Synthesis and characterization of novel organotin carboxylate maleimide monomers and copolymers
Two novel tributyltin carboxylate maleimide monomers, tributyltin(maleimido)acetate and tributyltin(4-maleimido)benzoate, were synthesized by condensation reaction of maleimidoacetic acid or 4-maleimidobenzoic acid with bis(tributyltin) oxide. Copolymerization of these monomers with styrene was carr...
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| Language: | English |
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Budapest University of Technology and Economics
2009-06-01
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| Series: | eXPRESS Polymer Letters |
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| Online Access: | http://www.expresspolymlett.com/letolt.php?file=EPL-0000921&mi=cd |
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| description | Two novel tributyltin carboxylate maleimide monomers, tributyltin(maleimido)acetate and tributyltin(4-maleimido)benzoate, were synthesized by condensation reaction of maleimidoacetic acid or 4-maleimidobenzoic acid with bis(tributyltin) oxide. Copolymerization of these monomers with styrene was carried in dioxane at 70°C using asobisisobutyronitrile as free radical initiator. The structures of monomers and copolymers were confirmed by FT-IR (Fourier Transform Infrared), 1H and 13C NMR (nuclear magnetic resonance) spectroscopy and elemental analysis. The copolymers were characterized by solubility and thermal analysis. |
| format | Article |
| id | doaj-art-43c06fa29fdb462380cd6416d41265e4 |
| institution | DOAJ |
| issn | 1788-618X |
| language | English |
| publishDate | 2009-06-01 |
| publisher | Budapest University of Technology and Economics |
| record_format | Article |
| series | eXPRESS Polymer Letters |
| spelling | doaj-art-43c06fa29fdb462380cd6416d41265e42025-08-20T02:52:45ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2009-06-013635235810.3144/expresspolymlett.2009.44Synthesis and characterization of novel organotin carboxylate maleimide monomers and copolymersTwo novel tributyltin carboxylate maleimide monomers, tributyltin(maleimido)acetate and tributyltin(4-maleimido)benzoate, were synthesized by condensation reaction of maleimidoacetic acid or 4-maleimidobenzoic acid with bis(tributyltin) oxide. Copolymerization of these monomers with styrene was carried in dioxane at 70°C using asobisisobutyronitrile as free radical initiator. The structures of monomers and copolymers were confirmed by FT-IR (Fourier Transform Infrared), 1H and 13C NMR (nuclear magnetic resonance) spectroscopy and elemental analysis. The copolymers were characterized by solubility and thermal analysis.http://www.expresspolymlett.com/letolt.php?file=EPL-0000921&mi=cdPolymer synthesis, molecular etributyltin polymeric carboxylmaleimide copolymer |
| spellingShingle | Synthesis and characterization of novel organotin carboxylate maleimide monomers and copolymers eXPRESS Polymer Letters Polymer synthesis, molecular e tributyltin polymeric carboxyl maleimide copolymer |
| title | Synthesis and characterization of novel organotin carboxylate maleimide monomers and copolymers |
| title_full | Synthesis and characterization of novel organotin carboxylate maleimide monomers and copolymers |
| title_fullStr | Synthesis and characterization of novel organotin carboxylate maleimide monomers and copolymers |
| title_full_unstemmed | Synthesis and characterization of novel organotin carboxylate maleimide monomers and copolymers |
| title_short | Synthesis and characterization of novel organotin carboxylate maleimide monomers and copolymers |
| title_sort | synthesis and characterization of novel organotin carboxylate maleimide monomers and copolymers |
| topic | Polymer synthesis, molecular e tributyltin polymeric carboxyl maleimide copolymer |
| url | http://www.expresspolymlett.com/letolt.php?file=EPL-0000921&mi=cd |