A BaTiO3-based flexible ferroelectric capacitor for non-volatile memories

BaTiO3 (BTO) ferroelectric films, which are renowned for their lead-free compositions, superior stability, and absence of a wake-up effect, are promising candidate materials in the field of non-volatile memories. However, the prerequisites for high-temperature conditions in the fabrication of ferroe...

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Main Authors: Xingpeng Liu, Chunshu Wei, Tangyou Sun, Fabi Zhang, Haiou Li, Linsheng Liu, Ying Peng, Hezhang Li, Min Hong
Format: Article
Language:English
Published: Elsevier 2025-03-01
Series:Journal of Materiomics
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Online Access:http://www.sciencedirect.com/science/article/pii/S2352847824000856
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author Xingpeng Liu
Chunshu Wei
Tangyou Sun
Fabi Zhang
Haiou Li
Linsheng Liu
Ying Peng
Hezhang Li
Min Hong
author_facet Xingpeng Liu
Chunshu Wei
Tangyou Sun
Fabi Zhang
Haiou Li
Linsheng Liu
Ying Peng
Hezhang Li
Min Hong
author_sort Xingpeng Liu
collection DOAJ
description BaTiO3 (BTO) ferroelectric films, which are renowned for their lead-free compositions, superior stability, and absence of a wake-up effect, are promising candidate materials in the field of non-volatile memories. However, the prerequisites for high-temperature conditions in the fabrication of ferroelectric thin films impose constraints on the substrate choice, which has limited the advancement in non-volatile memories based on single-crystal flexible BTO films with robust ferroelectric properties. Herein, a technique has been developed for the fabrication of flexible devices using a pulsed laser deposition system. BTO ferroelectric films have then been deposited onto a flexible mica substrate, with SrTiO3 (STO) serving as a buffer layer. The obtained flexible BTO devices exhibited excellent ferroelectricity, with a maximum polarization (2Pmax) of up to 42.58 μC/cm2 and a remnant polarization (2Pr) of up to 21.39 μC/cm2. Furthermore, even after 1000 bending cycles, the bipolar switching endurance remained high at 1012 cycles. After 104 s, the flexible BTO device still maintained excellent polarization characteristics. These results make the flexible BTO ferroelectric thin film a potential candidate for the next generation of non-volatile memories.
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id doaj-art-43c4d3db1a3a4ddab2cc4953998ef66f
institution Kabale University
issn 2352-8478
language English
publishDate 2025-03-01
publisher Elsevier
record_format Article
series Journal of Materiomics
spelling doaj-art-43c4d3db1a3a4ddab2cc4953998ef66f2025-01-14T04:12:27ZengElsevierJournal of Materiomics2352-84782025-03-01112100870A BaTiO3-based flexible ferroelectric capacitor for non-volatile memoriesXingpeng Liu0Chunshu Wei1Tangyou Sun2Fabi Zhang3Haiou Li4Linsheng Liu5Ying Peng6Hezhang Li7Min Hong8Guangxi Key Laboratory of Precision Navigation Technology and Application, Guilin University of Electronic Technology, Guilin, 541004, ChinaGuangxi Key Laboratory of Precision Navigation Technology and Application, Guilin University of Electronic Technology, Guilin, 541004, ChinaGuangxi Key Laboratory of Precision Navigation Technology and Application, Guilin University of Electronic Technology, Guilin, 541004, ChinaGuangxi Key Laboratory of Precision Navigation Technology and Application, Guilin University of Electronic Technology, Guilin, 541004, ChinaGuangxi Key Laboratory of Precision Navigation Technology and Application, Guilin University of Electronic Technology, Guilin, 541004, ChinaSchool of Electronic and Information Engineering/School of Integrated Circuits, Guangxi Normal University, Guilin, 541004, ChinaGuangxi Key Laboratory of Precision Navigation Technology and Application, Guilin University of Electronic Technology, Guilin, 541004, China; Corresponding author.Department of Precision Instrument, Tsinghua University, Beijing, 100084, China; Corresponding author.Centre for Future Materials, and School of Engineering, University of Southern Queensland, Springfield Central, Queensland, 4300, Australia; Corresponding author.BaTiO3 (BTO) ferroelectric films, which are renowned for their lead-free compositions, superior stability, and absence of a wake-up effect, are promising candidate materials in the field of non-volatile memories. However, the prerequisites for high-temperature conditions in the fabrication of ferroelectric thin films impose constraints on the substrate choice, which has limited the advancement in non-volatile memories based on single-crystal flexible BTO films with robust ferroelectric properties. Herein, a technique has been developed for the fabrication of flexible devices using a pulsed laser deposition system. BTO ferroelectric films have then been deposited onto a flexible mica substrate, with SrTiO3 (STO) serving as a buffer layer. The obtained flexible BTO devices exhibited excellent ferroelectricity, with a maximum polarization (2Pmax) of up to 42.58 μC/cm2 and a remnant polarization (2Pr) of up to 21.39 μC/cm2. Furthermore, even after 1000 bending cycles, the bipolar switching endurance remained high at 1012 cycles. After 104 s, the flexible BTO device still maintained excellent polarization characteristics. These results make the flexible BTO ferroelectric thin film a potential candidate for the next generation of non-volatile memories.http://www.sciencedirect.com/science/article/pii/S2352847824000856BaTiO3 ferroelectric filmsNon-volatile memoryFlexible mica substrate
spellingShingle Xingpeng Liu
Chunshu Wei
Tangyou Sun
Fabi Zhang
Haiou Li
Linsheng Liu
Ying Peng
Hezhang Li
Min Hong
A BaTiO3-based flexible ferroelectric capacitor for non-volatile memories
Journal of Materiomics
BaTiO3 ferroelectric films
Non-volatile memory
Flexible mica substrate
title A BaTiO3-based flexible ferroelectric capacitor for non-volatile memories
title_full A BaTiO3-based flexible ferroelectric capacitor for non-volatile memories
title_fullStr A BaTiO3-based flexible ferroelectric capacitor for non-volatile memories
title_full_unstemmed A BaTiO3-based flexible ferroelectric capacitor for non-volatile memories
title_short A BaTiO3-based flexible ferroelectric capacitor for non-volatile memories
title_sort batio3 based flexible ferroelectric capacitor for non volatile memories
topic BaTiO3 ferroelectric films
Non-volatile memory
Flexible mica substrate
url http://www.sciencedirect.com/science/article/pii/S2352847824000856
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