpenetrating network structures, which may offer useful inspiration for the architectural design of wear-resistant composites. Here, a strategy for designing self-lubricating medium entropy alloy (MEA) composites with high strength and excellent anti-wear performance was proposed through quasi-continuously networked in-situ carbides and graphene nanosheets. The discontinuous coating of graphene on the MEA powder surface inhibits continuous metallurgy bonding of the MEA powders during sintering, generating the typical quasi-continuously networked architecture. A good combination of mechanical properties with high fracture strength over 2 GPa and large compressive plasticity over 30% benefits from metallurgy bonding that prevents crack initiation and extension. The wear rate of an order of 10−6 m3·N−1·m−1 ascribing to an amorphous-crystalline nanocomposite surface, tribo-film induced by graphene, as well as the gradient worn subsurface during friction was achieved by the MEA composite, which is an order of magnitude lower than the unreinforced MEA matrix.https://www.sciopen.com/article/10.26599/FRICT.2025.9441001in-situ carbidetribological behaviormedium entropy alloy matrix compositegraphene
spellingShingle Wenting Ye
Mingda Xie
Qing Zhou
Biao Chen
Yixue Li
Lei Jia
Haifeng Wang
Weimin Liu
Superior wear performance of CoCrNi matrix composite reinforced with quasi-continuously networked graphene nanosheets and in-situ carbide
Friction
in-situ carbide
tribological behavior
medium entropy alloy matrix composite
graphene
title Superior wear performance of CoCrNi matrix composite reinforced with quasi-continuously networked graphene nanosheets and in-situ carbide
title_full Superior wear performance of CoCrNi matrix composite reinforced with quasi-continuously networked graphene nanosheets and in-situ carbide
title_fullStr Superior wear performance of CoCrNi matrix composite reinforced with quasi-continuously networked graphene nanosheets and in-situ carbide
title_full_unstemmed Superior wear performance of CoCrNi matrix composite reinforced with quasi-continuously networked graphene nanosheets and in-situ carbide
title_short Superior wear performance of CoCrNi matrix composite reinforced with quasi-continuously networked graphene nanosheets and in-situ carbide
title_sort superior wear performance of cocrni matrix composite reinforced with quasi continuously networked graphene nanosheets and in situ carbide
topic in-situ carbide
tribological behavior
medium entropy alloy matrix composite
graphene
url https://www.sciopen.com/article/10.26599/FRICT.2025.9441001
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